Zirconia Alumina Abrasive Discs - Belts1(US)
Also listed as: Zirconia Alumina Abrasive Disc and Belts
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Page 1\n \nPage 1/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 5.0\n59.1.0\n* 1 Identification\n· Product name: Zirconia Alumina Abrasive Discs - Belts\n· Part number:\n50-10001-Z , 50-10045-Z, 50-10050-Z\n50-10210-Z, 50-10215-Z, 50-10220-Z\n50-10420-Z, 50-10425-Z, 50-10435-Z\n50-11045-Z, 50-11050-Z\n50-146025-Z, 50-146035-Z\n· Application of the substance / the mixture Abrasive\n· Details of the supplier of the safety data sheet\n· Manufacturer/Supplier:\nAllied High Tech Products Inc.\n16207 Carmenita Road\nUSA-Cerritos, CA, 90703\nUSA\ninfo@alliedhightech.com\n· Information department: Product safety department\n· Emergency telephone number:\nDuring normal opening times: +1 (310) 635-2466\nChemtrec: +1 (202) 483-7616\n2 Hazard(s) identification\n· Classification of the substance or mixture\nGHS08 Health hazard\nSpecific Target Organ Toxicity - Repeated Exposure 1 H372 Causes damage to the lung and the bones through prolonged or repeated\nexposure.\nAquatic Chronic 3\nH412 Harmful to aquatic life with long lasting effects.\n· Additional information:\nAll components listed for this product are bound within the product. When handled as intended and under normal conditions of use, there is\nno evidence that any of the ingredients are released in amounts that pose a significant health risk.\n· Label elements\n· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).\n· Hazard pictograms\nGHS08\n· Signal word Danger\n(Contd. on page 2)\n\n\nPage 2\nPage 2/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 5.0\nProduct name: Zirconia Alumina Abrasive Discs - Belts\n(Contd. of page 1)\n59.1.0\n· Hazard-determining components of labeling:\ntrisodium hexafluoroaluminate\n· Hazard statements\nCauses damage to the lung and the bones through prolonged or repeated exposure.\nHarmful to aquatic life with long lasting effects.\n· Precautionary statements\nDo not breathe dust/fume/gas/mist/vapors/spray.\nWash thoroughly after handling.\nDo not eat, drink or smoke when using this product.\nAvoid release to the environment.\nGet medical advice/attention if you feel unwell.\nDispose of contents/container in accordance with local/regional/national/international regulations.\n3 Composition/information on ingredients\n· Chemical characterization: Mixtures\n· Description: Mixture of the substances listed below with nonhazardous additions.\n· Hazardous components and components with occupational exposure limits:\n7440-67-7 Zirconia alumina\n30-40%\n7727-43-7 barium sulphate, natural\n30-40%\n1317-65-3 Limestone\n Acute Toxicity - Inhalation 4, H332\n20-30%\n557-05-1 zinc distearate, pure\n5-10%\n1332-58-7 Kaolin\n5-10%\n13775-53-6 trisodium hexafluoroaluminate\n Specific Target Organ Toxicity - Repeated Exposure 1, H372;\n Aquatic Chronic 2, H411;\n Acute Toxicity\n- Inhalation 4, H332\n5-<10%\n7778-18-9 calcium sulphate, natural\n1-5%\n107-21-1 ethylene glycol\n Acute Toxicity - Oral 4, H302\n≤1%\n1309-37-1 diiron trioxide\n≤1%\n14075-53-7 potassium tetrafluoroborate\n Acute Toxicity - Oral 3, H301;\n Skin Irritation 2, H315; Eye Irritation 2A, H319\n≤1%\n15096-52-3 cryolite\n Aquatic Chronic 2, H411;\n Acute Toxicity - Inhalation 4, H332\n0.25-≤1%\n14808-60-7 Quartz (SiO2)\n Carcinogenicity 1A, H350\n<0.1%\n· Non-hazardous components:\nResin\n10-20%\nPaper Backing\n10-20%\n1592-23-0 calcium distearate, pure\n5-10%\nGarnet\n5-10%\nLubricant\n1-5%\nFiller\n1-5%\nNylon loop\n1-5%\nWax\n1-5%\n1317-61-9 triiron tetraoxide\n≤1%\n· Additional information:\nProduct may contain many or all of the above ingredients.