Aluminum Oxide Grinding Stones
Also listed as: ALUMINUM OXIDE GRINDING STONE SAFETY DATA SHEET
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Page 1\n \nPage 1/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\n59.1.0\n* 1 Identification\n· Product name: Aluminum Oxide Grinding Stone\n· Part number: 81-10900, 80-10920\n· Application of the substance / the mixture Abrasive\n· Details of the supplier of the safety data sheet\n· Manufacturer/Supplier:\nAllied High Tech Products Inc.\n16207 Carmenita Road\nUSA-Cerritos, CA, 90703\nUSA\ninfo@alliedhightech.com\n· Information department: Product safety department\n· Emergency telephone number:\nDuring normal opening times: +1 (310) 635-2466\nChemtrec: +1 (202) 483-7616\n2 Hazard(s) identification\n· Classification of the substance or mixture\nGHS08 Health hazard\nCarcinogenicity 1A H350 May cause cancer. Route of exposure: Inhalation.\n· Additional information:\nAll components listed for this product are bound within the product. When handled as intended and under normal conditions of use, there is\nno evidence that any of the ingredients are released in amounts that pose a significant health risk.\n· Label elements\n· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).\n· Hazard pictograms\nGHS08\n· Signal word Danger\n· Hazard-determining components of labeling:\nQuartz (SiO2)\ntitanium dioxide\n· Hazard statements\nMay cause cancer. Route of exposure: Inhalation.\n· Precautionary statements\nObtain special instructions before use.\n(Contd. on page 2)\n\n\nPage 2\nPage 2/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Grinding Stone\n(Contd. of page 1)\n59.1.0\nDo not handle until all safety precautions have been read and understood.\nWear protective gloves/protective clothing/eye protection/face protection.\nIF exposed or concerned: Get medical advice/attention.\nStore locked up.\nDispose of contents/container in accordance with local/regional/national/international regulations.\n* 3 Composition/information on ingredients\n· Chemical characterization: Mixtures\n· Description: Mixture of the substances listed below with nonhazardous additions.\n· Hazardous components and components with occupational exposure limits:\n1344-28-1 aluminium oxide\n≤95%\n13463-67-7 titanium dioxide\n Carcinogenicity 2, H351\n≤1%\n14808-60-7 Quartz (SiO2)\n Carcinogenicity 1A, H350\n≤1%\n· Non-hazardous components:\nGlass or glass porcelain\n≤40%\nUnknown\n≤35%\n· Additional information:\nUnknown ingredient may contain concentrations of one of the following treatments: sulfur, paraffin or resin.\nThe specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.\n4 First-aid measures\n· Description of first aid measures\n· After inhalation: Supply fresh air; consult doctor in case of complaints.\n· After skin contact: Generally the product does not irritate the skin.\n· After eye contact: Rinse opened eye for several minutes under running water.\n· After swallowing: If symptoms persist consult doctor.\n· Information for doctor:\n· Most important symptoms and effects, both acute and delayed\nBreathing difficulty\nEye irritation\nCoughing\nDermatitis\n· Indication of any immediate medical attention and special treatment needed No further relevant information available.\n5 Fire-fighting measures\n· Extinguishing media\n· Suitable extinguishing agents: Use fire fighting measures that suit the environment.\n· Special hazards arising from the substance or mixture No further relevant information available.\n· Advice for firefighters\n· Protective equipment: No special measures required.\n6 Accidental release measures\n· Personal precautions, protective equipment and emergency procedures Not required.\n· Environmental precautions: No special measures required.\n· Methods and material for containment and cleaning up:\nPick up mechanically.\nDispose contaminated material as waste according to section 13.\nEnsure adequate ventilation.\n· Reference to other sections\nSee Section 7 for information on safe handling.\nSee Section 8 for information on personal protection equipment.\nSee Section 13 for disposal information.\n(Contd. on page 3)\n\n\nPage 3\nPage 3/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Grinding Stone\n(Contd. of page 2)\n59.1.0\n7 Handling and storage\n· Handling:\n· Precautions for safe handling\nEnsure proper ventilation/exhaustion at workplaces.\nOpen and handle receptacle with care.\n· Information about protection against explosions and fires: No special measures required.