ALUMINUM OXIDE BLADE - RESIN BOND SAFETY DATA SHEET
Also listed as: ALUMINUM OXIDE BLADE SAFETY DATA SHEET; Aluminum Oxide Abrasive Cut-Off Blades Resin Bond
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Page 1\n \nPage 1/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\n59.1.0\n* 1 Identification\n· Product name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n· Part number:\n80-10001 - 80-10045\n80-11300 - 80-11710\n80-30000 - 80-30035\n80-40000 - 80-40040\n80-50000 - 80-50040\n· Application of the substance / the mixture Abrasive blade\n· Details of the supplier of the safety data sheet\n· Manufacturer/Supplier:\nAllied High Tech Products Inc.\n16207 Carmenita Road\nUSA-Cerritos, CA, 90703\nUSA\ninfo@alliedhightech.com\n· Information department: Product safety department\n· Emergency telephone number:\nDuring normal opening times: +1 (310) 635-2466\nChemtrec: +1 (202) 483-7616\n2 Hazard(s) identification\n· Classification of the substance or mixture\nGHS08 Health hazard\nCarcinogenicity 2\nH351 Suspected of causing cancer. Route of exposure: Inhalation.\nSpecific Target Organ Toxicity - Repeated Exposure 1 H372 Causes damage to the lung and the bones through prolonged or repeated\nexposure.\nGHS07\nSkin Irritation 2\nH315 Causes skin irritation.\nEye Irritation 2A\nH319 Causes serious eye irritation.\nSensitization - Skin 1\nH317 May cause an allergic skin reaction.\nAquatic Chronic 3\nH412 Harmful to aquatic life with long lasting effects.\n· Additional information:\nAll components listed for this product are bound within the product. When handled as intended and under normal conditions of use, there is\nno evidence that any of the ingredients are released in amounts that pose a significant health risk.\n(Contd. on page 2)\n\n\nPage 2\nPage 2/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n(Contd. of page 1)\n59.1.0\n· Label elements\n· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).\n· Hazard pictograms\nGHS07\nGHS08\n· Signal word Danger\n· Hazard-determining components of labeling:\ntrisodium hexafluoroaluminate\ntitanium dioxide\nmethenamine\n· Hazard statements\nCauses skin irritation.\nCauses serious eye irritation.\nMay cause an allergic skin reaction.\nSuspected of causing cancer. Route of exposure: Inhalation.\nCauses damage to the lung and the bones through prolonged or repeated exposure.\nHarmful to aquatic life with long lasting effects.\n· Precautionary statements\nObtain special instructions before use.\nDo not handle until all safety precautions have been read and understood.\nDo not breathe dust/fume/gas/mist/vapors/spray.\nWash thoroughly after handling.\nDo not eat, drink or smoke when using this product.\nContaminated work clothing must not be allowed out of the workplace.\nAvoid release to the environment.\nWear protective gloves/protective clothing/eye protection/face protection.\nIf on skin: Wash with plenty of water.\nIf in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.\nIF exposed or concerned: Get medical advice/attention.\nSpecific treatment (see on this label).\nGet medical advice/attention if you feel unwell.\nTake off contaminated clothing and wash it before reuse.\nIf skin irritation or rash occurs: Get medical advice/attention.\nIf eye irritation persists: Get medical advice/attention.\nWash contaminated clothing before reuse.\nStore locked up.\nDispose of contents/container in accordance with local/regional/national/international regulations.\n3 Composition/information on ingredients\n· Chemical characterization: Mixtures\n· Description: Mixture of the substances listed below with nonhazardous additions.