Loc-Tite 454 Sample Bonding Glue
Also listed as: LOC-TITE 454 SAFETY DATA SHEET
Refer to the original PDF for tables, figures and page layout.
Page 1\n \nPage 1/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 2.0\n59.1.0\n* 1 Identification\n· Product name: LOCTITE® 454™ Gel Adhesive\n· Part number: 71-40045G\n· Application of the substance / the mixture Adhesives\n· Details of the supplier of the safety data sheet\n· Manufacturer/Supplier:\nAllied High Tech Products Inc.\n16207 Carmenita Road\nUSA-Cerritos, CA, 90703\nUSA\ninfo@alliedhightech.com\n· Information department: Product safety department\n· Emergency telephone number:\nDuring normal opening times: +1 (310) 635-2466\nChemtrec: +1 (202) 483-7616\n* 2 Hazard(s) identification\n· Classification of the substance or mixture\nGHS07\nSkin Irritation 2\nH315 Causes skin irritation.\nEye Irritation 2A\nH319 Causes serious eye irritation.\nSpecific Target Organ Toxicity - Single Exposure 3 H335 May cause respiratory irritation.\nFlammable Liquids 4\nH227 Combustible liquid.\n· Label elements\n· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).\n· Hazard pictograms\nGHS07\n· Signal word Warning\n· Hazard-determining components of labeling:\nethyl 2-cyanoacrylate\n· Hazard statements\nCombustible liquid.\nCauses skin irritation.\nCauses serious eye irritation.\n(Contd. on page 2)\n\n\nPage 2\nPage 2/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 2.0\nProduct name: LOCTITE® 454™ Gel Adhesive\n(Contd. of page 1)\n59.1.0\nMay cause respiratory irritation.\n· Precautionary statements\nKeep away from flames and hot surfaces. – No smoking.\nAvoid breathing dust/fume/gas/mist/vapors/spray\nWash thoroughly after handling.\nUse only outdoors or in a well-ventilated area.\nWear protective gloves/protective clothing/eye protection/face protection.\nIf on skin: Wash with plenty of water.\nIF INHALED: Remove person to fresh air and keep comfortable for breathing.\nIf in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.\nCall a poison center/doctor if you feel unwell.\nSpecific treatment (see on this label).\nTake off contaminated clothing and wash it before reuse.\nIf skin irritation occurs: Get medical advice/attention.\nIf eye irritation persists: Get medical advice/attention.\nIn case of fire: Use CO2, powder or water spray to extinguish.\nStore in a well-ventilated place. Keep container tightly closed.\nStore in a well-ventilated place. Keep cool.\nStore locked up.\nDispose of contents/container in accordance with local/regional/national/international regulations.\n* 3 Composition/information on ingredients\n· Chemical characterization: Mixtures\n· Description: Mixture of the substances listed below with nonhazardous additions.\n· Hazardous components and components with occupational exposure limits:\n7085-85-0 ethyl 2-cyanoacrylate\n Skin Irritation 2, H315; Eye Irritation 2A, H319; Specific Target Organ Toxicity - Single Exposure 3, H335\n70-100%\n· Non-hazardous components:\n67762-90-7 Treated fumed silica\n1-10%\n· Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.\n4 First-aid measures\n· Description of first aid measures\n· General information: Immediately remove any clothing soiled by the product.\n· After inhalation: In case of unconsciousness place patient stably in side position for transportation.\n· After skin contact:\nIf skin is bonded, immediately wash with water and soap and rinse thoroughly.\nImmediately wash with water and soap and rinse thoroughly.\n· After eye contact:\nIf eyelids are bonded, immediately wash with warm water. Do not force eye open. Eye proteins will help to debond the adhesive. Keep eye\ncovered until the debonding is complete, usually within 1-3 days.\nRinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.\n· After swallowing: If symptoms persist consult doctor.\n· Information for doctor:\n· Most important symptoms and effects, both acute and delayed\nDizziness\nNausea\nDermatitis\nEye irritation\n· Indication of any immediate medical attention and special treatment needed No further relevant information available.\n5 Fire-fighting measures\n· Extinguishing media\n· Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.\n· Special hazards arising from the substance or mixture No further relevant information available.\n(Contd. on page 3)\n\n\nPage 3\nPage 3/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 2.0\nProduct name: LOCTITE® 454™ Gel Adhesive\n(Contd. of page 2)\n59.1.0\n· Advice for firefighters\n· Protective equipment: Wear fully protective suit.