SILICON CARBIDE BLADE - RUBBER BOND SAFETY DATA SHEET
Also listed as: SILICON CARBIDE BLADE RUBBER BOND SAFETY DATA SHEET; Silicon Carbide Cut-off & Wafering Blades Rubber Bond; SILICON CARBIDE BLADE SAFETY DATA SHEET
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Page 1\n \nPage 1/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\n59.1.0\n* 1 Identification\n· Product name: Silicon Carbide Cut-Off & Wafering Blades, Rubber Bond\n· Part number:\n80-10030\n80-11185 - 80-11225\n80-30050 - 80-30060\n80-40055 - 80-40065\n80-50055 - 80-50065\n· Application of the substance / the mixture Abrasive blade\n· Details of the supplier of the safety data sheet\n· Manufacturer/Supplier:\nAllied High Tech Products Inc.\n16207 Carmenita Road\nUSA-Cerritos, CA, 90703\nUSA\ninfo@alliedhightech.com\n· Information department: Product safety department\n· Emergency telephone number:\nDuring normal opening times: +1 (310) 635-2466\nChemtrec: +1 (202) 483-7616\n2 Hazard(s) identification\n· Classification of the substance or mixture\nGHS08 Health hazard\nCarcinogenicity 2 H351 Suspected of causing cancer. Route of exposure: Inhalation.\nGHS07\nSkin Irritation 2\nH315 Causes skin irritation.\nEye Irritation 2A\nH319 Causes serious eye irritation.\nAquatic Acute 3\nH402 Harmful to aquatic life.\nAquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.\n· Additional information:\nAll components listed for this product are bound within the product. When handled as intended and under normal conditions of use, there is\nno evidence that any of the ingredients are released in amounts that pose a significant health risk.\n· Label elements\n· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).\n(Contd. on page 2)\n\n\nPage 2\nPage 2/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Silicon Carbide Cut-Off & Wafering Blades, Rubber Bond\n(Contd. of page 1)\n59.1.0\n· Hazard pictograms\nGHS07\nGHS08\n· Signal word Warning\n· Hazard-determining components of labeling:\ntitanium dioxide\n· Hazard statements\nCauses skin irritation.\nCauses serious eye irritation.\nSuspected of causing cancer. Route of exposure: Inhalation.\nHarmful to aquatic life with long lasting effects.\n· Precautionary statements\nObtain special instructions before use.\nDo not handle until all safety precautions have been read and understood.\nWash thoroughly after handling.\nAvoid release to the environment.\nWear protective gloves/protective clothing/eye protection/face protection.\nIf on skin: Wash with plenty of water.\nIf in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.\nIF exposed or concerned: Get medical advice/attention.\nSpecific treatment (see on this label).\nTake off contaminated clothing and wash it before reuse.\nIf skin irritation occurs: Get medical advice/attention.\nIf eye irritation persists: Get medical advice/attention.\nStore locked up.\nDispose of contents/container in accordance with local/regional/national/international regulations.\n3 Composition/information on ingredients\n· Chemical characterization: Mixtures\n· Description: Mixture of the substances listed below with nonhazardous additions.\n· Hazardous components and components with occupational exposure limits:\n409-21-2 silicon carbide\n80-90%\n9006-04-6 Natural rubber latex\n10-20%\n13397-24-5 Gypsum (Calcium sulfate)\n10-20%\n60304-36-1 Potassium aluminum fluoride\n Skin Irritation 2, H315; Specific Target Organ Toxicity - Single Exposure 3, H335; Eye Irritation 2B, H320\n10-<20%\n1309-37-1 diiron trioxide\n5-10%\n15096-52-3 cryolite\n Aquatic Chronic 2, H411;\n Acute Toxicity - Inhalation 4, H332\n5-10%\n7704-34-9 sulfur\n Skin Irritation 2, H315\n5-<10%\n1317-65-3 Limestone\n Acute Toxicity - Inhalation 4, H332\n1-5%\n557-04-0 magnesium stearate\n1-5%\n1305-78-8 calcium oxide\n Eye Damage 1, H318\n1-<3%\n1332-58-7 Kaolin\n1-5%\n(Contd. on page 3)\n\n\nPage 3\nPage 3/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Silicon Carbide Cut-Off & Wafering Blades, Rubber Bond\n(Contd. of page 2)\n59.1.0\n14075-53-7 potassium tetrafluoroborate\n Acute Toxicity - Oral 3, H301;\n Skin Irritation 2, H315; Eye Irritation 2A, H319\n1-5%\n1314-13-2 zinc oxide\n Aquatic Acute 1, H400; Aquatic Chronic 1, H410\n0.25-≤1%\n13463-67-7 titanium dioxide\n Carcinogenicity 2, H351\n0.1-≤1%\n· Non-hazardous components:\nResin\n5-10%\n· Additional information:\nProduct may contain many or all of the above ingredients.