GP Cleaning Solution

Refer to the original PDF for tables, figures and page layout.

Page 1
 
Page 1/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
59.1.0
* 1 Identification
· Product name: Cleaning Solution, GP (Undiluted)
· Part number: 95-10230, 95-10235
· Application of the substance / the mixture Alkaline cleaner/ detergent
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Allied High Tech Products Inc.
16207 Carmenita Road
USA-Cerritos, CA, 90703
USA
info@alliedhightech.com
· Information department: Product safety department
· Emergency telephone number:
During normal opening times: +1 (310) 635-2466
Chemtrec: +1 (202) 483-7616
2 Hazard(s) identification
· Classification of the substance or mixture
GHS05 Corrosion
Skin Corrosion 1B H314 Causes severe skin burns and eye damage.
Eye Damage 1
H318 Causes serious eye damage.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
GHS05
· Signal word Danger
· Hazard-determining components of labeling:
disodium metasilicate
· Hazard statements
Causes severe skin burns and eye damage.
· Precautionary statements
Do not breathe dusts or mists.
Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Rinse mouth. Do NOT induce vomiting.
(Contd. on page 2)


Page 2
Page 2/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: Cleaning Solution, GP (Undiluted)
(Contd. of page 1)
59.1.0
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Hazardous components and components with occupational exposure limits:
111-76-2 ethylene glycol monobutyl ether
 Acute Toxicity - Dermal 3, H311; Acute Toxicity - Inhalation 3, H331;
 Acute Toxicity - Oral 4, H302; Skin
Irritation 2, H315; Eye Irritation 2A, H319; Flammable Liquids 4, H227
10%
6834-92-0 disodium metasilicate
 Skin Corrosion 1B, H314;
 Acute Toxicity - Oral 4, H302; Specific Target Organ Toxicity - Single Exposure 3,
H335
5-10%
· Non-hazardous components:
7732-18-5 water, distilled, conductivity or of similar purity
70-80%
· Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.
4 First-aid measures
· Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: Drink copious amounts of water and provide fresh air. Immediately call a doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
Dermatitis
Eye irritation
· Indication of any immediate medical attention and special treatment needed No further relevant information available.
5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
Alcohol resistant foam
Carbon dioxide
Fire-extinguishing powder
Water spray
Use fire fighting measures that suit the environment.
· Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced.
· Advice for firefighters
· Protective equipment: Wear fully protective suit.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Keep away from ignition sources
· Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
(Contd. on page 3)


Page 3
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: Cleaning Solution, GP (Undiluted)
(Contd. of page 2)
59.1.0
Dilute with plenty of water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling
Ensure proper ventilation/exhaustion at workplaces.
Prevent formation of aerosols.
· Information about protection against explosions and fires: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a cool location.
No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep away from heat.
Keep receptacle tightly sealed.
Store receptacle in a well ventilated area.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical systems: No additional data. See 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit.
At this time, the remaining constituent has no known exposure limits.
111-76-2 ethylene glycol monobutyl ether
PEL Long-term value: 240 mg/m³, 50 ppm
Skin
REL Long-term value: 24 mg/m³, 5 ppm
Skin
TLV Long-term value: 20 ppm
BEI, A3
· Ingredients with biological limit values:
111-76-2 ethylene glycol monobutyl ether
BEI 200 mg/g creatinine
Medium: urine
Time: end of shift
Parameter: Butoxyacetic acid (BAA) (with hydrolysis)
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
(Contd. on page 4)


