Phenolic Mounting Powder (Red, Black, Green)
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Page 1\n \nPage 1/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\n59.1.0\n* 1 Identification\n· Product name: Phenolic Mounting Powder - Red, Black, Green\n· Part number: 135-10005, 135-10007, 135-10010, 135-10012, 135-10015, 135-10017, Preforms\n· Application of the substance / the mixture Thermoset molding\n· Details of the supplier of the safety data sheet\n· Manufacturer/Supplier:\nAllied High Tech Products Inc.\n16207 Carmenita Road\nUSA-Cerritos, CA, 90703\nUSA\ninfo@alliedhightech.com\n· Information department: Product safety department\n· Emergency telephone number:\nDuring normal opening times: +1 (310) 635-2466\nChemtrec: +1 (202) 483-7616\n2 Hazard(s) identification\n· Classification of the substance or mixture\nGHS08 Health hazard\nGerm Cell Mutagenicity 2\nH341 Suspected of causing genetic defects.\nCarcinogenicity 2\nH351 Suspected of causing cancer.\nSpecific Target Organ Toxicity - Repeated Exposure 2 H373 May cause damage to the central nervous system, the kidneys, the liver, the\nheart and the respiratory system through prolonged or repeated exposure.\nGHS07\nSkin Irritation 2\nH315 Causes skin irritation.\nEye Irritation 2A\nH319 Causes serious eye irritation.\nSensitization - Skin 1\nH317 May cause an allergic skin reaction.\nCombustible Dust\n \nMay form combustible dust concentrations in air.\n· Label elements\n· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).\n(Contd. on page 2)\n\n\nPage 2\nPage 2/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Phenolic Mounting Powder - Red, Black, Green\n(Contd. of page 1)\n59.1.0\n· Hazard pictograms\nGHS07\nGHS08\n· Signal word Warning\n· Hazard-determining components of labeling:\nmethenamine\nCarbon black\nphenol\n· Hazard statements\nCauses skin irritation.\nCauses serious eye irritation.\nMay cause an allergic skin reaction.\nSuspected of causing genetic defects.\nSuspected of causing cancer.\nMay cause damage to the central nervous system, the kidneys, the liver, the heart and the respiratory system through prolonged or repeated\nexposure.\nMay form combustible dust concentrations in air.\n· Precautionary statements\nObtain special instructions before use.\nDo not handle until all safety precautions have been read and understood.\nDo not breathe dust/fume/gas/mist/vapors/spray.\nWash thoroughly after handling.\nContaminated work clothing must not be allowed out of the workplace.\nWear protective gloves/protective clothing/eye protection/face protection.\nIf on skin: Wash with plenty of water.\nIf in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.\nIF exposed or concerned: Get medical advice/attention.\nSpecific treatment (see on this label).\nGet medical advice/attention if you feel unwell.\nTake off contaminated clothing and wash it before reuse.\nIf skin irritation or rash occurs: Get medical advice/attention.\nIf eye irritation persists: Get medical advice/attention.\nWash contaminated clothing before reuse.\nStore locked up.\nDispose of contents/container in accordance with local/regional/national/international regulations.\n* 3 Composition/information on ingredients\n· Chemical characterization: Mixtures\n· Description: Mixture of the substances listed below with nonhazardous additions.