\nThe specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.\n4 First-aid measures\n· Description of first aid measures\n· General information: Immediately remove any clothing soiled by the product.\n· After inhalation: In case of unconsciousness place patient stably in side position for transportation.\n· After skin contact: Immediately wash with water and soap and rinse thoroughly.\n· After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.\n· After swallowing: If symptoms persist consult doctor.\n· Information for doctor:\n· Most important symptoms and effects, both acute and delayed\nBreathing difficulty\nEye irritation\nCoughing\nDermatitis\nEye irritation\nDermatitis\n· Indication of any immediate medical attention and special treatment needed No further relevant information available.\n5 Fire-fighting measures\n· Extinguishing media\n· Suitable extinguishing agents: Use fire fighting measures that suit the environment.\n· Special hazards arising from the substance or mixture No further relevant information available.\n· Advice for firefighters\n· Protective equipment: No special measures required.\n6 Accidental release measures\n· Personal precautions, protective equipment and emergency procedures Not required.\n· Environmental precautions:\nDo not allow to enter sewers/ surface or ground water.\nInform respective authorities in case of seepage into water course or sewage system.\n· Methods and material for containment and cleaning up:\nPick up mechanically.\nDispose contaminated material as waste according to section 13.\n· Reference to other sections\nSee Section 7 for information on safe handling.\nSee Section 8 for information on personal protection equipment.\nSee Section 13 for disposal information.\n7 Handling and storage\n· Handling:\n· Precautions for safe handling Open and handle receptacle with care.\n· Information about protection against explosions and fires: No special measures required.\n(Contd. on page 4)\n\n\nPage 4\nPage 4/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Silicon Carbide Cut-Off & Wafering Blades, Rubber Bond\n(Contd. of page 3)\n59.1.0\n· Conditions for safe storage, including any incompatibilities\n· Storage:\n· Requirements to be met by storerooms and receptacles:\nStore in a cool location.\nNo special requirements.\n· Information about storage in one common storage facility: Store away from foodstuffs.\n· Further information about storage conditions: Keep receptacle tightly sealed.\n· Specific end use(s) No further relevant information available.\n8 Exposure controls/personal protection\n· Additional information about design of technical systems: No additional data. See 7.\n· Control parameters\n· Components with limit values that require monitoring at the workplace:\nThe following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.\nAt this time, the other constituents have no known exposure limits.\n409-21-2 silicon carbide\nPEL Long-term value: 15* 5** mg/m³\nfibrous dust: *total dust **respirable fraction\nREL Long-term value: 10* 5** mg/m³\n*total dust **respirable fraction\nTLV Long-term value: 10* 3** mg/m³\nfibrous dust:0.1 f/cc A2, nonfibrous:*inh.,**resp.