\n· Conditions for safe storage, including any incompatibilities\n· Storage:\n· Requirements to be met by storerooms and receptacles:\nStore in a cool location.\nNo special requirements.\n· Information about storage in one common storage facility: Not required.\n· Further information about storage conditions:\nKeep receptacle tightly sealed.\nStore receptacle in a well ventilated area.\n· Specific end use(s) No further relevant information available.\n8 Exposure controls/personal protection\n· Additional information about design of technical systems: No additional data. See 7.\n· Control parameters\n· Components with limit values that require monitoring at the workplace:\n1344-28-1 aluminium oxide\nPEL Long-term value: 15*; 5** mg/m³\n*Total dust; ** Respirable fraction\nREL Long-term value: 10* 5** mg/m³\nas Al*Total dust**Respirable/pyro powd./welding f.\nTLV Long-term value: 1* mg/m³\nas Al; *as respirable fraction, A4\n13463-67-7 titanium dioxide\nPEL Long-term value: 15* mg/m³\n*total dust\nREL See Pocket Guide App. A\nTLV Long-term value: 0.2* 2.5** mg/m³\nresp. fraction, *nanoscale,**finescale, A3\n14808-60-7 Quartz (SiO2)\nPEL Long-term value: 0.05* mg/m³\n*resp. dust; 30mg/m3/%SiO2+2\nREL Long-term value: 0.05* mg/m³\n*respirable dust; See Pocket Guide App. A\nTLV Long-term value: 0.025* mg/m³\n*respirable particulate matter, A2\n· Exposure controls\n· Personal protective equipment:\n· General protective and hygienic measures:\nKeep away from foodstuffs, beverages and feed.\nWash hands before breaks and at the end of work.\nStore protective clothing separately.\n· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.\n(Contd. on page 4)\n\n\nPage 4\nPage 4/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Grinding Stone\n(Contd. of page 3)\n59.1.0\n· Protection of hands:\nProtective gloves\nThe glove material has to be impermeable and resistant to the product/ the substance/ the preparation.\nSelection of the glove material on consideration of the penetration times, rates of diffusion and the degradation\n· Material of gloves\nLeather gloves\nThe selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer\nto manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance\nand has therefore to be checked prior to the application.\n· Eye protection:\nTightly sealed goggles\n9 Physical and chemical properties\n· Information on basic physical and chemical properties\n· General Information\n· Appearance:\nForm:\nSolid\nColor:\nGrey\n· Odor:\nLight\n· Odor threshold:\nNot determined.\n· pH-value:\nNot applicable.\n· Change in condition\nMelting point/Melting range:\nUndetermined.\nBoiling point/Boiling range:\nUndetermined.\n· Flash point:\nNot applicable.\n· Flammability (solid, gaseous):\nNot determined.\n· Decomposition temperature:\nNot determined.\n· Ignition temperature:\nProduct is not selfigniting.\n· Danger of explosion:\nProduct does not present an explosion hazard.\n· Explosion limits:\nLower:\nNot determined.\nUpper:\nNot determined.\n· Vapor pressure:\nNot applicable.\n· Density at 20 °C (68 °F):\n1.5-3.1 g/cm³ (12.518-25.87 lbs/gal)\n· Relative density\nNot determined.\n· Vapor density\nNot applicable.\n· Evaporation rate\nNot applicable.\n· Solubility in / Miscibility with\nWater:\nSlightly soluble.\n· Partition coefficient (n-octanol/water): Not determined.\n· Viscosity:\nDynamic:\nNot applicable.\n(Contd. on page 5)\n\n\nPage 5\nPage 5/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Grinding Stone\n(Contd. of page 4)\n59.1.0\nKinematic:\nNot applicable.\n· Solvent content:\nVOC content:\n0.00 %\nSolids content:\n100.0 %\n· Other information\nNo further relevant information available.\n10 Stability and reactivity\n· Reactivity No further relevant information available.\n· Chemical stability\n· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.\n· Possibility of hazardous reactions No dangerous reactions known.\n· Conditions to avoid\nKeep away from oxidising agents and acidic substances.\nKeep away from alkaline solutions.\n· Incompatible materials: No further relevant information available.\n· Hazardous decomposition products: No dangerous decomposition products known.\n11 Toxicological information\n· Information on toxicological effects\n· Acute toxicity:\n· LD/LC50 values that are relevant for classification:\n1344-28-1 aluminium oxide\nOral\nLD50\n>5,000 mg/kg (rat)\nInhalative LC50/4 h >6 mg/l (rat)\n13463-67-7 titanium dioxide\nOral\nLD50\n>20,000 mg/kg (rat)\nDermal\nLD50\n>10,000 mg/kg (rabbit)\nInhalative LC50/4 h >6.82 mg/l (rat)\n· Primary chemical irritant effect:\n· on the skin: No irritant effect.