\n6 Accidental release measures\n· Personal precautions, protective equipment and emergency procedures\nEnsure adequate ventilation\nKeep away from ignition sources\n· Environmental precautions: No special measures required.\n· Methods and material for containment and cleaning up:\nAbsorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).\nDispose contaminated material as waste according to section 13.\nEnsure adequate ventilation.\n· Reference to other sections\nSee Section 7 for information on safe handling.\nSee Section 8 for information on personal protection equipment.\nSee Section 13 for disposal information.\n7 Handling and storage\n· Handling:\n· Precautions for safe handling\nProtect from heat and direct sunlight.\nEnsure proper ventilation/exhaustion at workplaces.\nPrevent formation of aerosols.\n· Information about protection against explosions and fires: No special measures required.\n· Conditions for safe storage, including any incompatibilities\n· Storage:\n· Requirements to be met by storerooms and receptacles: Store at temperatures not exceeding 2°C.\n· Information about storage in one common storage facility: Not required.\n· Further information about storage conditions:\nKeep receptacle tightly sealed.\nStore receptacle in a well ventilated area.\n· Specific end use(s) No further relevant information available.\n8 Exposure controls/personal protection\n· Additional information about design of technical systems: No additional data. See 7.\n· Control parameters\n· Components with limit values that require monitoring at the workplace:\n7085-85-0 ethyl 2-cyanoacrylate\nTLV Short-term value: 1 ppm\nLong-term value: 0.2 ppm\nDSEN, RSEN\n· Exposure controls\n· Personal protective equipment:\n· General protective and hygienic measures:\nKeep away from foodstuffs, beverages and feed.\nImmediately remove all soiled and contaminated clothing.\nWash hands before breaks and at the end of work.\nAvoid contact with the eyes and skin.\n· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.\n(Contd. on page 4)\n\n\nPage 4\nPage 4/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 2.0\nProduct name: LOCTITE® 454™ Gel Adhesive\n(Contd. of page 3)\n59.1.0\n· Protection of hands:\nProtective gloves\nThe glove material has to be impermeable and resistant to the product/ the substance/ the preparation.\nSelection of the glove material on consideration of the penetration times, rates of diffusion and the degradation\n· Material of gloves\nNitrile rubber, NBR\nThe selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer\nto manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance\nand has therefore to be checked prior to the application.\n· Eye protection:\nTightly sealed goggles\n9 Physical and chemical properties\n· Information on basic physical and chemical properties\n· General Information\n· Appearance:\nForm:\nPasty\nColor:\nClear\n· Odor:\nCharacteristic\n· Odor threshold:\nNot determined.\n· pH-value:\nNot determined.\n· Change in condition\nMelting point/Melting range:\nUndetermined.\nBoiling point/Boiling range:\n>149 °C (>300.2 °F)\n· Flash point:\n80-93 °C (176-199.4 °F)\n· Flammability (solid, gaseous):\nNot applicable.\n· Auto igniting:\n485 °C (905 °F)\n· Decomposition temperature:\nNot determined.\n· Ignition temperature:\nProduct is not selfigniting.\n· Danger of explosion:\nNot determined.\n· Explosion limits:\nLower:\nNot determined.\nUpper:\nNot determined.\n· Vapor pressure at 20 °C (68 °F):\n0.3 hPa (0.2 mm Hg)\n· Density:\nNot determined.\n· Relative density\nNot determined.\n· Vapor density\n3 \n· Specific gravity:\n1.1\n· Evaporation rate\nNot determined.\n· Solubility in / Miscibility with\nWater:\nNot miscible or difficult to mix.\n· Partition coefficient (n-octanol/water): Not determined.\n(Contd. on page 5)\n\n\nPage 5\nPage 5/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 2.0\nProduct name: LOCTITE® 454™ Gel Adhesive\n(Contd. of page 4)\n59.1.0\n· Viscosity:\nDynamic:\nNot determined.\nKinematic:\nNot determined.\n· Solvent content:\nVOC content:\n0.00 %\nSolids content:\n10.1 %\n· Other information\nNo further relevant information available.\n10 Stability and reactivity\n· Reactivity No further relevant information available.\n· Chemical stability\n· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.\n· Possibility of hazardous reactions\nReacts with water.\nReacts with strong alkali.\nReacts with amines.\nReacts with alcohols.\nDanger of polymerization.\n· Conditions to avoid\nWater\nAlcohol\nDo not mix with alkalis.\n· Incompatible materials: Amines\n· Hazardous decomposition products: No dangerous decomposition products known.