\nThe specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.\n(Contd. on page 3)\n\n\nPage 3\nPage 3/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 5.0\nProduct name: Zirconia Alumina Abrasive Discs - Belts\n(Contd. of page 2)\n59.1.0\n4 First-aid measures\n· Description of first aid measures\n· General information:\nSymptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.\n· After inhalation: Supply fresh air; consult doctor in case of complaints.\n· After skin contact: Generally the product does not irritate the skin.\n· After eye contact: Rinse opened eye for several minutes under running water.\n· After swallowing: If symptoms persist consult doctor.\n· Information for doctor:\n· Most important symptoms and effects, both acute and delayed\nEye irritation\nDermatitis\n· Indication of any immediate medical attention and special treatment needed No further relevant information available.\n5 Fire-fighting measures\n· Extinguishing media\n· Suitable extinguishing agents: Use fire fighting measures that suit the environment.\n· Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced.\n· Advice for firefighters\n· Protective equipment: No special measures required.\n6 Accidental release measures\n· Personal precautions, protective equipment and emergency procedures Keep away from ignition sources\n· Environmental precautions:\nDo not allow to enter sewers/ surface or ground water.\nInform respective authorities in case of seepage into water course or sewage system.\n· Methods and material for containment and cleaning up:\nPick up mechanically.\nDispose contaminated material as waste according to section 13.\nEnsure adequate ventilation.\n· Reference to other sections\nSee Section 7 for information on safe handling.\nSee Section 8 for information on personal protection equipment.\nSee Section 13 for disposal information.\n7 Handling and storage\n· Handling:\n· Precautions for safe handling Ensure proper ventilation/exhaustion at workplaces.\n· Information about protection against explosions and fires: No special measures required.\n· Conditions for safe storage, including any incompatibilities\n· Storage:\n· Requirements to be met by storerooms and receptacles:\nStore in a cool location.\nNo special requirements.\n· Information about storage in one common storage facility: Not required.\n· Further information about storage conditions: Store receptacle in a well ventilated area.\n· Specific end use(s) No further relevant information available.\n8 Exposure controls/personal protection\n· Additional information about design of technical systems: No additional data. See 7.\n· Control parameters\n· Components with limit values that require monitoring at the workplace:\nThe following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.\n(Contd. on page 4)\n\n\nPage 4\nPage 4/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 5.0\nProduct name: Zirconia Alumina Abrasive Discs - Belts\n(Contd. of page 3)\n59.1.0\nAt this time, the remaining constituent has no known exposure limits.