Page 4
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: Cleaning Solution, GP (Undiluted)
(Contd. of page 3)
59.1.0
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
Neoprene gloves
Nitrile rubber, NBR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer
to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance
and has therefore to be checked prior to the application.
· Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form:
Liquid
Color:
Red
· Odor:
Butyl-like
· Odor threshold:
Not determined.
· pH-value at 20 °C (68 °F):
12-13
· Change in condition
Melting point/Melting range:
Undetermined.
Boiling point/Boiling range:
Undetermined.
· Flash point:
Not applicable.
· Flammability (solid, gaseous):
Not applicable.
· Decomposition temperature:
Not determined.
· Ignition temperature:
Product is not selfigniting.
· Danger of explosion:
Product does not present an explosion hazard.
· Explosion limits:
Lower:
Not determined.
Upper:
Not determined.
· Vapor pressure at 20 °C (68 °F):
23 hPa (17.3 mm Hg)
· Density at 20 °C (68 °F):
1.06 g/cm³ (8.846 lbs/gal)
· Relative density
Not determined.
· Vapor density
Not determined.
· Evaporation rate
Not determined.
(Contd. on page 5)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: Cleaning Solution, GP (Undiluted)
(Contd. of page 4)
59.1.0
· Solubility in / Miscibility with
Water:
Fully miscible.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Not determined.
Kinematic:
Not determined.
· Solvent content:
Organic solvents:
10.0 %
Water:
80.0 %
VOC content:
10.00 %
· Other information
No further relevant information available.
10 Stability and reactivity
· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid
Keep away from oxidising agents and acidic substances.
Keep away from open flames. - No smoking.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: Carbon monoxide and carbon dioxide
· Additional information: Hazardous decomposition products may form during combustion.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
ATE (Acute Toxicity Estimate)
Oral
LD50
6,194 mg/kg
Dermal
LD50
4,000 mg/kg (rabbit)
Inhalative LC50/4 h 22 mg/l (ATE)
  111-76-2 ethylene glycol monobutyl ether
Oral
LD50
1,200 mg/kg (ATE)
1,480 mg/kg (rat)
Dermal
LD50
400 mg/kg (rabbit)
Inhalative LC50/4 h 3 mg/l (ATE)
2.2 mg/l (rat)
6834-92-0 disodium metasilicate
Oral
LD50
1,280 mg/kg (rat)
· Primary chemical irritant effect:
· on the skin: Caustic effect on skin and mucous membranes.
· on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.
(Contd. on page 6)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: Cleaning Solution, GP (Undiluted)
(Contd. of page 5)
59.1.0
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
111-76-2 ethylene glycol monobutyl ether
3 
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
· Toxicity
· Aquatic toxicity:
111-76-2 ethylene glycol monobutyl ether
EC50 (48 h) (static) 1,550 mg/l (daphnia)
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high pH-value harms aquatic
organisms. In the dilution of the use-level the pH-value is considerably reduced, so that after the use of the product the aqueous waste,
emptied into drains, is only low water-dangerous.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation: Contact waste processors for recycling information.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agent: Water, if necessary with cleansing agents.
14 Transport information
· UN-Number
· DOT, IMDG, IATA
UN3266
· UN proper shipping name
· DOT
Corrosive liquid, basic, inorganic, n.o.s. (Disodium trioxosilicate)
· IMDG, IATA
CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (DISODIUM
TRIOXOSILICATE)
(Contd. on page 7)


Page 7
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: Cleaning Solution, GP (Undiluted)
(Contd. of page 6)
59.1.0
· Transport hazard class(es)
· DOT
· Class
8 Corrosive substances
· Label
8 
· IMDG, IATA
· Class
8 Corrosive substances
· Label
8 
· Packing group
· DOT, IMDG, IATA
I 
· Environmental hazards:
· Marine pollutant:
No
· Special precautions for user
Warning: Corrosive substances
· Hazard identification number (Kemler code):
88
· EMS Number:
F-A,S-B
· Segregation groups
(SGG18) Alkalis
· Stowage Category
B 
· Stowage Code
SW2 Clear of living quarters.
· Segregation Code
SG35 Stow "separated from" acids.
· Transport in bulk according to Annex II of MARPOL73/78 and
the IBC Code
Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations
On passenger aircraft/rail: 0.5 L
On cargo aircraft only: 2.5 L
· Limited quantities (LQ)
0 
· Transport category
1 
· Tunnel restriction code
E 
· IMDG
· Limited quantities (LQ)
0 
· Excepted quantities (EQ)
Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation":
UN 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
(DISODIUM TRIOXOSILICATE), 8, I
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
(Contd. on page 8)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: Cleaning Solution, GP (Undiluted)
(Contd. of page 7)
59.1.0
· Section 313 (Specific toxic chemical listings):
111-76-2 ethylene glycol monobutyl ether
· TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
· Hazardous Air Pollutants
None of the ingredients is listed.
· Proposition 65
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties
and does not establish a contractual legal relationship.
· Department issuing SDS: Technical Services
· Contact: Pablo Mendoza
· Last revision / supersedes version: 06/01/2024 / 3.0
· Supersedes date: 06/01/2022
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by
Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Flammable Liquids 4: Flammable liquids – Category 4
Acute Toxicity - Oral 4: Acute toxicity – Category 4
Acute Toxicity - Dermal 3: Acute toxicity – Category 3
Skin Corrosion 1B: Skin corrosion/irritation – Category 1B
Skin Irritation 2: Skin corrosion/irritation – Category 2
Eye Damage 1: Serious eye damage/eye irritation – Category 1
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
Specific Target Organ Toxicity - Single Exposure 3: Specific target organ toxicity (single exposure) – Category 3
· * Data compared to the previous version altered.