Diamond Slurry, Alcohol-Based, All Microns1(US)
Also listed as: Diamond Slurry - Alcohol Based
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Page 1 Page 1/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 6.0 59.1.0 * 1 Identification · Product name: Diamond Slurry, Alcohol-Based, All Microns · Part number: 90-3AB0.25 - 90-3AB9 · Application of the substance / the mixture Polishing solution · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Allied High Tech Products Inc. 16207 Carmenita Road USA-Cerritos, CA, 90703 USA info@alliedhightech.com · Information department: Product safety department · Emergency telephone number: During normal opening times: +1 (310) 635-2466 Chemtrec: +1 (202) 483-7616 2 Hazard(s) identification · Classification of the substance or mixture GHS02 Flame Flammable Liquids 2 H225 Highly flammable liquid and vapor. GHS07 Eye Irritation 2A H319 Causes serious eye irritation. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS02 GHS07 · Signal word Danger · Hazard statements Highly flammable liquid and vapor. Causes serious eye irritation. · Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. (Contd. on page 2) Page 2 Page 2/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 6.0 Product name: Diamond Slurry, Alcohol-Based, All Microns (Contd. of page 1) 59.1.0 Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. In case of fire: Use CO2, powder or water spray to extinguish. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. · Hazardous components and components with occupational exposure limits: 64-17-5 ethyl alcohol Flammable Liquids 2, H225 70-80% 67-63-0 isopropyl alcohol Flammable Liquids 2, H225; Eye Irritation 2A, H319; Specific Target Organ Toxicity - Single Exposure 3, H336 10-<20% 57-55-6 propylene glycol 5-10% · Non-hazardous components: 7782-40-3 Diamond ≤1% · Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret. 4 First-aid measures · Description of first aid measures · General information: Immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Immediately rinse with water. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: If symptoms persist consult doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed Disorientation Unconsciousness Headache Dizziness Eye irritation Nausea Eye irritation · Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water with full jet · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: Wear fully protective suit. (Contd. on page 3) Page 3 Page 3/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 6.0 Product name: Diamond Slurry, Alcohol-Based, All Microns (Contd. of page 2) 59.1.0 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Keep away from ignition sources · Environmental precautions: Do not allow product to reach sewage system or any water course. Do not allow to enter sewers/ surface or ground water. Prevent seepage into sewage system, workpits and cellars. Dilute with plenty of water. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section 13. Ensure adequate ventilation. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Handling: · Precautions for safe handling Protect from heat and direct sunlight. Ensure proper ventilation/exhaustion at workplaces. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store in a cool location. No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No additional data. See 7. · Control parameters · Components with limit values that require monitoring at the workplace: 64-17-5 ethyl alcohol PEL Long-term value: 1900 mg/m³, 1000 ppm REL Long-term value: 1900 mg/m³, 1000 ppm TLV Short-term value: 1000 ppm A3 67-63-0 isopropyl alcohol PEL Long-term value: 980 mg/m³, 400 ppm (Contd. on page 4) Page 4 Page 4/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 6.0 Product name: Diamond Slurry, Alcohol-Based, All Microns (Contd. of page 3) 59.1.0 REL Short-term value: 1225 mg/m³, 500 ppm Long-term value: 980 mg/m³, 400 ppm TLV Short-term value: 400 ppm Long-term value: 200 ppm BEI, A4 57-55-6 propylene glycol WEEL Long-term value: 10 mg/m³ · Ingredients with biological limit values: 67-63-0 isopropyl alcohol BEI 40 mg/L Medium: urine Time: end of shift at end of workweek Parameter: Acetone (background, nonspecific) · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin. · Breathing equipment: Not required. Use suitable respiratory protective device in case of insufficient ventilation. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Butyl rubber, BR The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Eye protection: Tightly sealed goggles 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Suspension Color: According to product specification · Odor: Alcohol-like · Odor threshold: Not determined. · pH-value: Not determined. (Contd. on page 5) Page 5 Page 5/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 6.0 Product name: Diamond Slurry, Alcohol-Based, All Microns (Contd. of page 4) 59.1.0 · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 78.3 °C (172.9 °F) · Flash point: 10 °C (50 °F) · Flammability (solid, gaseous): Highly flammable. · Auto igniting: 363 °C (685.4 °F) · Decomposition temperature: Not determined. · Ignition temperature: Product is not selfigniting. · Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. · Explosion limits: Lower: 3.3 Vol % Upper: 19 Vol % · Vapor pressure at 20 °C (68 °F): 66.7 hPa (50 mm Hg) · Density: Not determined. · Relative density Not determined. · Vapor density 1.5 (air =1) · Specific gravity: 0.8 (water = 1) · Evaporation rate Not determined. · Solubility in / Miscibility with Water: Not miscible or difficult to mix. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · Solvent content: Organic solvents: 99.1 % VOC content: 99.14 % Solids content: 0.9 % · Other information No further relevant information available. 10 Stability and reactivity · Reactivity No further relevant information available. · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid Keep away from oxidising agents and acidic substances. Keep away from heat. Keep away from sources of ignition - No smoking. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: Carbon monoxide and carbon dioxide · Additional information: Hazardous decomposition products may form during combustion. (Contd. on page 6) Page 6 Page 6/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 6.0 Product name: Diamond Slurry, Alcohol-Based, All Microns (Contd. of page 5) 59.1.0 11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 64-17-5 ethyl alcohol Oral LD50 7,060 mg/kg (rat) Dermal LD50 15,800 mg/kg (rabbit) Inhalative LC50/4 h 20,000 mg/l (rat) 67-63-0 isopropyl alcohol Oral LD50 5,045 mg/kg (rat) Dermal LD50 12,800 mg/kg (rabbit) Inhalative LC50/4 h 30 mg/l (rat) 57-55-6 propylene glycol Oral LD50 >2,000 mg/kg (rat) Dermal LD50 20,800 mg/kg (rabbit) · Primary chemical irritant effect: · on the skin: No irritant effect. · on the eye: Irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: Abrasive eye irritant · Carcinogenic categories · IARC (International Agency for Research on Cancer) 64-17-5 ethyl alcohol 1 67-63-0 isopropyl alcohol 3 · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation: Contact waste processors for recycling information. (Contd. on page 7) Page 7 Page 7/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 6.0 Product name: Diamond Slurry, Alcohol-Based, All Microns (Contd. of page 6) 59.1.0 · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. 14 Transport information · UN-Number · DOT, IMDG, IATA UN1987 · UN proper shipping name · DOT Alcohols, n.o.s. (Ethanol, Isopropanol) · IMDG ALCOHOLS, N.O.S. (ETHANOL (ETHYL ALCOHOL), ISOPROPANOL (ISOPROPYL ALCOHOL)) · IATA ALCOHOLS, N.O.S. (ETHANOL, ISOPROPANOL (ISOPROPYL ALCOHOL)) · Transport hazard class(es) · DOT · Class 3 Flammable liquids · Label 3 · IMDG, IATA · Class 3 Flammable liquids · Label 3 · Packing group · DOT, IMDG, IATA II · Environmental hazards: · Marine pollutant: No · Special precautions for user Warning: Flammable liquids · Hazard identification number (Kemler code): 33 · EMS Number: F-E,S-D · Stowage Category B · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · DOT · Quantity limitations On passenger aircraft/rail: 5 L On cargo aircraft only: 60 L · Limited quantities (LQ) 1L · Transport category 2 · Tunnel restriction code D/E · IMDG · Limited quantities (LQ) 1L (Contd. on page 8) Page 8 Page 8/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 6.0 Product name: Diamond Slurry, Alcohol-Based, All Microns (Contd. of page 7) 59.1.0 · Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml · UN "Model Regulation": UN 1987 ALCOHOLS, N.O.S. (ETHANOL (ETHYL ALCOHOL), ISOPROPANOL (ISOPROPYL ALCOHOL)), 3, II 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available. · Sara · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): 67-63-0 isopropyl alcohol · TSCA (Toxic Substances Control Act): All components have the value ACTIVE. · Hazardous Air Pollutants None of the ingredients is listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: 64-17-5 ethyl alcohol · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties and does not establish a contractual legal relationship. · Department issuing SDS: Technical Services · Contact: Pablo Mendoza · Last revision / supersedes version: 06/01/2024 / 5.0 · Supersedes date: 06/01/2022 · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit (Contd. on page 9) Page 9 Page 9/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 6.0 Product name: Diamond Slurry, Alcohol-Based, All Microns (Contd. of page 8) 59.1.0 BEI: Biological Exposure Limit Flammable Liquids 2: Flammable liquids – Category 2 Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A Specific Target Organ Toxicity - Single Exposure 3: Specific target organ toxicity (single exposure) – Category 3 · * Data compared to the previous version altered.