Acrylic Tinting/Dye Concentrate

Refer to the original PDF for tables, figures and page layout.

Page 1
 
Page 1/9
Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
59.1.0
* 1 Identification
· Product name: Acrylic Tinting Concentrate
· Part number: 170-21000, 170-21005, 170-21010, 170-21015
· Application of the substance / the mixture
Tinting concentrate
Additive
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Allied High Tech Products Inc.
16207 Carmenita Road
USA-Cerritos, CA, 90703
USA
info@alliedhightech.com
· Information department: Product safety department
· Emergency telephone number:
During normal opening times: +1 (310) 635-2466
Chemtrec: +1 (202) 483-7616
* 2 Hazard(s) identification
· Classification of the substance or mixture
GHS02 Flame
Flammable Liquids 2
H225 Highly flammable liquid and vapor.
GHS07
Skin Irritation 2
H315 Causes skin irritation.
Sensitization - Skin 1
H317 May cause an allergic skin reaction.
Specific Target Organ Toxicity - Single Exposure 3 H335 May cause respiratory irritation.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
GHS02
GHS07
· Signal word Danger
(Contd. on page 2)


Page 2
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Acrylic Tinting Concentrate
(Contd. of page 1)
59.1.0
· Hazard-determining components of labeling:
methyl methacrylate
· Hazard statements
Highly flammable liquid and vapor.
Causes skin irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
· Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep cool.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a poison center/doctor if you feel unwell.
If skin irritation or rash occurs: Get medical advice/attention.
Take off contaminated clothing.
In case of fire: Use CO2, powder or water spray to extinguish.
Store in a well-ventilated place. Keep container tightly closed.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Hazardous components and components with occupational exposure limits:
80-62-6 methyl methacrylate
 Flammable Liquids 2, H225;
 Acute Toxicity - Inhalation 4, H332; Skin Irritation 2, H315; Sensitization - Skin 1,
H317; Specific Target Organ Toxicity - Single Exposure 3, H335
>95%
99-97-8 N,N-dimethyl-p-toluidine
 Acute Toxicity - Oral 3, H301; Acute Toxicity - Dermal 3, H311; Acute Toxicity - Inhalation 3, H331;
 Carcinogenicity 2, H351; Specific Target Organ Toxicity - Repeated Exposure 2, H373; Flammable Liquids 4, H227;
Aquatic Chronic 3, H412
<2%
· Non-hazardous components:
Dye
<2%
· Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.
4 First-aid measures
· Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: Rinse out mouth and then drink plenty of water.
(Contd. on page 3)


Page 3
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Acrylic Tinting Concentrate
(Contd. of page 2)
59.1.0
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
Headache
Dizziness
Allergic reactions
Nausea
Dermatitis
· Indication of any immediate medical attention and special treatment needed No further relevant information available.
5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: Wear fully protective suit.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
· Environmental precautions:
Prevent seepage into sewage system, workpits and cellars.
Dilute with plenty of water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling
Protect from heat and direct sunlight.
Ensure proper ventilation/exhaustion at workplaces.
Prevent formation of aerosols.
· Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store at temperatures not exceeding 25°C.
· Information about storage in one common storage facility:
Store away from oxidizing agents.
Store away from reducing agents.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Store receptacle in a well ventilated area.
· Specific end use(s) No further relevant information available.
(Contd. on page 4)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Acrylic Tinting Concentrate
(Contd. of page 3)
59.1.0
8 Exposure controls/personal protection
· Additional information about design of technical systems: No additional data. See 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
80-62-6 methyl methacrylate
PEL
Long-term value: 410 mg/m³, 100 ppm
REL
Long-term value: 410 mg/m³, 100 ppm
TLV
Short-term value: 100 ppm
Long-term value: 50 ppm
DSEN, A4
99-97-8 N,N-dimethyl-p-toluidine
WEEL Long-term value: 0.5 ppm
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.
· Protection of hands:
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer
to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance
and has therefore to be checked prior to the application.
· Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form:
Liquid
Color:
According to product specification
· Odor:
Acrid
· Odor threshold:
Not determined.
· pH-value:
Not determined.
(Contd. on page 5)