\n· Hazardous components and components with occupational exposure limits:\n1344-28-1 aluminium oxide\n50-60%\n1309-37-1 diiron trioxide\n5-10%\n7789-75-5 calcium fluoride\n5-10%\n13775-53-6 trisodium hexafluoroaluminate\n Specific Target Organ Toxicity - Repeated Exposure 1, H372;\n Aquatic Chronic 2, H411;\n Acute Toxicity -\nInhalation 4, H332\n2.5-<5%\n15096-52-3 cryolite\n Aquatic Chronic 2, H411;\n Acute Toxicity - Inhalation 4, H332\n2.5-<5%\n(Contd. on page 3)\n\n\nPage 3\nPage 3/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n(Contd. of page 2)\n59.1.0\n8002-74-2 Paraffin waxes and Hydrocarbon waxes\n1-5%\n14075-53-7 potassium tetrafluoroborate\n Acute Toxicity - Oral 3, H301;\n Skin Irritation 2, H315; Eye Irritation 2A, H319\n1-5%\n1305-62-0 calcium dihydroxide\n Skin Corrosion 1B, H314; Eye Damage 1, H318\n1-<3%\n100-97-0 methenamine\n Flammable Solids 2, H228;\n Sensitization - Skin 1, H317\n0.1-<1%\n13463-67-7 titanium dioxide\n Carcinogenicity 2, H351\n0.1-≤1%\n25104-55-6 Formaldehyde, polymer with phenol and urea\n Acute Toxicity - Dermal 4, H312; Sensitization - Skin 1B, H317\n0.1-<1%\n· Non-hazardous components:\n12068-85-8 Iron Disulphide\n5-10%\nPolymeric Resin (cured)\n5-10%\nEpoxy (cured)\n5-10%\n1314-98-3 zinc sulphide\n1-5%\n· Additional information:\nProduct may contain many or all of the above ingredients.\nThe specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.\n4 First-aid measures\n· Description of first aid measures\n· General information:\nImmediately remove any clothing soiled by the product.\nSymptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.\n· After inhalation:\nSupply fresh air and to be sure call for a doctor.\nIn case of unconsciousness place patient stably in side position for transportation.\n· After skin contact: Immediately wash with water and soap and rinse thoroughly.\n· After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.\n· After swallowing: If symptoms persist consult doctor.\n· Information for doctor:\n· Most important symptoms and effects, both acute and delayed\nBreathing difficulty\nEye irritation\nCoughing\nAllergic reactions\nDermatitis\nEye irritation\nDermatitis\n· Indication of any immediate medical attention and special treatment needed No further relevant information available.\n5 Fire-fighting measures\n· Extinguishing media\n· Suitable extinguishing agents: Use fire fighting measures that suit the environment.\n· Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced.\n· Advice for firefighters\n· Protective equipment: No special measures required.\n6 Accidental release measures\n· Personal precautions, protective equipment and emergency procedures Keep away from ignition sources\n· Environmental precautions:\nDo not allow product to reach sewage system or any water course.\n(Contd. on page 4)\n\n\nPage 4\nPage 4/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n(Contd. of page 3)\n59.1.0\nInform respective authorities in case of seepage into water course or sewage system.\n· Methods and material for containment and cleaning up:\nPick up mechanically.\nDispose contaminated material as waste according to section 13.\nEnsure adequate ventilation.\n· Reference to other sections\nSee Section 7 for information on safe handling.\nSee Section 8 for information on personal protection equipment.\nSee Section 13 for disposal information.\n7 Handling and storage\n· Handling:\n· Precautions for safe handling\nAny deposit of dust which cannot be avoided must be regularly removed.\nEnsure proper ventilation/exhaustion at workplaces.\nOpen and handle receptacle with care.\n· Information about protection against explosions and fires: No special measures required.\n· Conditions for safe storage, including any incompatibilities\n· Storage:\n· Requirements to be met by storerooms and receptacles:\nStore in a cool location.\nNo special requirements.\n· Information about storage in one common storage facility: Store away from foodstuffs.\n· Further information about storage conditions:\nKeep receptacle tightly sealed.\nStore receptacle in a well ventilated area.\n· Specific end use(s) No further relevant information available.\n8 Exposure controls/personal protection\n· Additional information about design of technical systems: No additional data. See 7.