\n· Hazardous components and components with occupational exposure limits:\n12001-26-2 Mica\n0-60%\nWood flour\n0-60%\n1332-58-7 Kaolin\n0-40%\n7782-42-5 Graphite\n0-40%\n14807-96-6 Talc (Mg3H2(SiO3)4)\n0-20%\nCoal dust\n0-18%\n100-97-0 methenamine\n Flammable Solids 2, H228;\n Sensitization - Skin 1, H317\n2-15%\n(Contd. on page 3)\n\n\nPage 3\nPage 3/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Phenolic Mounting Powder - Red, Black, Green\n(Contd. of page 2)\n59.1.0\n1333-86-4 Carbon black\n Self-heating substances and mixtures 2, H252;\n Carcinogenicity 2, H351\n0-12%\n1305-62-0 calcium dihydroxide\n Skin Corrosion 1B, H314; Eye Damage 1, H318\n0-10%\n108-95-2 phenol\n Acute Toxicity - Oral 3, H301; Acute Toxicity - Dermal 3, H311; Acute Toxicity - Inhalation 3, H331;\n Germ\nCell Mutagenicity 2, H341; Specific Target Organ Toxicity - Repeated Exposure 2, H373;\n Skin Corrosion 1B,\nH314\n<3.5%\n50-00-0 formaldehyde\n Acute Toxicity - Oral 3, H301; Acute Toxicity - Dermal 3, H311; Acute Toxicity - Inhalation 3, H331;\n Germ\nCell Mutagenicity 2, H341; Carcinogenicity 1A, H350;\n Skin Corrosion 1B, H314;\n Sensitization - Skin 1,\nH317; Flammable Liquids 4, H227\n<0.1%\n· Non-hazardous components:\n9003-35-4 Phenolic Polymer\n30-60%\n· Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.\n4 First-aid measures\n· Description of first aid measures\n· General information:\nImmediately remove any clothing soiled by the product.\nSymptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.\n· After inhalation:\nSupply fresh air and to be sure call for a doctor.\nIn case of unconsciousness place patient stably in side position for transportation.\n· After skin contact: Immediately wash with water and soap and rinse thoroughly.\n· After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.\n· After swallowing: If symptoms persist consult doctor.\n· Information for doctor:\n· Most important symptoms and effects, both acute and delayed\nBreathing difficulty\nCoughing\nAllergic reactions\nDermatitis\nEye irritation\n· Indication of any immediate medical attention and special treatment needed No further relevant information available.\n5 Fire-fighting measures\n· Extinguishing media\n· Suitable extinguishing agents: Use fire fighting measures that suit the environment.\n· Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced.\n· Advice for firefighters\n· Protective equipment: No special measures required.\n6 Accidental release measures\n· Personal precautions, protective equipment and emergency procedures Keep away from ignition sources\n· Environmental precautions: Do not allow to enter sewers/ surface or ground water.\n· Methods and material for containment and cleaning up:\nDispose contaminated material as waste according to section 13.\nEnsure adequate ventilation.\n· Reference to other sections\nSee Section 7 for information on safe handling.\nSee Section 8 for information on personal protection equipment.\nSee Section 13 for disposal information.\n(Contd. on page 4)\n\n\nPage 4\nPage 4/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Phenolic Mounting Powder - Red, Black, Green\n(Contd. of page 3)\n59.1.0\n7 Handling and storage\n· Handling:\n· Precautions for safe handling\nEnsure proper ventilation/exhaustion at workplaces.\nOpen and handle receptacle with care.\n· Information about protection against explosions and fires: No special measures required.\n· Conditions for safe storage, including any incompatibilities\n· Storage:\n· Requirements to be met by storerooms and receptacles:\nStore at temperatures not exceeding 30°C.\nStore only in the original receptacle.\n· Information about storage in one common storage facility: Not required.\n· Further information about storage conditions:\nKeep receptacle tightly sealed.\nStore receptacle in a well ventilated area.\n· Specific end use(s) No further relevant information available.\n8 Exposure controls/personal protection\n· Additional information about design of technical systems: No additional data. See 7.\n· Control parameters\n· Components with limit values that require monitoring at the workplace:\n12001-26-2 Mica\nPEL Long-term value: 20 mppcf ppm\n<1% crystalline silica\nREL Long-term value: 3* mg/m³\n*respirable dust; containing < 1% quartz\nTLV Long-term value: 0.1 mg/m³\n*Respirable particulate matter\nWood flour\nPEL Long-term value: 15 mg/m³\n1332-58-7 Kaolin\nPEL Long-term value: 15* 5** mg/m³\n*total dust **respirable fraction\nREL Long-term value: 10* 5** mg/m³\n*total dust **respirable fraction\nTLV Long-term value: 2* mg/m³\nE; respirable particulate matter, A4\n7782-42-5 Graphite\nPEL Long-term value: 15 mppcf* mg/m³\n*impinger samples counted by light field techn.