\n9006-04-6 Natural rubber latex\nTLV Long-term value: 0.0001* mg/m³\nSkin; DSEN, RSEN;* inh. particulate matter\n13397-24-5 Gypsum (Calcium sulfate)\nREL Long-term value: 10* 5** mg/m³\n*Total dust; **Respirable fraction\nTLV Long-term value: 10* mg/m³\n*as inhalable fraction\n1309-37-1 diiron trioxide\nPEL Long-term value: 10* mg/m³\n*Fume\nREL Long-term value: 5 mg/m³\nDust & fume, as Fe\nTLV Long-term value: 5* mg/m³\n*Respirable particulate matter, A4\n15096-52-3 cryolite\nPEL Long-term value: 2.5 mg/m³\nas F\nREL Long-term value: 2.5 mg/m³\nas F\n1317-65-3 Limestone\nPEL Long-term value: 15 mg/m³\n557-04-0 magnesium stearate\nTLV Long-term value: 10* 3** mg/m³\nA4; Fraction: *inhalable **respirable\n1305-78-8 calcium oxide\nPEL Long-term value: 5 mg/m³\n(Contd. on page 5)\n\n\nPage 5\nPage 5/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Silicon Carbide Cut-Off & Wafering Blades, Rubber Bond\n(Contd. of page 4)\n59.1.0\nREL Long-term value: 2 mg/m³\nTLV Long-term value: 2 mg/m³\n1332-58-7 Kaolin\nPEL Long-term value: 15* 5** mg/m³\n*total dust **respirable fraction\nREL Long-term value: 10* 5** mg/m³\n*total dust **respirable fraction\nTLV Long-term value: 2* mg/m³\nE; respirable particulate matter, A4\n14075-53-7 potassium tetrafluoroborate\nPEL Long-term value: 2.5 mg/m³\nas F\nREL Long-term value: 2.5 mg/m³\nas F\nTLV Long-term value: 2.5 mg/m³\nas F, A4; BEI\n1314-13-2 zinc oxide\nPEL Long-term value: 15* 5** mg/m³\n*total dust **respirable fraction and fume\nREL Short-term value: 10** mg/m³\nLong-term value: 5 mg/m³\nCeiling limit value: 15* mg/m³\n*dust only **fume\nTLV Short-term value: 10* mg/m³\nLong-term value: 2* mg/m³\n*respirable particulate matter\n13463-67-7 titanium dioxide\nPEL Long-term value: 15* mg/m³\n*total dust\nREL See Pocket Guide App. A\nTLV Long-term value: 0.2* 2.5** mg/m³\nresp. fraction, *nanoscale,**finescale, A3\n· Ingredients with biological limit values:\n15096-52-3 cryolite\nBEI 2 mg/L\nMedium: urine\nTime: prior to shift\nParameter: Fluoride (background, nonspecific)\n3 mg/L\nMedium: urine\nTime: end of shift\nParameter: Fluoride (background, nonspecific)\n(Contd. on page 6)\n\n\nPage 6\nPage 6/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Silicon Carbide Cut-Off & Wafering Blades, Rubber Bond\n(Contd. of page 5)\n59.1.0\n14075-53-7 potassium tetrafluoroborate\nBEI 2 mg/L\nMedium: urine\nTime: prior to shift\nParameter: Fluoride (background, nonspecific)\n3 mg/L\nMedium: urine\nTime: end of shift\nParameter: Fluoride (background, nonspecific)\n· Exposure controls\n· Personal protective equipment:\n· General protective and hygienic measures:\nKeep away from foodstuffs, beverages and feed.\nImmediately remove all soiled and contaminated clothing.\nWash hands before breaks and at the end of work.\nStore protective clothing separately.\nAvoid contact with the eyes and skin.\n· Breathing equipment:\nNot required.\nUse suitable respiratory protective device in case of insufficient ventilation.\n· Protection of hands:\nDue to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.\nProtective gloves\nThe glove material has to be impermeable and resistant to the product/ the substance/ the preparation.\nSelection of the glove material on consideration of the penetration times, rates of diffusion and the degradation\n· Material of gloves\nLeather gloves\nThe selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer\nto manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance\nand has therefore to be checked prior to the application.\n· Eye protection:\nTightly sealed goggles\n9 Physical and chemical properties\n· Information on basic physical and chemical properties\n· General Information\n· Appearance:\nForm:\nSolid\nColor:\nAccording to product specification\n· Odor:\nCharacteristic\n· Odor threshold:\nNot determined.\n· pH-value:\nNot applicable.\n· Change in condition\nMelting point/Melting range:\nUndetermined.\nBoiling point/Boiling range:\nUndetermined.\n(Contd. on page 7)\n\n\nPage 7\nPage 7/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Silicon Carbide Cut-Off & Wafering Blades, Rubber Bond\n(Contd. of page 6)\n59.1.0\n· Flash point:\nNot applicable.\n· Flammability (solid, gaseous):\nNot determined.\n· Decomposition temperature:\nNot determined.\n· Ignition temperature:\nProduct is not selfigniting.\n· Danger of explosion:\nProduct does not present an explosion hazard.\n· Explosion limits:\nLower:\nNot determined.\nUpper:\nNot determined.\n· Vapor pressure:\nNot applicable.\n· Density:\nNot determined.\n· Relative density\nNot determined.\n· Vapor density\nNot applicable.\n· Specific gravity:\n1.8 - 2.5 (Water = 1)\n· Evaporation rate\nNot applicable.\n· Solubility in / Miscibility with\nWater:\nInsoluble.\n· Partition coefficient (n-octanol/water): Not determined.\n· Viscosity:\nDynamic:\nNot applicable.\nKinematic:\nNot applicable.\n· Solvent content:\nVOC content:\n0.00 %\nSolids content:\n100.0 %\n· Other information\nNo further relevant information available.\n10 Stability and reactivity\n· Reactivity No further relevant information available.\n· Chemical stability\n· Thermal decomposition / conditions to be avoided: Degradation starts at 220 °C with 461.2 °C as final degradation temperature\n· Possibility of hazardous reactions No dangerous reactions known.\n· Conditions to avoid No further relevant information available.\n· Incompatible materials: No further relevant information available.\n· Hazardous decomposition products: Carbon monoxide and carbon dioxide\n· Additional information: Hazardous decomposition products may form during combustion.\n11 Toxicological information\n· Information on toxicological effects\n· Acute toxicity:\n· LD/LC50 values that are relevant for classification:\nATE (Acute Toxicity Estimate)\nOral\nLD50\n4,000 mg/kg\nInhalative LC50/4 h 17.6 mg/l\n 409-21-2 silicon carbide\nOral\nLD50\n>2,000 mg/kg (rat)\nDermal\nLD50\n>2,000 mg/kg (rat)\n(Contd. on page 8)\n\n\nPage 8\nPage 8/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Silicon Carbide Cut-Off & Wafering Blades, Rubber Bond\n(Contd. of page 7)\n59.1.0\n1309-37-1 diiron trioxide\nOral\nLD50\n>5,000 mg/kg (rat)\n15096-52-3 cryolite\nInhalative LC50/4 h 1.5 mg/l (ATE)\n1317-65-3 Limestone\nOral\nLD50\n6,450 mg/kg (rat)\nDermal\nLD50\n>2,000 mg/kg (rat)\nInhalative LC50/4 h 3 mg/l (rat)\n14075-53-7 potassium tetrafluoroborate\nOral\nLD50\n100 mg/kg (ATE)\n1314-13-2 zinc oxide\nOral\nLD50\n>5,000 mg/kg (rat)\n13463-67-7 titanium dioxide\nOral\nLD50\n>20,000 mg/kg (rat)\nDermal\nLD50\n>10,000 mg/kg (rabbit)\nInhalative LC50/4 h >6.82 mg/l (rat)\n· Primary chemical irritant effect:\n· on the skin: Irritant to skin and mucous membranes.\n· on the eye: Irritating effect.\n· Sensitization: No sensitizing effects known.\n· Additional toxicological information:\nAbrasive eye irritant\nAbrasive skin irritant\n· Carcinogenic categories\n· IARC (International Agency for Research on Cancer)\n409-21-2 silicon carbide\n2A\n1309-37-1 diiron trioxide\n3 \n14075-53-7 potassium tetrafluoroborate\n3 \n13463-67-7 titanium dioxide\n2B\n· NTP (National Toxicology Program)\nNone of the ingredients is listed.\n· OSHA-Ca (Occupational Safety & Health Administration)\nNone of the ingredients is listed.\n12 Ecological information\n· Toxicity\n· Aquatic toxicity: No further relevant information available.\n· Persistence and degradability No further relevant information available.\n· Behavior in environmental systems:\n· Bioaccumulative potential No further relevant information available.\n· Mobility in soil No further relevant information available.\n· Ecotoxical effects:\n· Remark: Harmful to fish\n· Additional ecological information:\n· General notes:\nDo not allow product to reach ground water, water course or sewage system, even in small quantities.\nDanger to drinking water if even extremely small quantities leak into the ground.\nHarmful to aquatic organisms\n(Contd. on page 9)\n\n\nPage 9\nPage 9/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Silicon Carbide Cut-Off & Wafering Blades, Rubber Bond\n(Contd. of page 8)\n59.1.0\n· Results of PBT and vPvB assessment\n· PBT: Not applicable.\n· vPvB: Not applicable.\n· Other adverse effects No further relevant information available.\n13 Disposal considerations\n· Waste treatment methods\n· Recommendation: Contact waste processors for recycling information.\n· Uncleaned packagings:\n· Recommendation: Disposal must be made according to official regulations.\n14 Transport information\n· UN-Number\n· DOT, ADN, IMDG, IATA\nnot regulated\n· UN proper shipping name\n· DOT, ADN, IMDG, IATA\nnot regulated\n· Transport hazard class(es)\n· DOT, ADN, IMDG, IATA\n· Class\nnot regulated\n· Packing group\n· DOT, IMDG, IATA\nnot regulated\n· Environmental hazards:\n· Marine pollutant:\nNo\n· Special precautions for user\nNot applicable.\n· Transport in bulk according to Annex II of MARPOL73/78 and\nthe IBC Code\nNot applicable.\n· UN "Model Regulation":\nnot regulated\n15 Regulatory information\n· Safety, health and environmental regulations/legislation specific for the substance or mixture\nNo further relevant information available.\n· Sara\n· Section 355 (extremely hazardous substances):\nNone of the ingredients is listed.\n· Section 313 (Specific toxic chemical listings):\n1314-13-2 zinc oxide\n· TSCA (Toxic Substances Control Act):\nAll components have the value ACTIVE.\n· Hazardous Air Pollutants\nNone of the ingredients is listed.\n· Proposition 65\n· Chemicals known to cause cancer:\n13463-67-7 titanium dioxide\n· Chemicals known to cause reproductive toxicity for females:\nNone of the ingredients is listed.\n(Contd. on page 10)\n\n\nPage 10\nPage 10/10\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 4.0\nProduct name: Silicon Carbide Cut-Off & Wafering Blades, Rubber Bond\n(Contd. of page 9)\n59.1.0\n· Chemicals known to cause reproductive toxicity for males:\nNone of the ingredients is listed.\n· Chemicals known to cause developmental toxicity:\nNone of the ingredients is listed.\n· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.\n16 Other information\nTo the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties\nand does not establish a contractual legal relationship.\n· Department issuing SDS: Technical Services\n· Contact: Pablo Mendoza\n· Last revision / supersedes version: 06/01/2024 / 3.0\n· Supersedes date: 06/01/2022\n· Abbreviations and acronyms:\nADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by\nRoad)\nIMDG: International Maritime Code for Dangerous Goods\nDOT: US Department of Transportation\nIATA: International Air Transport Association\nEINECS: European Inventory of Existing Commercial Chemical Substances\nELINCS: European List of Notified Chemical Substances\nCAS: Chemical Abstracts Service (division of the American Chemical Society)\nVOC: Volatile Organic Compounds (USA, EU)\nLC50: Lethal concentration, 50 percent\nLD50: Lethal dose, 50 percent\nPBT: Persistent, Bioaccumulative and Toxic\nvPvB: very Persistent and very Bioaccumulative\nOSHA: Occupational Safety & Health\nTLV: Threshold Limit Value\nPEL: Permissible Exposure Limit\nREL: Recommended Exposure Limit\nBEI: Biological Exposure Limit\nAcute Toxicity - Oral 3: Acute toxicity – Category 3\nAcute Toxicity - Inhalation 4: Acute toxicity – Category 4\nSkin Irritation 2: Skin corrosion/irritation – Category 2\nEye Damage 1: Serious eye damage/eye irritation – Category 1\nEye Irritation 2A: Serious eye damage/eye irritation – Category 2A\nEye Irritation 2B: Serious eye damage/eye irritation – Category 2B\nCarcinogenicity 2: Carcinogenicity – Category 2\nSpecific Target Organ Toxicity - Single Exposure 3: Specific target organ toxicity (single exposure) – Category 3\nAquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1\nAquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard – Category 3\nAquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1\nAquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2\nAquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3\n· * Data compared to the previous version altered. \n