Page 5
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Acrylic Tinting Concentrate
(Contd. of page 4)
59.1.0
· Change in condition
Melting point/Melting range:
-48 °C (-54.4 °F)
Boiling point/Boiling range:
101 °C (213.8 °F)
· Flash point:
11.5 °C (52.7 °F)
· Flammability (solid, gaseous):
Highly flammable.
· Auto igniting:
430 °C (806 °F)
· Decomposition temperature:
Not determined.
· Ignition temperature:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive. However, formation of explosive air/vapor mixtures are possible.
· Explosion limits:
Lower:
2.1 Vol %
Upper:
12.5 Vol %
· Vapor pressure at 20 °C (68 °F):
47 hPa (35.3 mm Hg)
· Density at 20 °C (68 °F):
0.94 g/cm³ (7.844 lbs/gal)
· Relative density
Not determined.
· Vapor density at 15.5 °C (59.9 °F)
3.5 (Air = 1)
· Specific gravity:
0.949 (Water = 1)
· Evaporation rate
3.1 (BuAc =1)
· Solubility in / Miscibility with
Water at 20 °C (68 °F):
1.6 g/l
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Not determined.
Kinematic:
Not determined.
· Solvent content:
VOC content:
0.00 %
· Other information
No further relevant information available.
10 Stability and reactivity
· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions Danger of polymerization.
· Conditions to avoid
Protect from sunlight.
Keep away from oxidising agents and acidic substances.
Freezing conditions
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: Carbon monoxide and carbon dioxide
· Additional information: Hazardous decomposition products may form during combustion.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
ATE (Acute Toxicity Estimate)
Oral
LD50
165,000 mg/kg (rat)
(Contd. on page 6)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Acrylic Tinting Concentrate
(Contd. of page 5)
59.1.0
Dermal
LD50
30,000 mg/kg
Inhalative LC50/4 h 16.2 mg/l (rat)
  80-62-6 methyl methacrylate
Oral
LD50
7,872 mg/kg (rat)
Dermal
LD50
5,000 mg/kg (rabbit)
Inhalative LC50/4 h 18 mg/l (rat)
99-97-8 N,N-dimethyl-p-toluidine
Oral
LD50
1,650 mg/kg (rat)
Dermal
LD50
300 mg/kg (ATE)
Inhalative LC50/4 h 1.4 mg/l (rat)
· Primary chemical irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: No irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
80-62-6 methyl methacrylate
3 
99-97-8 N,N-dimethyl-p-toluidine
2B
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
· Toxicity
· Aquatic toxicity:
80-62-6 methyl methacrylate
EC50 (96 h) 170 mg/l (pseudokirchneriella subcapitata)
EC50 (48 h) 69 mg/l (daphnia)
LC50 (96 h) 79 mg/l (oncorhynchus mykiss)
99-97-8 N,N-dimethyl-p-toluidine
LC50 (96 h) 46 mg/l (pimephales promelas)
· Persistence and degradability Not easily biodegradable
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil Potential for mobility in soil is very high.
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
(Contd. on page 7)


Page 7
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Acrylic Tinting Concentrate
(Contd. of page 6)
59.1.0
13 Disposal considerations
· Waste treatment methods
· Recommendation: Contact waste processors for recycling information.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
· UN-Number
· DOT, IMDG, IATA
UN1993
· UN proper shipping name
· DOT
Flammable liquids, n.o.s. (Methyl methacrylate monomer, stabilized)
· IMDG, IATA
FLAMMABLE LIQUID, N.O.S. (METHYL METHACRYLATE
MONOMER, STABILIZED)
· Transport hazard class(es)
· DOT
· Class
3 Flammable liquids
· Label
3 
· IMDG, IATA
· Class
3 Flammable liquids
· Label
3 
· Packing group
· DOT, IMDG, IATA
II
· Environmental hazards:
· Marine pollutant:
No
· Special precautions for user
Warning: Flammable liquids
· Hazard identification number (Kemler code):
33
· EMS Number:
F-E,S-E
· Stowage Category
B 
· Transport in bulk according to Annex II of MARPOL73/78 and
the IBC Code
Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations
On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
· Limited quantities (LQ)
1L
· Transport category
2 
· Tunnel restriction code
D/E
(Contd. on page 8)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Acrylic Tinting Concentrate
(Contd. of page 7)
59.1.0
· IMDG
· Limited quantities (LQ)
1L
· Excepted quantities (EQ)
Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· UN "Model Regulation":
UN 1993 FLAMMABLE LIQUID, N.O.S. (METHYL
METHACRYLATE MONOMER, STABILIZED), 3, II
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
80-62-6 methyl methacrylate
· TSCA (Toxic Substances Control Act):
All other ingredients are exempt from listing.
All components have the value ACTIVE.
· Hazardous Air Pollutants
80-62-6 methyl methacrylate
· Proposition 65
· Chemicals known to cause cancer:
99-97-8 N,N-dimethyl-p-toluidine
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties
and does not establish a contractual legal relationship.
· Department issuing SDS: Technical Services
· Contact: Pablo Mendoza
· Last revision / supersedes version: 06/01/2024 / 5.1
· Supersedes date: 06/01/2022
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by
Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
OSHA: Occupational Safety & Health
(Contd. on page 9)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Acrylic Tinting Concentrate
(Contd. of page 8)
59.1.0
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flammable Liquids 2: Flammable liquids – Category 2
Flammable Liquids 4: Flammable liquids – Category 4
Acute Toxicity - Oral 3: Acute toxicity – Category 3
Acute Toxicity - Inhalation 4: Acute toxicity – Category 4
Skin Irritation 2: Skin corrosion/irritation – Category 2
Sensitization - Skin 1: Skin sensitisation – Category 1
Carcinogenicity 2: Carcinogenicity – Category 2
Specific Target Organ Toxicity - Single Exposure 3: Specific target organ toxicity (single exposure) – Category 3
Specific Target Organ Toxicity - Repeated Exposure 2: Specific target organ toxicity (repeated exposure) – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered.