Diamond Slurry - Polycrystalline
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Page 1\n \nPage 1/8\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\n59.1.0\n* 1 Identification\n· Product name: Diamond Slurry, Polycrystalline, 0.05 and 0.1 microns\n· Part number: 90-22995-S - 90-23000-S\n· Application of the substance / the mixture Polishing solution\n· Details of the supplier of the safety data sheet\n· Manufacturer/Supplier:\nAllied High Tech Products Inc.\n16207 Carmenita Road\nUSA-Cerritos, CA, 90703\nUSA\ninfo@alliedhightech.com\n· Information department: Product safety department\n· Emergency telephone number:\nDuring normal opening times: +1 (310) 635-2466\nChemtrec: +1 (202) 483-7616\n2 Hazard(s) identification\n· Classification of the substance or mixture\nGHS07\nAcute Toxicity - Inhalation 4 H332 Harmful if inhaled.\nSensitization - Skin 1\nH317 May cause an allergic skin reaction.\nFlammable Liquids 4\nH227 Combustible liquid.\n· Label elements\n· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).\n· Hazard pictograms\nGHS07\n· Signal word Warning\n· Hazard-determining components of labeling:\nFumd Silica, Crystalline Free\nethylene glycol monobutyl ether\nmequinol\n· Hazard statements\nCombustible liquid.\nHarmful if inhaled.\n(Contd. on page 2)\n\n\nPage 2\nPage 2/8\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Diamond Slurry, Polycrystalline, 0.05 and 0.1 microns\n(Contd. of page 1)\n59.1.0\nMay cause an allergic skin reaction.\n· Precautionary statements\nKeep away from flames and hot surfaces. – No smoking.\nAvoid breathing dust/fume/gas/mist/vapors/spray\nUse only outdoors or in a well-ventilated area.\nContaminated work clothing must not be allowed out of the workplace.\nWear protective gloves/protective clothing/eye protection/face protection.\nIf on skin: Wash with plenty of water.\nIF INHALED: Remove person to fresh air and keep comfortable for breathing.\nCall a poison center/doctor if you feel unwell.\nSpecific treatment (see on this label).\nIf skin irritation or rash occurs: Get medical advice/attention.\nWash contaminated clothing before reuse.\nIn case of fire: Use CO2, powder or water spray to extinguish.\nStore in a well-ventilated place. Keep cool.\nDispose of contents/container in accordance with local/regional/national/international regulations.\n* 3 Composition/information on ingredients\n· Chemical characterization: Mixtures\n· Description: Mixture of the substances listed below with nonhazardous additions.\n· Hazardous components and components with occupational exposure limits:\n112945-52-5 Fumd Silica, Crystalline Free\n Acute Toxicity - Inhalation 3, H331\n1-5%\n150-76-5 mequinol\n Acute Toxicity - Oral 4, H302; Eye Irritation 2A, H319; Sensitization - Skin 1, H317\n0.1-<1%\n111-76-2 ethylene glycol monobutyl ether\n Acute Toxicity - Dermal 3, H311; Acute Toxicity - Inhalation 3, H331;\n Acute Toxicity - Oral 4, H302; Skin\nIrritation 2, H315; Eye Irritation 2A, H319; Flammable Liquids 4, H227\n≤1%\n· Non-hazardous components:\n9038-95-3 polyalkylene glycol monobutyl ether\n90-100%\n9005-65-6 Lubricant\n1-5%\n7782-40-3 Diamond\n≤1%\n· Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.\n4 First-aid measures\n· Description of first aid measures\n· General information:\nSymptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.\n· After inhalation:\nSupply fresh air and to be sure call for a doctor.\nIn case of unconsciousness place patient stably in side position for transportation.\n· After skin contact: Immediately wash with water and soap and rinse thoroughly.\n· After eye contact: Rinse opened eye for several minutes under running water.\n· After swallowing: If symptoms persist consult doctor.