TP Silicone Resin Cartridges - Green Light, Black1(US)
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Page 1 Page 1/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/03/2024 Last revision 06/01/2024 Version 3.0 59.1.0 * 1 Identification · Product name: TP Silicone Resin Cartridges - Green/Light, Black · Part number: 145-81005, 145-81000 · Application of the substance / the mixture Resin · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Allied High Tech Products Inc. 16207 Carmenita Road USA-Cerritos, CA, 90703 USA info@alliedhightech.com · Information department: Product safety department · Emergency telephone number: During normal opening times: +1 (310) 635-2466 Chemtrec: +1 (202) 483-7616 2 Hazard(s) identification · Classification of the substance or mixture GHS08 Health hazard Specific Target Organ Toxicity - Repeated Exposure 1 H372 Causes damage to organs through prolonged or repeated exposure. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS08 · Signal word Danger · Hazard statements Causes damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects. · Precautionary statements Do not breathe dust/fume/gas/mist/vapors/spray. Avoid release to the environment. [In case of inadequate ventilation] wear respiratory protection. If experiencing respiratory symptoms: Call a poison center/doctor. (Contd. on page 2) Page 2 Page 2/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/03/2024 Last revision 06/01/2024 Version 3.0 Product name: TP Silicone Resin Cartridges - Green/Light, Black (Contd. of page 1) 59.1.0 Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients · CAS No. Description Polyvinyl siloxane · Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. · Hazardous components and components with occupational exposure limits: 14464-46-1 cristobalite Carcinogenicity 1A, H350 20-50% 556-67-2 octamethylcyclotetrasiloxane Flammable Liquids 3, H226; Toxic to Reproduction 2, H361; Aquatic Chronic 1, H410 PBT; vPvB 0.1-<0.25% 4 First-aid measures · Description of first aid measures · General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Generally the product does not irritate the skin. · After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: If symptoms persist consult doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. · Advice for firefighters · Protective equipment: No special measures required. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Keep away from ignition sources · Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Dilute with plenty of water. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section 13. Ensure adequate ventilation. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Handling: · Precautions for safe handling Ensure proper ventilation/exhaustion at workplaces. Prevent formation of aerosols. · Information about protection against explosions and fires: No special measures required. (Contd. on page 3) Page 3 Page 3/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/03/2024 Last revision 06/01/2024 Version 3.0 Product name: TP Silicone Resin Cartridges - Green/Light, Black (Contd. of page 2) 59.1.0 · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store in a cool location. No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Store receptacle in a well ventilated area. · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No additional data. See 7. · Control parameters · Components with limit values that require monitoring at the workplace: 14464-46-1 cristobalite PEL Long-term value: 0.05* mg/m³ *resp. dust;½ value from resp.dust formulae Quartz REL Long-term value: 0.05* mg/m³ *respirable dust; See Pocket Guide App. A TLV Long-term value: 0.025* mg/m³ *respirable particulate matter, A2 556-67-2 octamethylcyclotetrasiloxane WEEL Long-term value: 10* ppm *OARS WEEL · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Store protective clothing separately. · Breathing equipment: Use suitable respiratory protective device when high concentrations are present. · Protection of hands: Not required. · Eye protection: Tightly sealed goggles 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Pasty Color: According to product specification · Odor: Odorless · Odor threshold: Not determined. · pH-value: Not determined. · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 175 °C (347 °F) (Contd. on page 4) Page 4 Page 4/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/03/2024 Last revision 06/01/2024 Version 3.0 Product name: TP Silicone Resin Cartridges - Green/Light, Black (Contd. of page 3) 59.1.0 · Flash point: 51 °C (123.8 °F) · Flammability (solid, gaseous): Not applicable. · Auto igniting: 384 °C (723.2 °F) · Decomposition temperature: Not determined. · Ignition temperature: Product is not selfigniting. · Danger of explosion: Product does not present an explosion hazard. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapor pressure at 25 °C (77 °F): 1.3 hPa (1 mm Hg) · Density at 20 °C (68 °F): 1.6 g/cm³ (13.352 lbs/gal) · Relative density Not determined. · Vapor density Not determined. · Evaporation rate Not determined. · Solubility in / Miscibility with Water: Not miscible or difficult to mix. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · Solvent content: VOC content: 0.00 % Solids content: 100.0 % · Other information No further relevant information available. 10 Stability and reactivity · Reactivity No further relevant information available. · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: Oral LD50 >5,000 mg/kg (rat) · Primary chemical irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known. (Contd. on page 5) Page 5 Page 5/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/03/2024 Last revision 06/01/2024 Version 3.0 Product name: TP Silicone Resin Cartridges - Green/Light, Black (Contd. of page 4) 59.1.0 · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) 14464-46-1 cristobalite 1 · NTP (National Toxicology Program) 14464-46-1 cristobalite K · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Harmful to fish · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Harmful to aquatic organisms · Results of PBT and vPvB assessment · PBT: 556-67-2 octamethylcyclotetrasiloxane · vPvB: 556-67-2 octamethylcyclotetrasiloxane · Other adverse effects No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation: Contact waste processors for recycling information. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. 14 Transport information · UN-Number · DOT, IMDG, IATA not regulated · UN proper shipping name · DOT, ADN, IMDG, IATA not regulated · Transport hazard class(es) · DOT, ADN, IMDG, IATA · Class not regulated · Packing group · DOT, IMDG, IATA not regulated · Environmental hazards: Not applicable. (Contd. on page 6) Page 6 Page 6/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/03/2024 Last revision 06/01/2024 Version 3.0 Product name: TP Silicone Resin Cartridges - Green/Light, Black (Contd. of page 5) 59.1.0 · Special precautions for user Not applicable. · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · UN "Model Regulation": not regulated 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available. · Sara · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All components have the value ACTIVE. · Hazardous Air Pollutants None of the ingredients is listed. · Proposition 65 · Chemicals known to cause cancer: 14464-46-1 cristobalite · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties and does not establish a contractual legal relationship. · Department issuing SDS: Technical Services · Contact: Pablo Mendoza · Last revision / supersedes version: 06/01/2024 / 2.0 · Supersedes date: 09/27/2023 · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit (Contd. on page 7) Page 7 Page 7/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/03/2024 Last revision 06/01/2024 Version 3.0 Product name: TP Silicone Resin Cartridges - Green/Light, Black (Contd. of page 6) 59.1.0 Flammable Liquids 3: Flammable liquids – Category 3 Carcinogenicity 1A: Carcinogenicity – Category 1A Toxic to Reproduction 2: Reproductive toxicity – Category 2 Specific Target Organ Toxicity - Repeated Exposure 1: Specific target organ toxicity (repeated exposure) – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3 · * Data compared to the previous version altered.