\nREL Long-term value: 2.5* mg/m³\n*respirable dust\nTLV Long-term value: 2* mg/m³\nall forms except graphite fibers;*resp. fraction\n14807-96-6 Talc (Mg3H2(SiO3)4)\nPEL Long-term value: 20 mppcf ppm\n(containing <1% Quartz)\n(Contd. on page 5)\n\n\nPage 5\nPage 5/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Phenolic Mounting Powder - Red, Black, Green\n(Contd. of page 4)\n59.1.0\nREL Long-term value: 2* mg/m³\n*respirable dust; and <1% Quartz\nTLV Long-term value: 2* mg/m³\n*no asbestos fibers,resp. particulate matter,E,A4\nCoal dust\nPEL Long-term value: 10 mg/m³\n100-97-0 methenamine\nTLV Long-term value: 1 mg/m³\n*inhalable fraction, A4, DSEN\n1333-86-4 Carbon black\nPEL Long-term value: 3.5 mg/m³\nREL Long-term value: 3.5* mg/m³\n*0.1 in presence of PAHs;See Pocket Guide Apps.A+C\nTLV Long-term value: 3* mg/m³\n*inhalable fraction, A3\n1305-62-0 calcium dihydroxide\nPEL Long-term value: 15* 5** mg/m³\n*total dust **respirable fraction\nREL Long-term value: 5 mg/m³\nTLV Long-term value: 5 mg/m³\n108-95-2 phenol\nPEL Long-term value: 19 mg/m³, 5 ppm\nSkin\nREL Long-term value: 19 mg/m³, 5 ppm\nCeiling limit value: 60* mg/m³, 15.6* ppm\n*15-min; Skin\nTLV Long-term value: 5 ppm\nSkin; BEI, A4\n50-00-0 formaldehyde\nPEL Short-term value: 2 ppm\nLong-term value: 0.75 ppm\nsee 29 CFR 1910.1048(c)\nREL Long-term value: 0.016 ppm\nCeiling limit value: 0.1* ppm\n*15-min; See Pocket Guide App. A\nTLV Short-term value: 0.3 ppm\nLong-term value: 0.1 ppm\nDSEN; RSEN, A1\n· Ingredients with biological limit values:\n108-95-2 phenol\nBEI 250 mg/g creatinine\nMedium: urine\nTime: end of shift\nParameter: Phenol with hydrolysis (background, nonspecific)\n· Exposure controls\n· Personal protective equipment:\n· General protective and hygienic measures:\nKeep away from foodstuffs, beverages and feed.\nImmediately remove all soiled and contaminated clothing.\nWash hands before breaks and at the end of work.\n(Contd. on page 6)\n\n\nPage 6\nPage 6/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Phenolic Mounting Powder - Red, Black, Green\n(Contd. of page 5)\n59.1.0\nStore protective clothing separately.\nAvoid contact with the eyes and skin.\n· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.\n· Protection of hands:\nDue to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.\nProtective gloves\nThe glove material has to be impermeable and resistant to the product/ the substance/ the preparation.\nSelection of the glove material on consideration of the penetration times, rates of diffusion and the degradation\n· Material of gloves\nThe selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer\nto manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance\nand has therefore to be checked prior to the application.\n· Eye protection:\nTightly sealed goggles\n9 Physical and chemical properties\n· Information on basic physical and chemical properties\n· General Information\n· Appearance:\nForm:\nPowder\nColor:\nAccording to product specification\n· Odor:\nPhenol-like\n· Odor threshold:\nNot determined.\n· pH-value:\nNot applicable.\n· Change in condition\nMelting point/Melting range:\nUndetermined.\nBoiling point/Boiling range:\nUndetermined.\n· Flash point:\nNot applicable.\n· Flammability (solid, gaseous):\nNot determined.\n· Decomposition temperature:\nNot determined.\n· Ignition temperature:\nProduct is not selfigniting.\n· Danger of explosion:\nProduct does not present an explosion hazard.\n· Explosion limits:\nLower:\nDust 0.03 oz per cubic foot\nUpper:\nNot determined.