\n7440-67-7 Zirconia alumina\nPEL\nLong-term value: 5 mg/m³\nas Zr\nREL\nShort-term value: 10 mg/m³\nLong-term value: 5 mg/m³\nas Zr\nTLV\nShort-term value: 10 mg/m³\nLong-term value: 5 mg/m³\nas Zr; A4\n7727-43-7 barium sulphate, natural\nPEL\nLong-term value: 15* 5** mg/m³\n*total dust **respirable fraction\nREL\nLong-term value: 10* 5** mg/m³\n*total dust **respirable fraction\nTLV\nLong-term value: 5* mg/m³\n*inhalable fraction; E\n1317-65-3 Limestone\nPEL\nLong-term value: 15 mg/m³\n557-05-1 zinc distearate, pure\nPEL\nLong-term value: 15* 5** mg/m³\n*total dust **respirable fraction\nREL\nLong-term value: 10* 5** mg/m³\n*total dust **respirable fraction\nTLV\nLong-term value: 10* 3** mg/m³\n*inhalable, **respirable particulate matter, *A4\n1332-58-7 Kaolin\nPEL\nLong-term value: 15* 5** mg/m³\n*total dust **respirable fraction\nREL\nLong-term value: 10* 5** mg/m³\n*total dust **respirable fraction\nTLV\nLong-term value: 2* mg/m³\nE; respirable particulate matter, A4\n7778-18-9 calcium sulphate, natural\nPEL\nLong-term value: 15* 5** mg/m³\n*total dust **respirable fraction\nREL\nLong-term value: 10* 5** mg/m³\n*total dust **respirable fraction\nTLV\nLong-term value: 10* mg/m³\n*as inhalable fraction\n107-21-1 ethylene glycol\nTLV\nShort-term value: 10** mg/m³, 50* ppm\nLong-term value: 25* ppm\n*vapor fraction:**inh. fraction, aerosol only, A4\nWEEL I (2)\n1309-37-1 diiron trioxide\nPEL\nLong-term value: 10* mg/m³\n*Fume\n(Contd. on page 5)\n\n\nPage 5\nPage 5/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 5.0\nProduct name: Zirconia Alumina Abrasive Discs - Belts\n(Contd. of page 4)\n59.1.0\nREL\nLong-term value: 5 mg/m³\nDust & fume, as Fe\nTLV\nLong-term value: 5* mg/m³\n*Respirable particulate matter, A4\n14075-53-7 potassium tetrafluoroborate\nPEL\nLong-term value: 2.5 mg/m³\nas F\nREL\nLong-term value: 2.5 mg/m³\nas F\nTLV\nLong-term value: 2.5 mg/m³\nas F, A4; BEI\n15096-52-3 cryolite\nPEL\nLong-term value: 2.5 mg/m³\nas F\nREL\nLong-term value: 2.5 mg/m³\nas F\n14808-60-7 Quartz (SiO2)\nPEL\nLong-term value: 0.05* mg/m³\n*resp. dust; 30mg/m3/%SiO2+2\nREL\nLong-term value: 0.05* mg/m³\n*respirable dust; See Pocket Guide App. A\nTLV\nLong-term value: 0.025* mg/m³\n*respirable particulate matter, A2\n· Ingredients with biological limit values:\n14075-53-7 potassium tetrafluoroborate\nBEI 2 mg/L\nMedium: urine\nTime: prior to shift\nParameter: Fluoride (background, nonspecific)\n3 mg/L\nMedium: urine\nTime: end of shift\nParameter: Fluoride (background, nonspecific)\n15096-52-3 cryolite\nBEI 2 mg/L\nMedium: urine\nTime: prior to shift\nParameter: Fluoride (background, nonspecific)\n3 mg/L\nMedium: urine\nTime: end of shift\nParameter: Fluoride (background, nonspecific)\n· Exposure controls\n· Personal protective equipment:\n· General protective and hygienic measures:\nKeep away from foodstuffs, beverages and feed.\nWash hands before breaks and at the end of work.\nStore protective clothing separately.\n· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.\n· Protection of hands: Not required.\n(Contd. on page 6)\n\n\nPage 6\nPage 6/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 5.0\nProduct name: Zirconia Alumina Abrasive Discs - Belts\n(Contd. of page 5)\n59.1.0\n· Eye protection:\nTightly sealed goggles\n9 Physical and chemical properties\n· Information on basic physical and chemical properties\n· General Information\n· Appearance:\nForm:\nBelt\nColor:\nAccording to product specification\n· Odor:\nuncharacteristic\n· Odor threshold:\nNot determined.\n· pH-value:\nNot applicable.\n· Change in condition\nMelting point/Melting range:\nUndetermined.\nBoiling point/Boiling range:\nUndetermined.\n· Flash point:\nNot applicable.\n· Flammability (solid, gaseous):\nNot determined.\n· Decomposition temperature:\nNot determined.\n· Ignition temperature:\nProduct is not selfigniting.\n· Danger of explosion:\nProduct does not present an explosion hazard.