\n· Information for doctor:\n· Most important symptoms and effects, both acute and delayed\nGastric or intestinal disorders\nBreathing difficulty\nCoughing\nAllergic reactions\nDermatitis\n· Indication of any immediate medical attention and special treatment needed No further relevant information available.\n(Contd. on page 3)\n\n\nPage 3\nPage 3/8\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Diamond Slurry, Polycrystalline, 0.05 and 0.1 microns\n(Contd. of page 2)\n59.1.0\n5 Fire-fighting measures\n· Extinguishing media\n· Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.\n· Special hazards arising from the substance or mixture No further relevant information available.\n· Advice for firefighters\n· Protective equipment: Wear fully protective suit.\n6 Accidental release measures\n· Personal precautions, protective equipment and emergency procedures\nEnsure adequate ventilation\nKeep away from ignition sources\n· Environmental precautions:\nDo not allow to enter sewers/ surface or ground water.\nDilute with plenty of water.\n· Methods and material for containment and cleaning up:\nAbsorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).\nDispose contaminated material as waste according to section 13.\nEnsure adequate ventilation.\n· Reference to other sections\nSee Section 7 for information on safe handling.\nSee Section 8 for information on personal protection equipment.\nSee Section 13 for disposal information.\n7 Handling and storage\n· Handling:\n· Precautions for safe handling\nProtect from heat and direct sunlight.\nEnsure proper ventilation/exhaustion at workplaces.\nPrevent formation of aerosols.\n· Information about protection against explosions and fires: No special measures required.\n· Conditions for safe storage, including any incompatibilities\n· Storage:\n· Requirements to be met by storerooms and receptacles:\nStore in a cool location.\nNo special requirements.\n· Information about storage in one common storage facility: Not required.\n· Further information about storage conditions:\nKeep receptacle tightly sealed.\nStore receptacle in a well ventilated area.\n· Specific end use(s) No further relevant information available.\n8 Exposure controls/personal protection\n· Additional information about design of technical systems: No additional data. See 7.\n· Control parameters\n· Components with limit values that require monitoring at the workplace:\n112945-52-5 Fumd Silica, Crystalline Free\nTWA Long-term value: 0.8 mg/m³\n150-76-5 mequinol\nREL\nLong-term value: 5 mg/m³\nTLV\nLong-term value: 5 mg/m³\n(Contd. on page 4)\n\n\nPage 4\nPage 4/8\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Diamond Slurry, Polycrystalline, 0.05 and 0.1 microns\n(Contd. of page 3)\n59.1.0\n111-76-2 ethylene glycol monobutyl ether\nPEL\nLong-term value: 240 mg/m³, 50 ppm\nSkin\nREL\nLong-term value: 24 mg/m³, 5 ppm\nSkin\nTLV\nLong-term value: 20 ppm\nBEI, A3\n· Ingredients with biological limit values:\n111-76-2 ethylene glycol monobutyl ether\nBEI 200 mg/g creatinine\nMedium: urine\nTime: end of shift\nParameter: Butoxyacetic acid (BAA) (with hydrolysis)\n· Exposure controls\n· Personal protective equipment:\n· General protective and hygienic measures:\nImmediately remove all soiled and contaminated clothing.\nWash hands before breaks and at the end of work.\n· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.\n· Protection of hands:\nProtective gloves\nThe glove material has to be impermeable and resistant to the product/ the substance/ the preparation.\nSelection of the glove material on consideration of the penetration times, rates of diffusion and the degradation\n· Material of gloves\nButyl rubber, BR\nThe selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer\nto manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance\nand has therefore to be checked prior to the application.