\n· Vapor pressure:\nNot applicable.\n· Density at 20 °C (68 °F):\n0.6 g/cm³ (5.007 lbs/gal)\n· Relative density\nNot determined.\n· Vapor density\nNot applicable.\n· Specific gravity at 20 °C (68 °F):\n1.39 g/cm³ (11.6 lbs/gal)\n· Evaporation rate\nNot applicable.\n· Solubility in / Miscibility with\nWater:\nInsoluble.\n(Contd. on page 7)\n\n\nPage 7\nPage 7/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Phenolic Mounting Powder - Red, Black, Green\n(Contd. of page 6)\n59.1.0\n· Partition coefficient (n-octanol/water): Not determined.\n· Viscosity:\nDynamic:\nNot applicable.\nKinematic:\nNot applicable.\n· Solvent content:\nOrganic solvents:\n1.1 %\nVOC content:\n1.06 %\nSolids content:\n100.0 %\n· Other information\nNo further relevant information available.\n10 Stability and reactivity\n· Reactivity No further relevant information available.\n· Chemical stability\n· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.\n· Possibility of hazardous reactions No dangerous reactions known.\n· Conditions to avoid\nKeep away from oxidising agents and acidic substances.\nKeep away from heat.\nKeep away from open flames. - No smoking.\n· Incompatible materials: No further relevant information available.\n· Hazardous decomposition products:\nCarbon monoxide and carbon dioxide\nFormaldehyde\nPhenol\nAmmonia\n· Additional information: Hazardous decomposition products may form during combustion.\n11 Toxicological information\n· Information on toxicological effects\n· Acute toxicity:\n· LD/LC50 values that are relevant for classification:\nOral\nLD50\n>5,000 mg/kg (rat)\nDermal\nLD50\n>5,000 mg/kg (rabbit)\n 1333-86-4 Carbon black\nOral\nLD50\n10,000 mg/kg (rat)\n1305-62-0 calcium dihydroxide\nOral\nLD50\n7,340 mg/kg (rat)\n108-95-2 phenol\nOral\nLD50\n317 mg/kg (rat)\nDermal\nLD50\n850 mg/kg (rabbit)\nInhalative LC50/4 h 0.5 mg/l (ATE)\n50-00-0 formaldehyde\nOral\nLD50\n>200 mg/kg (rat)\nDermal\nLD50\n270 mg/kg (rabbit)\nInhalative LC50/4 h 3 mg/l (ATE)\n· Primary chemical irritant effect:\n· on the skin: Irritant to skin and mucous membranes.\n· on the eye: Irritating effect.\n(Contd. on page 8)\n\n\nPage 8\nPage 8/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Phenolic Mounting Powder - Red, Black, Green\n(Contd. of page 7)\n59.1.0\n· Sensitization: Sensitization possible through skin contact.\n· Additional toxicological information:\n· Carcinogenic categories\n· IARC (International Agency for Research on Cancer)\n14807-96-6 Talc (Mg3H2(SiO3)4)\n3 \n1333-86-4 Carbon black\n2B\n108-95-2 phenol\n3 \n50-00-0 formaldehyde\n1 \n· NTP (National Toxicology Program)\n50-00-0 formaldehyde\nK \n· OSHA-Ca (Occupational Safety & Health Administration)\n50-00-0 formaldehyde\n12 Ecological information\n· Toxicity\n· Aquatic toxicity: No further relevant information available.\n· Persistence and degradability No further relevant information available.\n· Behavior in environmental systems:\n· Bioaccumulative potential No further relevant information available.\n· Mobility in soil No further relevant information available.\n· Additional ecological information:\n· General notes:\nWater hazard class 1 (Self-assessment): slightly hazardous for water\nDo not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.\n· Results of PBT and vPvB assessment\n· PBT: Not applicable.\n· vPvB: Not applicable.\n· Other adverse effects No further relevant information available.\n13 Disposal considerations\n· Waste treatment methods\n· Recommendation: Contact waste processors for recycling information.\n· Uncleaned packagings:\n· Recommendation: Disposal must be made according to official regulations.