\n· Control parameters\n· Components with limit values that require monitoring at the workplace:\nThe following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.\nAt this time, the other constituents have no known exposure limits.\n1344-28-1 aluminium oxide\nPEL Long-term value: 15*; 5** mg/m³\n*Total dust; ** Respirable fraction\nREL Long-term value: 10* 5** mg/m³\nas Al*Total dust**Respirable/pyro powd./welding f.\nTLV Long-term value: 1* mg/m³\nas Al; *as respirable fraction, A4\n1309-37-1 diiron trioxide\nPEL Long-term value: 10* mg/m³\n*Fume\nREL Long-term value: 5 mg/m³\nDust & fume, as Fe\nTLV Long-term value: 5* mg/m³\n*Respirable particulate matter, A4\n7789-75-5 calcium fluoride\nPEL Long-term value: 2.5 mg/m³\nas F\n(Contd. on page 5)\n\n\nPage 5\nPage 5/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n(Contd. of page 4)\n59.1.0\nREL Long-term value: 2.5 mg/m³\nas F\nTLV Long-term value: 2.5 mg/m³\nas F, A4; BEI\n15096-52-3 cryolite\nPEL Long-term value: 2.5 mg/m³\nas F\nREL Long-term value: 2.5 mg/m³\nas F\n8002-74-2 Paraffin waxes and Hydrocarbon waxes\nREL Long-term value: 2 mg/m³\nTLV Long-term value: 2 mg/m³\n14075-53-7 potassium tetrafluoroborate\nPEL Long-term value: 2.5 mg/m³\nas F\nREL Long-term value: 2.5 mg/m³\nas F\nTLV Long-term value: 2.5 mg/m³\nas F, A4; BEI\n1305-62-0 calcium dihydroxide\nPEL Long-term value: 15* 5** mg/m³\n*total dust **respirable fraction\nREL Long-term value: 5 mg/m³\nTLV Long-term value: 5 mg/m³\n100-97-0 methenamine\nTLV Long-term value: 1 mg/m³\n*inhalable fraction, A4, DSEN\n13463-67-7 titanium dioxide\nPEL Long-term value: 15* mg/m³\n*total dust\nREL See Pocket Guide App. A\nTLV Long-term value: 0.2* 2.5** mg/m³\nresp. fraction, *nanoscale,**finescale, A3\n· Ingredients with biological limit values:\n7789-75-5 calcium fluoride\nBEI 2 mg/L\nMedium: urine\nTime: prior to shift\nParameter: Fluoride (background, nonspecific)\n3 mg/L\nMedium: urine\nTime: end of shift\nParameter: Fluoride (background, nonspecific)\n(Contd. on page 6)\n\n\nPage 6\nPage 6/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n(Contd. of page 5)\n59.1.0\n15096-52-3 cryolite\nBEI 2 mg/L\nMedium: urine\nTime: prior to shift\nParameter: Fluoride (background, nonspecific)\n3 mg/L\nMedium: urine\nTime: end of shift\nParameter: Fluoride (background, nonspecific)\n14075-53-7 potassium tetrafluoroborate\nBEI 2 mg/L\nMedium: urine\nTime: prior to shift\nParameter: Fluoride (background, nonspecific)\n3 mg/L\nMedium: urine\nTime: end of shift\nParameter: Fluoride (background, nonspecific)\n· Exposure controls\n· Personal protective equipment:\n· General protective and hygienic measures:\nKeep away from foodstuffs, beverages and feed.\nImmediately remove all soiled and contaminated clothing.\nWash hands before breaks and at the end of work.\nStore protective clothing separately.\nAvoid contact with the eyes and skin.\n· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.\n· Protection of hands:\nDue to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.\nProtective gloves\nThe glove material has to be impermeable and resistant to the product/ the substance/ the preparation.\nSelection of the glove material on consideration of the penetration times, rates of diffusion and the degradation\n· Material of gloves\nThe selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer\nto manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance\nand has therefore to be checked prior to the application.\n· Eye protection:\nTightly sealed goggles\n9 Physical and chemical properties\n· Information on basic physical and chemical properties\n· General Information\n· Appearance:\nForm:\nSolid\nColor:\nAccording to product specification\n(Contd. on page 7)\n\n\nPage 7\nPage 7/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n(Contd. of page 6)\n59.1.0\n· Odor:\nOdorless\n· Odor threshold:\nNot determined.\n· pH-value:\nNot applicable.\n· Change in condition\nMelting point/Melting range:\nUndetermined.\nBoiling point/Boiling range:\nUndetermined.\n· Flash point:\nNot applicable.