Acrylic Tinting/Dye Concentrate
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Page 1\n \nPage 1/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\n59.1.0\n* 1 Identification\n· Product name: Acrylic Tinting Concentrate\n· Part number: 170-21000, 170-21005, 170-21010, 170-21015\n· Application of the substance / the mixture\nTinting concentrate\nAdditive\n· Details of the supplier of the safety data sheet\n· Manufacturer/Supplier:\nAllied High Tech Products Inc.\n16207 Carmenita Road\nUSA-Cerritos, CA, 90703\nUSA\ninfo@alliedhightech.com\n· Information department: Product safety department\n· Emergency telephone number:\nDuring normal opening times: +1 (310) 635-2466\nChemtrec: +1 (202) 483-7616\n* 2 Hazard(s) identification\n· Classification of the substance or mixture\nGHS02 Flame\nFlammable Liquids 2\nH225 Highly flammable liquid and vapor.\nGHS07\nSkin Irritation 2\nH315 Causes skin irritation.\nSensitization - Skin 1\nH317 May cause an allergic skin reaction.\nSpecific Target Organ Toxicity - Single Exposure 3 H335 May cause respiratory irritation.\n· Label elements\n· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).\n· Hazard pictograms\nGHS02\nGHS07\n· Signal word Danger\n(Contd. on page 2)\n\n\nPage 2\nPage 2/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Acrylic Tinting Concentrate\n(Contd. of page 1)\n59.1.0\n· Hazard-determining components of labeling:\nmethyl methacrylate\n· Hazard statements\nHighly flammable liquid and vapor.\nCauses skin irritation.\nMay cause an allergic skin reaction.\nMay cause respiratory irritation.\n· Precautionary statements\nKeep away from heat/sparks/open flames/hot surfaces. - No smoking.\nKeep cool.\nGround/bond container and receiving equipment.\nUse explosion-proof electrical/ventilating/lighting/equipment.\nUse only non-sparking tools.\nTake precautionary measures against static discharge.\nAvoid breathing dust/fume/gas/mist/vapors/spray\nWash thoroughly after handling.\nUse only outdoors or in a well-ventilated area.\nContaminated work clothing must not be allowed out of the workplace.\nWear protective gloves/protective clothing/eye protection/face protection.\nIf on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.\nIF INHALED: Remove person to fresh air and keep comfortable for breathing.\nCall a poison center/doctor if you feel unwell.\nIf skin irritation or rash occurs: Get medical advice/attention.\nTake off contaminated clothing.\nIn case of fire: Use CO2, powder or water spray to extinguish.\nStore in a well-ventilated place. Keep container tightly closed.\nDispose of contents/container in accordance with local/regional/national/international regulations.\n3 Composition/information on ingredients\n· Chemical characterization: Mixtures\n· Description: Mixture of the substances listed below with nonhazardous additions.\n· Hazardous components and components with occupational exposure limits:\n80-62-6 methyl methacrylate\n Flammable Liquids 2, H225;\n Acute Toxicity - Inhalation 4, H332; Skin Irritation 2, H315; Sensitization - Skin 1,\nH317; Specific Target Organ Toxicity - Single Exposure 3, H335\n>95%\n99-97-8 N,N-dimethyl-p-toluidine\n Acute Toxicity - Oral 3, H301; Acute Toxicity - Dermal 3, H311; Acute Toxicity - Inhalation 3, H331;\n Carcinogenicity 2, H351; Specific Target Organ Toxicity - Repeated Exposure 2, H373; Flammable Liquids 4, H227;\nAquatic Chronic 3, H412\n<2%\n· Non-hazardous components:\nDye\n<2%\n· Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.\n4 First-aid measures\n· Description of first aid measures\n· General information: Immediately remove any clothing soiled by the product.\n· After inhalation:\nSupply fresh air and to be sure call for a doctor.\nIn case of unconsciousness place patient stably in side position for transportation.\n· After skin contact: Immediately wash with water and soap and rinse thoroughly.\n· After eye contact: Rinse opened eye for several minutes under running water.\n· After swallowing: Rinse out mouth and then drink plenty of water.\n(Contd. on page 3)\n\n\nPage 3\nPage 3/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Acrylic Tinting Concentrate\n(Contd. of page 2)\n59.1.0\n· Information for doctor:\n· Most important symptoms and effects, both acute and delayed\nHeadache\nDizziness\nAllergic reactions\nNausea\nDermatitis\n· Indication of any immediate medical attention and special treatment needed No further relevant information available.\n5 Fire-fighting measures\n· Extinguishing media\n· Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.\n· For safety reasons unsuitable extinguishing agents: Water with full jet\n· Special hazards arising from the substance or mixture No further relevant information available.\n· Advice for firefighters\n· Protective equipment: Wear fully protective suit.\n6 Accidental release measures\n· Personal precautions, protective equipment and emergency procedures\nWear protective equipment. Keep unprotected persons away.\nEnsure adequate ventilation\nKeep away from ignition sources\n· Environmental precautions:\nPrevent seepage into sewage system, workpits and cellars.\nDilute with plenty of water.\n· Methods and material for containment and cleaning up:\nAbsorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).\nDispose contaminated material as waste according to section 13.\nEnsure adequate ventilation.\n· Reference to other sections\nSee Section 7 for information on safe handling.\nSee Section 8 for information on personal protection equipment.\nSee Section 13 for disposal information.\n7 Handling and storage\n· Handling:\n· Precautions for safe handling\nProtect from heat and direct sunlight.\nEnsure proper ventilation/exhaustion at workplaces.\nPrevent formation of aerosols.\n· Information about protection against explosions and fires:\nKeep ignition sources away - Do not smoke.\nProtect against electrostatic charges.\n· Conditions for safe storage, including any incompatibilities\n· Storage:\n· Requirements to be met by storerooms and receptacles: Store at temperatures not exceeding 25°C.\n· Information about storage in one common storage facility:\nStore away from oxidizing agents.\nStore away from reducing agents.\n· Further information about storage conditions:\nKeep receptacle tightly sealed.\nStore in cool, dry conditions in well sealed receptacles.\nStore receptacle in a well ventilated area.\n· Specific end use(s) No further relevant information available.\n(Contd. on page 4)\n\n\nPage 4\nPage 4/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Acrylic Tinting Concentrate\n(Contd. of page 3)\n59.1.0\n8 Exposure controls/personal protection\n· Additional information about design of technical systems: No additional data. See 7.\n· Control parameters\n· Components with limit values that require monitoring at the workplace:\n80-62-6 methyl methacrylate\nPEL\nLong-term value: 410 mg/m³, 100 ppm\nREL\nLong-term value: 410 mg/m³, 100 ppm\nTLV\nShort-term value: 100 ppm\nLong-term value: 50 ppm\nDSEN, A4\n99-97-8 N,N-dimethyl-p-toluidine\nWEEL Long-term value: 0.5 ppm\n· Exposure controls\n· Personal protective equipment:\n· General protective and hygienic measures:\nKeep away from foodstuffs, beverages and feed.\nImmediately remove all soiled and contaminated clothing.\nWash hands before breaks and at the end of work.\nAvoid contact with the skin.\nAvoid contact with the eyes and skin.\n· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.\n· Protection of hands:\nDue to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.\nProtective gloves\nThe glove material has to be impermeable and resistant to the product/ the substance/ the preparation.\nSelection of the glove material on consideration of the penetration times, rates of diffusion and the degradation\n· Material of gloves\nThe selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer\nto manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance\nand has therefore to be checked prior to the application.\n· Eye protection:\nTightly sealed goggles\n9 Physical and chemical properties\n· Information on basic physical and chemical properties\n· General Information\n· Appearance:\nForm:\nLiquid\nColor:\nAccording to product specification\n· Odor:\nAcrid\n· Odor threshold:\nNot determined.\n· pH-value:\nNot determined.\n(Contd. on page 5)\n\n\nPage 5\nPage 5/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Acrylic Tinting Concentrate\n(Contd. of page 4)\n59.1.0\n· Change in condition\nMelting point/Melting range:\n-48 °C (-54.4 °F)\nBoiling point/Boiling range:\n101 °C (213.8 °F)\n· Flash point:\n11.5 °C (52.7 °F)\n· Flammability (solid, gaseous):\nHighly flammable.\n· Auto igniting:\n430 °C (806 °F)\n· Decomposition temperature:\nNot determined.\n· Ignition temperature:\nProduct is not selfigniting.\n· Danger of explosion:\nProduct is not explosive. However, formation of explosive air/vapor mixtures are possible.\n· Explosion limits:\nLower:\n2.1 Vol %\nUpper:\n12.5 Vol %\n· Vapor pressure at 20 °C (68 °F):\n47 hPa (35.3 mm Hg)\n· Density at 20 °C (68 °F):\n0.94 g/cm³ (7.844 lbs/gal)\n· Relative density\nNot determined.\n· Vapor density at 15.5 °C (59.9 °F)\n3.5 (Air = 1)\n· Specific gravity:\n0.949 (Water = 1)\n· Evaporation rate\n3.1 (BuAc =1)\n· Solubility in / Miscibility with\nWater at 20 °C (68 °F):\n1.6 g/l\n· Partition coefficient (n-octanol/water): Not determined.\n· Viscosity:\nDynamic:\nNot determined.\nKinematic:\nNot determined.\n· Solvent content:\nVOC content:\n0.00 %\n· Other information\nNo further relevant information available.\n10 Stability and reactivity\n· Reactivity No further relevant information available.\n· Chemical stability\n· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.\n· Possibility of hazardous reactions Danger of polymerization.\n· Conditions to avoid\nProtect from sunlight.\nKeep away from oxidising agents and acidic substances.\nFreezing conditions\n· Incompatible materials: No further relevant information available.\n· Hazardous decomposition products: Carbon monoxide and carbon dioxide\n· Additional information: Hazardous decomposition products may form during combustion.\n11 Toxicological information\n· Information on toxicological effects\n· Acute toxicity:\n· LD/LC50 values that are relevant for classification:\nATE (Acute Toxicity Estimate)\nOral\nLD50\n165,000 mg/kg (rat)\n(Contd. on page 6)\n\n\nPage 6\nPage 6/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Acrylic Tinting Concentrate\n(Contd. of page 5)\n59.1.0\nDermal\nLD50\n30,000 mg/kg\nInhalative LC50/4 h 16.2 mg/l (rat)\n 80-62-6 methyl methacrylate\nOral\nLD50\n7,872 mg/kg (rat)\nDermal\nLD50\n5,000 mg/kg (rabbit)\nInhalative LC50/4 h 18 mg/l (rat)\n99-97-8 N,N-dimethyl-p-toluidine\nOral\nLD50\n1,650 mg/kg (rat)\nDermal\nLD50\n300 mg/kg (ATE)\nInhalative LC50/4 h 1.4 mg/l (rat)\n· Primary chemical irritant effect:\n· on the skin: Irritant to skin and mucous membranes.\n· on the eye: No irritating effect.\n· Sensitization: Sensitization possible through skin contact.\n· Additional toxicological information:\n· Carcinogenic categories\n· IARC (International Agency for Research on Cancer)\n80-62-6 methyl methacrylate\n3 \n99-97-8 N,N-dimethyl-p-toluidine\n2B\n· NTP (National Toxicology Program)\nNone of the ingredients is listed.\n· OSHA-Ca (Occupational Safety & Health Administration)\nNone of the ingredients is listed.\n12 Ecological information\n· Toxicity\n· Aquatic toxicity:\n80-62-6 methyl methacrylate\nEC50 (96 h) 170 mg/l (pseudokirchneriella subcapitata)\nEC50 (48 h) 69 mg/l (daphnia)\nLC50 (96 h) 79 mg/l (oncorhynchus mykiss)\n99-97-8 N,N-dimethyl-p-toluidine\nLC50 (96 h) 46 mg/l (pimephales promelas)\n· Persistence and degradability Not easily biodegradable\n· Behavior in environmental systems:\n· Bioaccumulative potential No further relevant information available.\n· Mobility in soil Potential for mobility in soil is very high.\n· Additional ecological information:\n· General notes:\nWater hazard class 1 (Self-assessment): slightly hazardous for water\nDo not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.\n· Results of PBT and vPvB assessment\n· PBT: Not applicable.\n· vPvB: Not applicable.\n· Other adverse effects No further relevant information available.\n(Contd. on page 7)\n\n\nPage 7\nPage 7/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Acrylic Tinting Concentrate\n(Contd. of page 6)\n59.1.0\n13 Disposal considerations\n· Waste treatment methods\n· Recommendation: Contact waste processors for recycling information.\n· Uncleaned packagings:\n· Recommendation: Disposal must be made according to official regulations.\n* 14 Transport information\n· UN-Number\n· DOT, IMDG, IATA\nUN1993\n· UN proper shipping name\n· DOT\nFlammable liquids, n.o.s. (Methyl methacrylate monomer, stabilized)\n· IMDG, IATA\nFLAMMABLE LIQUID, N.O.S. (METHYL METHACRYLATE\nMONOMER, STABILIZED)\n· Transport hazard class(es)\n· DOT\n· Class\n3 Flammable liquids\n· Label\n3 \n· IMDG, IATA\n· Class\n3 Flammable liquids\n· Label\n3 \n· Packing group\n· DOT, IMDG, IATA\nII\n· Environmental hazards:\n· Marine pollutant:\nNo\n· Special precautions for user\nWarning: Flammable liquids\n· Hazard identification number (Kemler code):\n33\n· EMS Number:\nF-E,S-E\n· Stowage Category\nB \n· Transport in bulk according to Annex II of MARPOL73/78 and\nthe IBC Code\nNot applicable.\n· Transport/Additional information:\n· DOT\n· Quantity limitations\nOn passenger aircraft/rail: 5 L\nOn cargo aircraft only: 60 L\n· Limited quantities (LQ)\n1L\n· Transport category\n2 \n· Tunnel restriction code\nD/E\n(Contd. on page 8)\n\n\nPage 8\nPage 8/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Acrylic Tinting Concentrate\n(Contd. of page 7)\n59.1.0\n· IMDG\n· Limited quantities (LQ)\n1L\n· Excepted quantities (EQ)\nCode: E2\nMaximum net quantity per inner packaging: 30 ml\nMaximum net quantity per outer packaging: 500 ml\n· UN "Model Regulation":\nUN 1993 FLAMMABLE LIQUID, N.O.S. (METHYL\nMETHACRYLATE MONOMER, STABILIZED), 3, II\n15 Regulatory information\n· Safety, health and environmental regulations/legislation specific for the substance or mixture\n· Sara\n· Section 355 (extremely hazardous substances):\nNone of the ingredients is listed.\n· Section 313 (Specific toxic chemical listings):\n80-62-6 methyl methacrylate\n· TSCA (Toxic Substances Control Act):\nAll other ingredients are exempt from listing.\nAll components have the value ACTIVE.\n· Hazardous Air Pollutants\n80-62-6 methyl methacrylate\n· Proposition 65\n· Chemicals known to cause cancer:\n99-97-8 N,N-dimethyl-p-toluidine\n· Chemicals known to cause reproductive toxicity for females:\nNone of the ingredients is listed.\n· Chemicals known to cause reproductive toxicity for males:\nNone of the ingredients is listed.\n· Chemicals known to cause developmental toxicity:\nNone of the ingredients is listed.\n· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.\n16 Other information\nTo the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties\nand does not establish a contractual legal relationship.\n· Department issuing SDS: Technical Services\n· Contact: Pablo Mendoza\n· Last revision / supersedes version: 06/01/2024 / 5.1\n· Supersedes date: 06/01/2022\n· Abbreviations and acronyms:\nADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by\nRoad)\nIMDG: International Maritime Code for Dangerous Goods\nDOT: US Department of Transportation\nIATA: International Air Transport Association\nEINECS: European Inventory of Existing Commercial Chemical Substances\nELINCS: European List of Notified Chemical Substances\nCAS: Chemical Abstracts Service (division of the American Chemical Society)\nVOC: Volatile Organic Compounds (USA, EU)\nLC50: Lethal concentration, 50 percent\nLD50: Lethal dose, 50 percent\nPBT: Persistent, Bioaccumulative and Toxic\nvPvB: very Persistent and very Bioaccumulative\nOSHA: Occupational Safety & Health\n(Contd. on page 9)\n\n\nPage 9\nPage 9/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Acrylic Tinting Concentrate\n(Contd. of page 8)\n59.1.0\nTLV: Threshold Limit Value\nPEL: Permissible Exposure Limit\nREL: Recommended Exposure Limit\nFlammable Liquids 2: Flammable liquids – Category 2\nFlammable Liquids 4: Flammable liquids – Category 4\nAcute Toxicity - Oral 3: Acute toxicity – Category 3\nAcute Toxicity - Inhalation 4: Acute toxicity – Category 4\nSkin Irritation 2: Skin corrosion/irritation – Category 2\nSensitization - Skin 1: Skin sensitisation – Category 1\nCarcinogenicity 2: Carcinogenicity – Category 2\nSpecific Target Organ Toxicity - Single Exposure 3: Specific target organ toxicity (single exposure) – Category 3\nSpecific Target Organ Toxicity - Repeated Exposure 2: Specific target organ toxicity (repeated exposure) – Category 2\nAquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3\n· * Data compared to the previous version altered. \n