\n14 Transport information\n· UN-Number\n· DOT, ADN, IMDG, IATA\nnot regulated\n· UN proper shipping name\n· DOT, ADN, IMDG, IATA\nnot regulated\n· Transport hazard class(es)\n· DOT, IMDG, IATA\n· Class\nnot regulated\n· Label\n- \n· ADN/R Class:\nnot regulated\n· Packing group\n· DOT, IMDG, IATA\nnot regulated\n(Contd. on page 9)\n\n\nPage 9\nPage 9/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Phenolic Mounting Powder - Red, Black, Green\n(Contd. of page 8)\n59.1.0\n· Environmental hazards:\n· Marine pollutant:\nNo\n· Special precautions for user\nNot applicable.\n· Transport in bulk according to Annex II of MARPOL73/78 and\nthe IBC Code\nNot applicable.\n· UN "Model Regulation":\nnot regulated\n15 Regulatory information\n· Safety, health and environmental regulations/legislation specific for the substance or mixture\n· Sara\n· Section 355 (extremely hazardous substances):\n108-95-2 phenol\n50-00-0 formaldehyde\n· Section 313 (Specific toxic chemical listings):\n108-95-2 phenol\n50-00-0 formaldehyde\n· TSCA (Toxic Substances Control Act):\nAll other ingredients are exempt from listing.\n9003-35-4 Phenolic Polymer\nACTIVE\n1332-58-7 Kaolin\nACTIVE\n7782-42-5 Graphite\nACTIVE\n14807-96-6 Talc (Mg3H2(SiO3)4)\nACTIVE\n100-97-0 methenamine\nACTIVE\n1333-86-4 Carbon black\nACTIVE\n1305-62-0 calcium dihydroxide\nACTIVE\n108-95-2 phenol\nACTIVE\n50-00-0 formaldehyde\nACTIVE\n· Hazardous Air Pollutants\n108-95-2 phenol\n50-00-0 formaldehyde\n· Proposition 65\n· Chemicals known to cause cancer:\n1333-86-4 Carbon black\n50-00-0 formaldehyde\n· Chemicals known to cause reproductive toxicity for females:\nNone of the ingredients is listed.\n· Chemicals known to cause reproductive toxicity for males:\nNone of the ingredients is listed.\n· Chemicals known to cause developmental toxicity:\nNone of the ingredients is listed.\n· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.\n16 Other information\nTo the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties\nand does not establish a contractual legal relationship.\n· Department issuing SDS: Technical Services\n(Contd. on page 10)\n\n\nPage 10\nPage 10/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 6.0\nProduct name: Phenolic Mounting Powder - Red, Black, Green\n(Contd. of page 9)\n59.1.0\n· Contact: Pablo Mendoza\n· Last revision / supersedes version: 06/01/2024 / 5.0\n· Supersedes date: 06/01/2022\n· Abbreviations and acronyms:\nADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by\nRoad)\nIMDG: International Maritime Code for Dangerous Goods\nDOT: US Department of Transportation\nIATA: International Air Transport Association\nEINECS: European Inventory of Existing Commercial Chemical Substances\nELINCS: European List of Notified Chemical Substances\nCAS: Chemical Abstracts Service (division of the American Chemical Society)\nVOC: Volatile Organic Compounds (USA, EU)\nLC50: Lethal concentration, 50 percent\nLD50: Lethal dose, 50 percent\nPBT: Persistent, Bioaccumulative and Toxic\nvPvB: very Persistent and very Bioaccumulative\nOSHA: Occupational Safety & Health\nTLV: Threshold Limit Value\nPEL: Permissible Exposure Limit\nREL: Recommended Exposure Limit\nBEI: Biological Exposure Limit\nFlammable Liquids 4: Flammable liquids – Category 4\nFlammable Solids 2: Flammable solids – Category 2\nSelf-heating substances and mixtures 2: Self-heating substances and mixtures – Category 2\nAcute Toxicity - Oral 3: Acute toxicity – Category 3\nSkin Corrosion 1B: Skin corrosion/irritation – Category 1B\nSkin Irritation 2: Skin corrosion/irritation – Category 2\nEye Damage 1: Serious eye damage/eye irritation – Category 1\nEye Irritation 2A: Serious eye damage/eye irritation – Category 2A\nSensitization - Skin 1: Skin sensitisation – Category 1\nGerm Cell Mutagenicity 2: Germ cell mutagenicity – Category 2\nCarcinogenicity 1A: Carcinogenicity – Category 1A\nCarcinogenicity 2: Carcinogenicity – Category 2\nSpecific Target Organ Toxicity - Repeated Exposure 2: Specific target organ toxicity (repeated exposure) – Category 2\n· * Data compared to the previous version altered. \n