\n· Eye protection: Goggles recommended during refilling.\n9 Physical and chemical properties\n· Information on basic physical and chemical properties\n· General Information\n· Appearance:\nForm:\nSolution\nColor:\nYellowish\n· Odor:\nMild\n· Odor threshold:\nNot determined.\n· pH-value:\nNot determined.\n· Change in condition\nMelting point/Melting range:\n-9.4 °C (15.1 °F)\nBoiling point/Boiling range:\n171.1 °C (340 °F)\n· Flash point:\n90 °C (194 °F)\n· Flammability (solid, gaseous):\nNot applicable.\n· Decomposition temperature:\nNot determined.\n· Ignition temperature:\nProduct is not selfigniting.\n(Contd. on page 5)\n\n\nPage 5\nPage 5/8\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Diamond Slurry, Polycrystalline, 0.05 and 0.1 microns\n(Contd. of page 4)\n59.1.0\n· Danger of explosion:\nNot determined.\n· Explosion limits:\nLower:\nNot determined.\nUpper:\nNot determined.\n· Vapor pressure:\nNot determined.\n· Density:\nNot determined.\n· Relative density\nNot determined.\n· Vapor density\n1\n· Evaporation rate\nNot determined.\n· Solubility in / Miscibility with\nWater:\nNot miscible or difficult to mix.\n· Partition coefficient (n-octanol/water): Not determined.\n· Viscosity:\nDynamic:\nNot determined.\nKinematic:\nNot determined.\n· Solvent content:\nOrganic solvents:\n0.2 %\nVOC content:\n0.19 %\nSolids content:\n97.6 %\n· Other information\nNo further relevant information available.\n10 Stability and reactivity\n· Reactivity No further relevant information available.\n· Chemical stability\n· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.\n· Possibility of hazardous reactions No dangerous reactions known.\n· Conditions to avoid\nAlkaline earth metals\nKeep away from oxidising agents and acidic substances.\nExcessive heat\n· Incompatible materials: No further relevant information available.\n· Hazardous decomposition products: Carbon monoxide and carbon dioxide\n· Additional information: Hazardous decomposition products may form during combustion.\n11 Toxicological information\n· Information on toxicological effects\n· Acute toxicity:\n· LD/LC50 values that are relevant for classification:\nATE (Acute Toxicity Estimate)\nDermal\nLD50\n215,750 mg/kg (rabbit)\nInhalative LC50/4 h >14.7 mg/l\n 112945-52-5 Fumd Silica, Crystalline Free\nOral\nLD50\n>5,110 mg/kg (rat)\nDermal\nLD50\n>5,000 mg/kg (rabbit)\nInhalative LC50/4 h >0.691 mg/l (rat)\n150-76-5 mequinol\nOral\nLD50\n1,600 mg/kg (rat)\n(Contd. on page 6)\n\n\nPage 6\nPage 6/8\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Diamond Slurry, Polycrystalline, 0.05 and 0.1 microns\n(Contd. of page 5)\n59.1.0\nDermal\nLD50\n5,010 mg/kg (rat)\n111-76-2 ethylene glycol monobutyl ether\nOral\nLD50\n1,200 mg/kg (ATE)\n1,480 mg/kg (rat)\nDermal\nLD50\n400 mg/kg (rabbit)\nInhalative LC50/4 h 3 mg/l (ATE)\n2.2 mg/l (rat)\n· Primary chemical irritant effect:\n· on the skin: No irritant effect.\n· on the eye: No irritating effect.\n· Sensitization: Sensitization possible through skin contact.\n· Additional toxicological information:\n· Carcinogenic categories\n· IARC (International Agency for Research on Cancer)\n111-76-2 ethylene glycol monobutyl ether\n3 \n· NTP (National Toxicology Program)\nNone of the ingredients is listed.\n· OSHA-Ca (Occupational Safety & Health Administration)\nNone of the ingredients is listed.\n12 Ecological information\n· Toxicity\n· Aquatic toxicity:\n111-76-2 ethylene glycol monobutyl ether\nEC50 (48 h) (static) 1,550 mg/l (daphnia)\n· Persistence and degradability No further relevant information available.\n· Behavior in environmental systems:\n· Bioaccumulative potential No further relevant information available.\n· Mobility in soil No further relevant information available.