\n· Explosion limits:\nLower:\nNot determined.\nUpper:\nNot determined.\n· Vapor pressure:\nNot applicable.\n· Density:\nNot determined.\n· Relative density\nNot determined.\n· Vapor density\nNot applicable.\n· Evaporation rate\nNot applicable.\n· Solubility in / Miscibility with\nWater:\nInsoluble.\n· Partition coefficient (n-octanol/water): Not determined.\n· Viscosity:\nDynamic:\nNot applicable.\nKinematic:\nNot applicable.\n· Solvent content:\nVOC content:\n1.00 %\nSolids content:\n100.0 %\n· Other information\nNo further relevant information available.\n10 Stability and reactivity\n· Reactivity No further relevant information available.\n· Chemical stability\n· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.\n· Possibility of hazardous reactions No dangerous reactions known.\n(Contd. on page 7)\n\n\nPage 7\nPage 7/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 5.0\nProduct name: Zirconia Alumina Abrasive Discs - Belts\n(Contd. of page 6)\n59.1.0\n· Conditions to avoid No further relevant information available.\n· Incompatible materials: No further relevant information available.\n· Hazardous decomposition products: No dangerous decomposition products known.\n11 Toxicological information\n· Information on toxicological effects\n· Acute toxicity:\n· LD/LC50 values that are relevant for classification:\nATE (Acute Toxicity Estimate)\nOral\nLD50\n10,000 mg/kg\nInhalative LC50/4 h 7.69 mg/l\n 1317-65-3 Limestone\nOral\nLD50\n6,450 mg/kg (rat)\nDermal\nLD50\n>2,000 mg/kg (rat)\nInhalative LC50/4 h 3 mg/l (rat)\n557-05-1 zinc distearate, pure\nOral\nLD50\n5,000 mg/kg (rat)\nDermal\nLD50\n>2,000 mg/kg (rabbit)\n13775-53-6 trisodium hexafluoroaluminate\nInhalative LC50/4 h 1.5 mg/l (ATE)\n107-21-1 ethylene glycol\nOral\nLD50\n5,840 mg/kg (rat)\nDermal\nLD50\n9,430 mg/kg (rabbit)\n1309-37-1 diiron trioxide\nOral\nLD50\n>5,000 mg/kg (rat)\n14075-53-7 potassium tetrafluoroborate\nOral\nLD50\n100 mg/kg (ATE)\n15096-52-3 cryolite\nInhalative LC50/4 h 1.5 mg/l (ATE)\n· Primary chemical irritant effect:\n· on the skin: No irritant effect.\n· on the eye: No irritating effect.\n· Sensitization: No sensitizing effects known.\n· Additional toxicological information:\nAbrasive eye irritant\nAbrasive skin irritant\n· Carcinogenic categories\n· IARC (International Agency for Research on Cancer)\n1309-37-1 diiron trioxide\n3 \n14075-53-7 potassium tetrafluoroborate\n3 \n14808-60-7 Quartz (SiO2)\n1 \n· NTP (National Toxicology Program)\n14808-60-7 Quartz (SiO2)\nK \n· OSHA-Ca (Occupational Safety & Health Administration)\nNone of the ingredients is listed.\n(Contd. on page 8)\n\n\nPage 8\nPage 8/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 5.0\nProduct name: Zirconia Alumina Abrasive Discs - Belts\n(Contd. of page 7)\n59.1.0\n12 Ecological information\n· Toxicity\n· Aquatic toxicity: No further relevant information available.\n· Persistence and degradability No further relevant information available.\n· Behavior in environmental systems:\n· Bioaccumulative potential No further relevant information available.\n· Mobility in soil No further relevant information available.\n· Ecotoxical effects:\n· Remark: Harmful to fish\n· Additional ecological information:\n· General notes:\nWater hazard class 1 (Self-assessment): slightly hazardous for water\nDo not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.\nHarmful to aquatic organisms\n· Results of PBT and vPvB assessment\n· PBT: Not applicable.\n· vPvB: Not applicable.\n· Other adverse effects No further relevant information available.