\n11 Toxicological information\n· Information on toxicological effects\n· Acute toxicity:\n· Primary chemical irritant effect:\n· on the skin: Irritant to skin and mucous membranes.\n· on the eye: Irritating effect.\n· Sensitization: No sensitizing effects known.\n· Additional toxicological information:\n· Carcinogenic categories\n· IARC (International Agency for Research on Cancer)\nNone of the ingredients is listed.\n· NTP (National Toxicology Program)\nNone of the ingredients is listed.\n· OSHA-Ca (Occupational Safety & Health Administration)\nNone of the ingredients is listed.\n12 Ecological information\n· Toxicity\n· Aquatic toxicity: No further relevant information available.\n· Persistence and degradability No further relevant information available.\n· Behavior in environmental systems:\n· Bioaccumulative potential No further relevant information available.\n· Mobility in soil No further relevant information available.\n· Additional ecological information:\n· General notes:\nWater hazard class 2 (Self-assessment): hazardous for water\n(Contd. on page 6)\n\n\nPage 6\nPage 6/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 2.0\nProduct name: LOCTITE® 454™ Gel Adhesive\n(Contd. of page 5)\n59.1.0\nDo not allow product to reach ground water, water course or sewage system.\nDanger to drinking water if even small quantities leak into the ground.\n· Results of PBT and vPvB assessment\n· PBT: Not applicable.\n· vPvB: Not applicable.\n· Other adverse effects No further relevant information available.\n13 Disposal considerations\n· Waste treatment methods\n· Recommendation: Contact waste processors for recycling information.\n· Uncleaned packagings:\n· Recommendation: Disposal must be made according to official regulations.\n14 Transport information\n· UN-Number\n· DOT, ADN, IMDG, IATA\nnot regulated\n· UN proper shipping name\n· DOT, ADN, IMDG, IATA\nnot regulated\n· Transport hazard class(es)\n· DOT, ADN, IMDG, IATA\n· Class\nnot regulated\n· Packing group\n· DOT, IMDG, IATA\nnot regulated\n· Environmental hazards:\nNot applicable.\n· Special precautions for user\nNot applicable.\n· Transport in bulk according to Annex II of MARPOL73/78 and\nthe IBC Code\nNot applicable.\n· UN "Model Regulation":\nnot regulated\n15 Regulatory information\n· Safety, health and environmental regulations/legislation specific for the substance or mixture\nNo further relevant information available.\n· Sara\n· Section 355 (extremely hazardous substances):\nNone of the ingredients is listed.\n· Section 313 (Specific toxic chemical listings):\nNone of the ingredients is listed.\n· TSCA (Toxic Substances Control Act):\nAll components have the value ACTIVE.\n· Hazardous Air Pollutants\nNone of the ingredients is listed.\n· Proposition 65\n· Chemicals known to cause cancer:\nNone of the ingredients is listed.\n· Chemicals known to cause reproductive toxicity for females:\nNone of the ingredients is listed.\n(Contd. on page 7)\n\n\nPage 7\nPage 7/7\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 2.0\nProduct name: LOCTITE® 454™ Gel Adhesive\n(Contd. of page 6)\n59.1.0\n· Chemicals known to cause reproductive toxicity for males:\nNone of the ingredients is listed.\n· Chemicals known to cause developmental toxicity:\nNone of the ingredients is listed.\n· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.\n16 Other information\nTo the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties\nand does not establish a contractual legal relationship.\n· Department issuing SDS: Technical Services\n· Contact: Pablo Mendoza\n· Last revision / supersedes version: 06/01/2024 / 1.0\n· Supersedes date: 06/01/2022\n· Abbreviations and acronyms:\nADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by\nRoad)\nIMDG: International Maritime Code for Dangerous Goods\nDOT: US Department of Transportation\nIATA: International Air Transport Association\nEINECS: European Inventory of Existing Commercial Chemical Substances\nELINCS: European List of Notified Chemical Substances\nCAS: Chemical Abstracts Service (division of the American Chemical Society)\nVOC: Volatile Organic Compounds (USA, EU)\nPBT: Persistent, Bioaccumulative and Toxic\nvPvB: very Persistent and very Bioaccumulative\nOSHA: Occupational Safety & Health\nTLV: Threshold Limit Value\nPEL: Permissible Exposure Limit\nREL: Recommended Exposure Limit\nFlammable Liquids 4: Flammable liquids – Category 4\nSkin Irritation 2: Skin corrosion/irritation – Category 2\nEye Irritation 2A: Serious eye damage/eye irritation – Category 2A\nSpecific Target Organ Toxicity - Single Exposure 3: Specific target organ toxicity (single exposure) – Category 3\n· * Data compared to the previous version altered. \n