\n· Additional ecological information:\n· General notes:\nWater hazard class 1 (Self-assessment): slightly hazardous for water\nDo not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.\n· Results of PBT and vPvB assessment\n· PBT: Not applicable.\n· vPvB: Not applicable.\n· Other adverse effects No further relevant information available.\n13 Disposal considerations\n· Waste treatment methods\n· Recommendation: Contact waste processors for recycling information.\n· Uncleaned packagings:\n· Recommendation: Disposal must be made according to official regulations.\n14 Transport information\n· UN-Number\n· DOT, ADN, IMDG, IATA\nnot regulated\n(Contd. on page 7)\n\n\nPage 7\nPage 7/8\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Diamond Slurry, Polycrystalline, 0.05 and 0.1 microns\n(Contd. of page 6)\n59.1.0\n· UN proper shipping name\n· DOT, ADN, IMDG, IATA\nnot regulated\n· Transport hazard class(es)\n· DOT, ADN, IMDG, IATA\n· Class\nnot regulated\n· Packing group\n· DOT, IMDG, IATA\nnot regulated\n· Environmental hazards:\n· Marine pollutant:\nNo\n· Special precautions for user\nNot applicable.\n· Transport in bulk according to Annex II of MARPOL73/78 and\nthe IBC Code\nNot applicable.\n· UN "Model Regulation":\nnot regulated\n15 Regulatory information\n· Safety, health and environmental regulations/legislation specific for the substance or mixture\nNo further relevant information available.\n· Sara\n· Section 355 (extremely hazardous substances):\nNone of the ingredients is listed.\n· Section 313 (Specific toxic chemical listings):\n111-76-2 ethylene glycol monobutyl ether\n· TSCA (Toxic Substances Control Act):\nAll components have the value ACTIVE.\n· Hazardous Air Pollutants\nNone of the ingredients is listed.\n· Proposition 65\n· Chemicals known to cause cancer:\nNone of the ingredients is listed.\n· Chemicals known to cause reproductive toxicity for females:\nNone of the ingredients is listed.\n· Chemicals known to cause reproductive toxicity for males:\nNone of the ingredients is listed.\n· Chemicals known to cause developmental toxicity:\nNone of the ingredients is listed.\n· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.\n16 Other information\nTo the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties\nand does not establish a contractual legal relationship.\n· Department issuing SDS: Technical Services\n· Contact: Pablo Mendoza\n· Last revision / supersedes version: 06/01/2024 / 3.0\n· Supersedes date: 06/01/2022\n· Abbreviations and acronyms:\nADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by\nRoad)\nIMDG: International Maritime Code for Dangerous Goods\n(Contd. on page 8)\n\n\nPage 8\nPage 8/8\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Diamond Slurry, Polycrystalline, 0.05 and 0.1 microns\n(Contd. of page 7)\n59.1.0\nDOT: US Department of Transportation\nIATA: International Air Transport Association\nEINECS: European Inventory of Existing Commercial Chemical Substances\nELINCS: European List of Notified Chemical Substances\nCAS: Chemical Abstracts Service (division of the American Chemical Society)\nVOC: Volatile Organic Compounds (USA, EU)\nLC50: Lethal concentration, 50 percent\nLD50: Lethal dose, 50 percent\nPBT: Persistent, Bioaccumulative and Toxic\nvPvB: very Persistent and very Bioaccumulative\nOSHA: Occupational Safety & Health\nTLV: Threshold Limit Value\nPEL: Permissible Exposure Limit\nREL: Recommended Exposure Limit\nBEI: Biological Exposure Limit\nFlammable Liquids 4: Flammable liquids – Category 4\nAcute Toxicity - Oral 4: Acute toxicity – Category 4\nAcute Toxicity - Inhalation 3: Acute toxicity – Category 3\nSkin Irritation 2: Skin corrosion/irritation – Category 2\nEye Irritation 2A: Serious eye damage/eye irritation – Category 2A\nSensitization - Skin 1: Skin sensitisation – Category 1\n· * Data compared to the previous version altered. \n