\n· on the eye: No irritating effect.\n· Sensitization: No sensitizing effects known.\n· Additional toxicological information:\nAbrasive skin irritant\nAbrasive eye irritant\n· Carcinogenic categories\n· IARC (International Agency for Research on Cancer)\n13463-67-7 titanium dioxide\n2B\n14808-60-7 Quartz (SiO2)\n1 \n· NTP (National Toxicology Program)\n14808-60-7 Quartz (SiO2)\nK \n· OSHA-Ca (Occupational Safety & Health Administration)\nNone of the ingredients is listed.\n12 Ecological information\n· Toxicity\n· Aquatic toxicity: No further relevant information available.\n· Persistence and degradability No further relevant information available.\n(Contd. on page 6)\n\n\nPage 6\nPage 6/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Grinding Stone\n(Contd. of page 5)\n59.1.0\n· Behavior in environmental systems:\n· Bioaccumulative potential No further relevant information available.\n· Mobility in soil No further relevant information available.\n· Additional ecological information:\n· General notes: Not hazardous for water.\n· Results of PBT and vPvB assessment\n· PBT: Not applicable.\n· vPvB: Not applicable.\n· Other adverse effects No further relevant information available.\n13 Disposal considerations\n· Waste treatment methods\n· Recommendation: Contact waste processors for recycling information.\n· Uncleaned packagings:\n· Recommendation: Disposal must be made according to official regulations.\n14 Transport information\n· UN-Number\n· DOT, ADN, IMDG, IATA\nnot regulated\n· UN proper shipping name\n· DOT, ADN, IMDG, IATA\nnot regulated\n· Transport hazard class(es)\n· DOT, ADN, IMDG, IATA\n· Class\nnot regulated\n· Packing group\n· DOT, IMDG, IATA\nnot regulated\n· Environmental hazards:\n· Marine pollutant:\nNo\n· Special precautions for user\nNot applicable.\n· Transport in bulk according to Annex II of MARPOL73/78 and\nthe IBC Code\nNot applicable.\n· UN "Model Regulation":\nnot regulated\n15 Regulatory information\n· Safety, health and environmental regulations/legislation specific for the substance or mixture\n· Sara\n· Section 355 (extremely hazardous substances):\nNone of the ingredients is listed.\n· Section 313 (Specific toxic chemical listings):\n1344-28-1 aluminium oxide\n· TSCA (Toxic Substances Control Act):\nAll components have the value ACTIVE.\n· Hazardous Air Pollutants\nNone of the ingredients is listed.\n· Proposition 65\n· Chemicals known to cause cancer:\n13463-67-7 titanium dioxide\n(Contd. on page 7)\n\n\nPage 7\nPage 7/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Aluminum Oxide Grinding Stone\n(Contd. of page 6)\n59.1.0\n14808-60-7 Quartz (SiO2)\n· Chemicals known to cause reproductive toxicity for females:\nNone of the ingredients is listed.\n· Chemicals known to cause reproductive toxicity for males:\nNone of the ingredients is listed.\n· Chemicals known to cause developmental toxicity:\nNone of the ingredients is listed.\n· National regulations:\n· Information about limitation of use:\nWorkers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the\nauthorities in certain cases.\n· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.\n16 Other information\nTo the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties\nand does not establish a contractual legal relationship.\n· Department issuing SDS: Technical Services\n· Contact: Pablo Mendoza\n· Last revision / supersedes version: 06/01/2024 / 3.0\n· Supersedes date: 06/01/2022\n· Abbreviations and acronyms:\nADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by\nRoad)\nIMDG: International Maritime Code for Dangerous Goods\nDOT: US Department of Transportation\nIATA: International Air Transport Association\nEINECS: European Inventory of Existing Commercial Chemical Substances\nELINCS: European List of Notified Chemical Substances\nCAS: Chemical Abstracts Service (division of the American Chemical Society)\nVOC: Volatile Organic Compounds (USA, EU)\nLC50: Lethal concentration, 50 percent\nLD50: Lethal dose, 50 percent\nPBT: Persistent, Bioaccumulative and Toxic\nvPvB: very Persistent and very Bioaccumulative\nOSHA: Occupational Safety & Health\nTLV: Threshold Limit Value\nPEL: Permissible Exposure Limit\nREL: Recommended Exposure Limit\nCarcinogenicity 1A: Carcinogenicity – Category 1A\nCarcinogenicity 2: Carcinogenicity – Category 2\n· * Data compared to the previous version altered. \n