\n· Flammability (solid, gaseous):\nNot determined.\n· Decomposition temperature:\nNot determined.\n· Ignition temperature:\nProduct is not selfigniting.\n· Danger of explosion:\nProduct does not present an explosion hazard.\n· Explosion limits:\nLower:\nNot determined.\nUpper:\nNot determined.\n· Vapor pressure:\nNot applicable.\n· Density:\nNot determined.\n· Relative density\nNot determined.\n· Vapor density\nNot applicable.\n· Evaporation rate\nNot applicable.\n· Solubility in / Miscibility with\nWater:\nInsoluble.\n· Partition coefficient (n-octanol/water): Not determined.\n· Viscosity:\nDynamic:\nNot applicable.\nKinematic:\nNot applicable.\n· Solvent content:\nVOC content:\n0.00 %\nSolids content:\n100.0 %\n· Other information\nNo further relevant information available.\n10 Stability and reactivity\n· Reactivity No further relevant information available.\n· Chemical stability\n· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.\n· Possibility of hazardous reactions No dangerous reactions known.\n· Conditions to avoid Keep away from oxidising agents and acidic substances.\n· Incompatible materials: No further relevant information available.\n· Hazardous decomposition products:\nAluminum oxides\nCarbon monoxide and carbon dioxide\n· Additional information: Hazardous decomposition products may form during combustion.\n(Contd. on page 8)\n\n\nPage 8\nPage 8/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n(Contd. of page 7)\n59.1.0\n11 Toxicological information\n· Information on toxicological effects\n· Acute toxicity:\n· LD/LC50 values that are relevant for classification:\nATE (Acute Toxicity Estimate)\nOral\nLD50\n6,024 mg/kg\nInhalative LC50/4 h 20.5 mg/l\n 1344-28-1 aluminium oxide\nOral\nLD50\n>5,000 mg/kg (rat)\nInhalative LC50/4 h >6 mg/l (rat)\n1309-37-1 diiron trioxide\nOral\nLD50\n>5,000 mg/kg (rat)\n7789-75-5 calcium fluoride\nOral\nLD50\n4,250 mg/kg (rat)\n13775-53-6 trisodium hexafluoroaluminate\nInhalative LC50/4 h 1.5 mg/l (ATE)\n15096-52-3 cryolite\nInhalative LC50/4 h 1.5 mg/l (ATE)\n14075-53-7 potassium tetrafluoroborate\nOral\nLD50\n100 mg/kg (ATE)\n1305-62-0 calcium dihydroxide\nOral\nLD50\n7,340 mg/kg (rat)\n13463-67-7 titanium dioxide\nOral\nLD50\n>20,000 mg/kg (rat)\nDermal\nLD50\n>10,000 mg/kg (rabbit)\nInhalative LC50/4 h >6.82 mg/l (rat)\n25104-55-6 Formaldehyde, polymer with phenol and urea\nOral\nLD50\n5,000 mg/kg (rat)\nDermal\nLD50\n2,000 mg/kg (rat)\n· Primary chemical irritant effect:\n· on the skin: Irritant to skin and mucous membranes.\n· on the eye: Irritating effect.\n· Sensitization: Sensitization possible through skin contact.\n· Additional toxicological information:\nAbrasive skin irritant\nAbrasive eye irritant\n· Carcinogenic categories\n· IARC (International Agency for Research on Cancer)\n1309-37-1 diiron trioxide\n3 \n7789-75-5 calcium fluoride\n3 \n14075-53-7 potassium tetrafluoroborate\n3 \n13463-67-7 titanium dioxide\n2B\n· NTP (National Toxicology Program)\nNone of the ingredients is listed.\n(Contd. on page 9)\n\n\nPage 9\nPage 9/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n(Contd. of page 8)\n59.1.0\n· OSHA-Ca (Occupational Safety & Health Administration)\nNone of the ingredients is listed.\n12 Ecological information\n· Toxicity\n· Aquatic toxicity: No further relevant information available.\n· Persistence and degradability No further relevant information available.\n· Behavior in environmental systems:\n· Bioaccumulative potential No further relevant information available.\n· Mobility in soil No further relevant information available.\n· Ecotoxical effects:\n· Remark: Harmful to fish\n· Additional ecological information:\n· General notes:\nDo not allow product to reach ground water, water course or sewage system, even in small quantities.\nDanger to drinking water if even extremely small quantities leak into the ground.\nHarmful to aquatic organisms\n· Results of PBT and vPvB assessment\n· PBT: Not applicable.\n· vPvB: Not applicable.\n· Other adverse effects No further relevant information available.\n13 Disposal considerations\n· Waste treatment methods\n· Recommendation: Contact waste processors for recycling information.\n· Uncleaned packagings:\n· Recommendation: Disposal must be made according to official regulations.\n14 Transport information\n· UN-Number\n· DOT, ADN, IMDG, IATA\nnot regulated\n· UN proper shipping name\n· DOT, ADN, IMDG, IATA\nnot regulated\n· Transport hazard class(es)\n· DOT, ADN, IMDG, IATA\n· Class\nnot regulated\n· Packing group\n· DOT, IMDG, IATA\nnot regulated\n· Environmental hazards:\n· Marine pollutant:\nNo\n· Special precautions for user\nNot applicable.\n· Transport in bulk according to Annex II of MARPOL73/78 and\nthe IBC Code\nNot applicable.\n· UN "Model Regulation":\nnot regulated\n15 Regulatory information\n· Safety, health and environmental regulations/legislation specific for the substance or mixture\nNo further relevant information available.\n(Contd. on page 10)\n\n\nPage 10\nPage 10/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n(Contd. of page 9)\n59.1.0\n· Sara\n· Section 355 (extremely hazardous substances):\nNone of the ingredients is listed.\n· Section 313 (Specific toxic chemical listings):\n1344-28-1 aluminium oxide\n1314-98-3 zinc sulphide\n· TSCA (Toxic Substances Control Act):\nAll components have the value ACTIVE.\n· Hazardous Air Pollutants\nNone of the ingredients is listed.\n· Proposition 65\n· Chemicals known to cause cancer:\n13463-67-7 titanium dioxide\n· Chemicals known to cause reproductive toxicity for females:\nNone of the ingredients is listed.\n· Chemicals known to cause reproductive toxicity for males:\nNone of the ingredients is listed.\n· Chemicals known to cause developmental toxicity:\nNone of the ingredients is listed.\n· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.\n16 Other information\nTo the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties\nand does not establish a contractual legal relationship.\n· Department issuing SDS: Technical Services\n· Contact: Pablo Mendoza\n· Last revision / supersedes version: 06/01/2024 / 3.0\n· Supersedes date: 06/01/2022\n· Abbreviations and acronyms:\nADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by\nRoad)\nIMDG: International Maritime Code for Dangerous Goods\nDOT: US Department of Transportation\nIATA: International Air Transport Association\nEINECS: European Inventory of Existing Commercial Chemical Substances\nELINCS: European List of Notified Chemical Substances\nCAS: Chemical Abstracts Service (division of the American Chemical Society)\nVOC: Volatile Organic Compounds (USA, EU)\nLC50: Lethal concentration, 50 percent\nLD50: Lethal dose, 50 percent\nPBT: Persistent, Bioaccumulative and Toxic\nvPvB: very Persistent and very Bioaccumulative\nOSHA: Occupational Safety & Health\nTLV: Threshold Limit Value\nPEL: Permissible Exposure Limit\nREL: Recommended Exposure Limit\nBEI: Biological Exposure Limit\nFlammable Solids 2: Flammable solids – Category 2\nAcute Toxicity - Oral 3: Acute toxicity – Category 3\nAcute Toxicity - Inhalation 4: Acute toxicity – Category 4\nSkin Corrosion 1B: Skin corrosion/irritation – Category 1B\nSkin Irritation 2: Skin corrosion/irritation – Category 2\nEye Damage 1: Serious eye damage/eye irritation – Category 1\nEye Irritation 2A: Serious eye damage/eye irritation – Category 2A\nSensitization - Skin 1: Skin sensitisation – Category 1\nSensitization - Skin 1B: Skin sensitisation – Category 1B\nCarcinogenicity 2: Carcinogenicity – Category 2\nSpecific Target Organ Toxicity - Repeated Exposure 1: Specific target organ toxicity (repeated exposure) – Category 1\n(Contd. on page 11)\n\n\nPage 11\nPage 11/11\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Cut-Off & Wafering Blades, Resin Bond\n(Contd. of page 10)\n59.1.0\nAquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2\nAquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3\n· * Data compared to the previous version altered. \n