Phenolic Mounting Powder (Red, Black, Green)

Refer to the original PDF for tables, figures and page layout.

Page 1
 
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
59.1.0
* 1 Identification
· Product name: Phenolic Mounting Powder - Red, Black, Green
· Part number: 135-10005, 135-10007, 135-10010, 135-10012, 135-10015, 135-10017, Preforms
· Application of the substance / the mixture Thermoset molding
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Allied High Tech Products Inc.
16207 Carmenita Road
USA-Cerritos, CA, 90703
USA
info@alliedhightech.com
· Information department: Product safety department
· Emergency telephone number:
During normal opening times: +1 (310) 635-2466
Chemtrec: +1 (202) 483-7616
2 Hazard(s) identification
· Classification of the substance or mixture
GHS08 Health hazard
Germ Cell Mutagenicity 2
H341 Suspected of causing genetic defects.
Carcinogenicity 2
H351 Suspected of causing cancer.
Specific Target Organ Toxicity - Repeated Exposure 2 H373 May cause damage to the central nervous system, the kidneys, the liver, the
heart and the respiratory system through prolonged or repeated exposure.
GHS07
Skin Irritation 2
H315 Causes skin irritation.
Eye Irritation 2A
H319 Causes serious eye irritation.
Sensitization - Skin 1
H317 May cause an allergic skin reaction.
Combustible Dust
  
May form combustible dust concentrations in air.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Phenolic Mounting Powder - Red, Black, Green
(Contd. of page 1)
59.1.0
· Hazard pictograms
GHS07
GHS08
· Signal word Warning
· Hazard-determining components of labeling:
methenamine
Carbon black
phenol
· Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
Suspected of causing cancer.
May cause damage to the central nervous system, the kidneys, the liver, the heart and the respiratory system through prolonged or repeated
exposure.
May form combustible dust concentrations in air.
· Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin: Wash with plenty of water.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
* 3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Hazardous components and components with occupational exposure limits:
12001-26-2 Mica
0-60%
Wood flour
0-60%
1332-58-7 Kaolin
0-40%
7782-42-5 Graphite
0-40%
14807-96-6 Talc (Mg3H2(SiO3)4)
0-20%
Coal dust
0-18%
100-97-0 methenamine
 Flammable Solids 2, H228;
 Sensitization - Skin 1, H317
2-15%
(Contd. on page 3)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Phenolic Mounting Powder - Red, Black, Green
(Contd. of page 2)
59.1.0
1333-86-4 Carbon black
 Self-heating substances and mixtures 2, H252;
 Carcinogenicity 2, H351
0-12%
1305-62-0 calcium dihydroxide
 Skin Corrosion 1B, H314; Eye Damage 1, H318
0-10%
108-95-2 phenol
 Acute Toxicity - Oral 3, H301; Acute Toxicity - Dermal 3, H311; Acute Toxicity - Inhalation 3, H331;
 Germ
Cell Mutagenicity 2, H341; Specific Target Organ Toxicity - Repeated Exposure 2, H373;
 Skin Corrosion 1B,
H314
<3.5%
50-00-0 formaldehyde
 Acute Toxicity - Oral 3, H301; Acute Toxicity - Dermal 3, H311; Acute Toxicity - Inhalation 3, H331;
 Germ
Cell Mutagenicity 2, H341; Carcinogenicity 1A, H350;
 Skin Corrosion 1B, H314;
 Sensitization - Skin 1,
H317; Flammable Liquids 4, H227
<0.1%
· Non-hazardous components:
9003-35-4 Phenolic Polymer
30-60%
· Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.
4 First-aid measures
· Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
Breathing difficulty
Coughing
Allergic reactions
Dermatitis
Eye irritation
· Indication of any immediate medical attention and special treatment needed No further relevant information available.
5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents: Use fire fighting measures that suit the environment.
· Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced.
· Advice for firefighters
· Protective equipment: No special measures required.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures Keep away from ignition sources
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
(Contd. on page 4)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Phenolic Mounting Powder - Red, Black, Green
(Contd. of page 3)
59.1.0
7 Handling and storage
· Handling:
· Precautions for safe handling
Ensure proper ventilation/exhaustion at workplaces.
Open and handle receptacle with care.
· Information about protection against explosions and fires: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store at temperatures not exceeding 30°C.
Store only in the original receptacle.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Store receptacle in a well ventilated area.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical systems: No additional data. See 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
12001-26-2 Mica
PEL Long-term value: 20 mppcf ppm
<1% crystalline silica
REL Long-term value: 3* mg/m³
*respirable dust; containing < 1% quartz
TLV Long-term value: 0.1 mg/m³
*Respirable particulate matter
Wood flour
PEL Long-term value: 15 mg/m³
1332-58-7 Kaolin
PEL Long-term value: 15* 5** mg/m³
*total dust **respirable fraction
REL Long-term value: 10* 5** mg/m³
*total dust **respirable fraction
TLV Long-term value: 2* mg/m³
E; respirable particulate matter, A4
7782-42-5 Graphite
PEL Long-term value: 15 mppcf* mg/m³
*impinger samples counted by light field techn.
REL Long-term value: 2.5* mg/m³
*respirable dust
TLV Long-term value: 2* mg/m³
all forms except graphite fibers;*resp. fraction
14807-96-6 Talc (Mg3H2(SiO3)4)
PEL Long-term value: 20 mppcf ppm
(containing <1% Quartz)
(Contd. on page 5)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Phenolic Mounting Powder - Red, Black, Green
(Contd. of page 4)
59.1.0
REL Long-term value: 2* mg/m³
*respirable dust; and <1% Quartz
TLV Long-term value: 2* mg/m³
*no asbestos fibers,resp. particulate matter,E,A4
Coal dust
PEL Long-term value: 10 mg/m³
100-97-0 methenamine
TLV Long-term value: 1 mg/m³
*inhalable fraction, A4, DSEN
1333-86-4 Carbon black
PEL Long-term value: 3.5 mg/m³
REL Long-term value: 3.5* mg/m³
*0.1 in presence of PAHs;See Pocket Guide Apps.A+C
TLV Long-term value: 3* mg/m³
*inhalable fraction, A3
1305-62-0 calcium dihydroxide
PEL Long-term value: 15* 5** mg/m³
*total dust **respirable fraction
REL Long-term value: 5 mg/m³
TLV Long-term value: 5 mg/m³
108-95-2 phenol
PEL Long-term value: 19 mg/m³, 5 ppm
Skin
REL Long-term value: 19 mg/m³, 5 ppm
Ceiling limit value: 60* mg/m³, 15.6* ppm
*15-min; Skin
TLV Long-term value: 5 ppm
Skin; BEI, A4
50-00-0 formaldehyde
PEL Short-term value: 2 ppm
Long-term value: 0.75 ppm
see 29 CFR 1910.1048(c)
REL Long-term value: 0.016 ppm
Ceiling limit value: 0.1* ppm
*15-min; See Pocket Guide App. A
TLV Short-term value: 0.3 ppm
Long-term value: 0.1 ppm
DSEN; RSEN, A1
· Ingredients with biological limit values:
108-95-2 phenol
BEI 250 mg/g creatinine
Medium: urine
Time: end of shift
Parameter: Phenol with hydrolysis (background, nonspecific)
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
(Contd. on page 6)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Phenolic Mounting Powder - Red, Black, Green
(Contd. of page 5)
59.1.0
Store protective clothing separately.
Avoid contact with the eyes and skin.
· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.
· Protection of hands:
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer
to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance
and has therefore to be checked prior to the application.
· Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form:
Powder
Color:
According to product specification
· Odor:
Phenol-like
· Odor threshold:
Not determined.
· pH-value:
Not applicable.
· Change in condition
Melting point/Melting range:
Undetermined.
Boiling point/Boiling range:
Undetermined.
· Flash point:
Not applicable.
· Flammability (solid, gaseous):
Not determined.
· Decomposition temperature:
Not determined.
· Ignition temperature:
Product is not selfigniting.
· Danger of explosion:
Product does not present an explosion hazard.
· Explosion limits:
Lower:
Dust 0.03 oz per cubic foot
Upper:
Not determined.
· Vapor pressure:
Not applicable.
· Density at 20 °C (68 °F):
0.6 g/cm³ (5.007 lbs/gal)
· Relative density
Not determined.
· Vapor density
Not applicable.
· Specific gravity at 20 °C (68 °F):
1.39 g/cm³ (11.6 lbs/gal)
· Evaporation rate
Not applicable.
· Solubility in / Miscibility with
Water:
Insoluble.
(Contd. on page 7)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Phenolic Mounting Powder - Red, Black, Green
(Contd. of page 6)
59.1.0
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Not applicable.
Kinematic:
Not applicable.
· Solvent content:
Organic solvents:
1.1 %
VOC content:
1.06 %
Solids content:
100.0 %
· Other information
No further relevant information available.
10 Stability and reactivity
· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid
Keep away from oxidising agents and acidic substances.
Keep away from heat.
Keep away from open flames. - No smoking.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Formaldehyde
Phenol
Ammonia
· Additional information: Hazardous decomposition products may form during combustion.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
Oral
LD50
>5,000 mg/kg (rat)
Dermal
LD50
>5,000 mg/kg (rabbit)
  1333-86-4 Carbon black
Oral
LD50
10,000 mg/kg (rat)
1305-62-0 calcium dihydroxide
Oral
LD50
7,340 mg/kg (rat)
108-95-2 phenol
Oral
LD50
317 mg/kg (rat)
Dermal
LD50
850 mg/kg (rabbit)
Inhalative LC50/4 h 0.5 mg/l (ATE)
50-00-0 formaldehyde
Oral
LD50
>200 mg/kg (rat)
Dermal
LD50
270 mg/kg (rabbit)
Inhalative LC50/4 h 3 mg/l (ATE)
· Primary chemical irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: Irritating effect.
(Contd. on page 8)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Phenolic Mounting Powder - Red, Black, Green
(Contd. of page 7)
59.1.0
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
14807-96-6 Talc (Mg3H2(SiO3)4)
3 
1333-86-4 Carbon black
2B
108-95-2 phenol
3 
50-00-0 formaldehyde
1 
· NTP (National Toxicology Program)
50-00-0 formaldehyde
K 
· OSHA-Ca (Occupational Safety & Health Administration)
50-00-0 formaldehyde
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation: Contact waste processors for recycling information.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· DOT, ADN, IMDG, IATA
not regulated
· UN proper shipping name
· DOT, ADN, IMDG, IATA
not regulated
· Transport hazard class(es)
· DOT, IMDG, IATA
· Class
not regulated
· Label
- 
· ADN/R Class:
not regulated
· Packing group
· DOT, IMDG, IATA
not regulated
(Contd. on page 9)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Phenolic Mounting Powder - Red, Black, Green
(Contd. of page 8)
59.1.0
· Environmental hazards:
· Marine pollutant:
No
· Special precautions for user
Not applicable.
· Transport in bulk according to Annex II of MARPOL73/78 and
the IBC Code
Not applicable.
· UN "Model Regulation":
not regulated
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
108-95-2 phenol
50-00-0 formaldehyde
· Section 313 (Specific toxic chemical listings):
108-95-2 phenol
50-00-0 formaldehyde
· TSCA (Toxic Substances Control Act):
All other ingredients are exempt from listing.
9003-35-4 Phenolic Polymer
ACTIVE
1332-58-7 Kaolin
ACTIVE
7782-42-5 Graphite
ACTIVE
14807-96-6 Talc (Mg3H2(SiO3)4)
ACTIVE
100-97-0 methenamine
ACTIVE
1333-86-4 Carbon black
ACTIVE
1305-62-0 calcium dihydroxide
ACTIVE
108-95-2 phenol
ACTIVE
50-00-0 formaldehyde
ACTIVE
· Hazardous Air Pollutants
108-95-2 phenol
50-00-0 formaldehyde
· Proposition 65
· Chemicals known to cause cancer:
1333-86-4 Carbon black
50-00-0 formaldehyde
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties
and does not establish a contractual legal relationship.
· Department issuing SDS: Technical Services
(Contd. on page 10)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Phenolic Mounting Powder - Red, Black, Green
(Contd. of page 9)
59.1.0
· Contact: Pablo Mendoza
· Last revision / supersedes version: 06/01/2024 / 5.0
· Supersedes date: 06/01/2022
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by
Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Flammable Liquids 4: Flammable liquids – Category 4
Flammable Solids 2: Flammable solids – Category 2
Self-heating substances and mixtures 2: Self-heating substances and mixtures – Category 2
Acute Toxicity - Oral 3: Acute toxicity – Category 3
Skin Corrosion 1B: Skin corrosion/irritation – Category 1B
Skin Irritation 2: Skin corrosion/irritation – Category 2
Eye Damage 1: Serious eye damage/eye irritation – Category 1
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
Sensitization - Skin 1: Skin sensitisation – Category 1
Germ Cell Mutagenicity 2: Germ cell mutagenicity – Category 2
Carcinogenicity 1A: Carcinogenicity – Category 1A
Carcinogenicity 2: Carcinogenicity – Category 2
Specific Target Organ Toxicity - Repeated Exposure 2: Specific target organ toxicity (repeated exposure) – Category 2
· * Data compared to the previous version altered.