\n13 Disposal considerations\n· Waste treatment methods\n· Recommendation: Contact waste processors for recycling information.\n· Uncleaned packagings:\n· Recommendation: Disposal must be made according to official regulations.\n14 Transport information\n· UN-Number\n· DOT, ADN, IMDG, IATA\nnot regulated\n· UN proper shipping name\n· DOT, ADN, IMDG, IATA\nnot regulated\n· Transport hazard class(es)\n· DOT, ADN, IMDG, IATA\n· Class\nnot regulated\n· Packing group\n· DOT, IMDG, IATA\nnot regulated\n· Environmental hazards:\n· Marine pollutant:\nNo\n· Special precautions for user\nNot applicable.\n· Transport in bulk according to Annex II of MARPOL73/78 and\nthe IBC Code\nNot applicable.\n· UN "Model Regulation":\nnot regulated\n15 Regulatory information\n· Safety, health and environmental regulations/legislation specific for the substance or mixture\nNo further relevant information available.\n· Sara\n· Section 355 (extremely hazardous substances):\nNone of the ingredients is listed.\n(Contd. on page 9)\n\n\nPage 9\nPage 9/9\nSafety Data Sheet\nacc. to OSHA HCS\nPrinting date 07/02/2024\nLast revision 06/01/2024\nVersion 5.0\nProduct name: Zirconia Alumina Abrasive Discs - Belts\n(Contd. of page 8)\n59.1.0\n· Section 313 (Specific toxic chemical listings):\n7727-43-7 barium sulphate, natural\n557-05-1 zinc distearate, pure\n107-21-1 ethylene glycol\n· TSCA (Toxic Substances Control Act):\nAll components have the value ACTIVE.\n· Hazardous Air Pollutants\n107-21-1 ethylene glycol\n· Proposition 65\n· Chemicals known to cause cancer:\n14808-60-7 Quartz (SiO2)\n· Chemicals known to cause reproductive toxicity for females:\nNone of the ingredients is listed.\n· Chemicals known to cause reproductive toxicity for males:\nNone of the ingredients is listed.\n· Chemicals known to cause developmental toxicity:\n107-21-1 ethylene glycol\n· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.\n16 Other information\nTo the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties\nand does not establish a contractual legal relationship.\n· Department issuing SDS: Technical Services\n· Contact: Pablo Mendoza\n· Last revision / supersedes version: 06/01/2024 / 4.0\n· Supersedes date: 06/01/2022\n· Abbreviations and acronyms:\nADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by\nRoad)\nIMDG: International Maritime Code for Dangerous Goods\nDOT: US Department of Transportation\nIATA: International Air Transport Association\nEINECS: European Inventory of Existing Commercial Chemical Substances\nELINCS: European List of Notified Chemical Substances\nCAS: Chemical Abstracts Service (division of the American Chemical Society)\nVOC: Volatile Organic Compounds (USA, EU)\nLC50: Lethal concentration, 50 percent\nLD50: Lethal dose, 50 percent\nPBT: Persistent, Bioaccumulative and Toxic\nvPvB: very Persistent and very Bioaccumulative\nOSHA: Occupational Safety & Health\nTLV: Threshold Limit Value\nPEL: Permissible Exposure Limit\nREL: Recommended Exposure Limit\nBEI: Biological Exposure Limit\nAcute Toxicity - Oral 3: Acute toxicity – Category 3\nAcute Toxicity - Inhalation 4: Acute toxicity – Category 4\nSkin Irritation 2: Skin corrosion/irritation – Category 2\nEye Irritation 2A: Serious eye damage/eye irritation – Category 2A\nCarcinogenicity 1A: Carcinogenicity – Category 1A\nSpecific Target Organ Toxicity - Repeated Exposure 1: Specific target organ toxicity (repeated exposure) – Category 1\nAquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2\nAquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3\n· * Data compared to the previous version altered. \n