COLD RELEASE PTFE LIQUID: SAFETY DATA SHEET
Also listed as: Mold Release Liquid, PTFE Based (Hot or Cold)
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Page 1 Page 1/8 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 59.1.0 * 1 Identification · Product name: Mold Release, Liquid, Hot and Cold, PTFE · Part number: 200-10015 · Application of the substance / the mixture Releasing agent · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Allied High Tech Products Inc. 16207 Carmenita Road USA-Cerritos, CA, 90703 USA info@alliedhightech.com · Information department: Product safety department · Emergency telephone number: During normal opening times: +1 (310) 635-2466 Chemtrec: +1 (202) 483-7616 2 Hazard(s) identification · Classification of the substance or mixture GHS07 Acute Toxicity - Inhalation 4 H332 Harmful if inhaled. Skin Irritation 2 H315 Causes skin irritation. Eye Irritation 2A H319 Causes serious eye irritation. Specific Target Organ Toxicity - Single Exposure 3 H335 May cause respiratory irritation. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS07 · Signal word Warning · Hazard-determining components of labeling: trans-dichloroethylene 2h, 3h-Decafluoropentane · Hazard statements Harmful if inhaled. (Contd. on page 2) Page 2 Page 2/8 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: Mold Release, Liquid, Hot and Cold, PTFE (Contd. of page 1) 59.1.0 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Harmful to aquatic life with long lasting effects. · Precautionary statements Avoid breathing dust/fume/gas/mist/vapors/spray Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves / eye protection / face protection. If on skin: Wash with plenty of water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. Specific treatment (see on this label). Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. * 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. · Hazardous components and components with occupational exposure limits: 156-60-5 trans-dichloroethylene Flammable Liquids 2, H225; Acute Toxicity - Inhalation 4, H332; Aquatic Chronic 3, H412 60-66% 138495-42-8 2h, 3h-Decafluoropentane Skin Irritation 2, H315; Specific Target Organ Toxicity - Single Exposure 3, H335; Eye Irritation 2B, H320; Aquatic Chronic 3, H412 22-26% 67-63-0 isopropyl alcohol Flammable Liquids 2, H225; Eye Irritation 2A, H319; Specific Target Organ Toxicity - Single Exposure 3, H336 6-12% · Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret. 4 First-aid measures · Description of first aid measures · General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. · After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: If symptoms persist consult doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed Breathing difficulty Dizziness Coughing Nausea Dermatitis Eye irritation (Contd. on page 3) Page 3 Page 3/8 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: Mold Release, Liquid, Hot and Cold, PTFE (Contd. of page 2) 59.1.0 · Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: Carbon dioxide Alcohol resistant foam Use fire fighting measures that suit the environment. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: Mouth respiratory protective device. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Not required. · Environmental precautions: Do not allow to enter sewers/ surface or ground water. Inform respective authorities in case of seepage into water course or sewage system. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section 13. Ensure adequate ventilation. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Handling: · Precautions for safe handling Ensure proper ventilation/exhaustion at workplaces. Prevent formation of aerosols. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store at temperatures not exceeding 52°C. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Protect from frost. Keep receptacle tightly sealed. Store receptacle in a well ventilated area. · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No additional data. See 7. · Control parameters · Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the remaining constituent has no known exposure limits. 156-60-5 trans-dichloroethylene PEL Long-term value: 790 mg/m³, 200 ppm REL Long-term value: 790 mg/m³, 200 ppm TLV Long-term value: 200 ppm (Contd. on page 4) Page 4 Page 4/8 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: Mold Release, Liquid, Hot and Cold, PTFE (Contd. of page 3) 59.1.0 67-63-0 isopropyl alcohol PEL Long-term value: 980 mg/m³, 400 ppm REL Short-term value: 1225 mg/m³, 500 ppm Long-term value: 980 mg/m³, 400 ppm TLV Short-term value: 400 ppm Long-term value: 200 ppm BEI, A4 · Ingredients with biological limit values: 67-63-0 isopropyl alcohol BEI 40 mg/L Medium: urine Time: end of shift at end of workweek Parameter: Acetone (background, nonspecific) · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. · Breathing equipment: Use suitable respiratory protective device when high concentrations are present. · Protection of hands: Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Eye protection: Safety glasses Tightly sealed goggles 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Color: White · Odor: Light · Odor threshold: Not determined. · pH-value at 20 °C (68 °F): 7 · Change in condition Melting point/Melting range: Undetermined. (Contd. on page 5) Page 5 Page 5/8 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: Mold Release, Liquid, Hot and Cold, PTFE (Contd. of page 4) 59.1.0 Boiling point/Boiling range: 48 °C (118.4 °F) · Flash point: Not applicable. · Flammability (solid, gaseous): Not applicable. · Auto igniting: 440 °C (824 °F) · Decomposition temperature: Not determined. · Ignition temperature: Product is not selfigniting. · Danger of explosion: Product does not present an explosion hazard. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapor pressure at 25 °C (77 °F): 425.3 hPa (319 mm Hg) · Density: Not determined. · Relative density Not determined. · Vapor density Not determined. · Evaporation rate Not determined. · Solubility in / Miscibility with Water: Not miscible or difficult to mix. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · Solvent content: Organic solvents: 63.5-75 % VOC content: 63.46-75 % Solids content: 0.0 % · Other information No further relevant information available. 10 Stability and reactivity · Reactivity No further relevant information available. · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid Keep away from oxidising agents and acidic substances. Do not mix with alkalis. Keep away from heat. Keep away from open flames. - No smoking. Keep away from alkaline solutions. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: Carbon monoxide and carbon dioxide Hydrogen chloride (HCl) Hydrogen fluoride · Additional information: Hazardous decomposition products may form during combustion. (Contd. on page 6) Page 6 Page 6/8 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: Mold Release, Liquid, Hot and Cold, PTFE (Contd. of page 5) 59.1.0 11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: ATE (Acute Toxicity Estimate) Inhalative LC50/4 h 17.3-19.1 mg/l 156-60-5 trans-dichloroethylene Oral LD50 7,902 mg/kg (rat) Inhalative LC50/4 h 11 mg/l (ATE) 138495-42-8 2h, 3h-Decafluoropentane Oral LD50 >5,000 mg/kg (rat) Dermal LD50 >5,000 mg/kg (rabbit) Inhalative LC50/4 h 114 mg/l (rat) 67-63-0 isopropyl alcohol Oral LD50 5,045 mg/kg (rat) Dermal LD50 12,800 mg/kg (rabbit) Inhalative LC50/4 h 30 mg/l (rat) · Primary chemical irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) 67-63-0 isopropyl alcohol 3 · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information · Toxicity · Aquatic toxicity: 156-60-5 trans-dichloroethylene EC50 (96 h) 798 mg/l (fresh water algae) LC50 (96 h) 74 mg/l (bluegill sunfish) LC50 (48 h) 79 mg/l (daphnia) 138495-42-8 2h, 3h-Decafluoropentane LC50 (96 h) 27.2 mg/l (fathead minnows) 13.9 mg/l (rainbow trout) LC50 (48 h) 11.7 mg/l (daphnia) · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. (Contd. on page 7) Page 7 Page 7/8 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: Mold Release, Liquid, Hot and Cold, PTFE (Contd. of page 6) 59.1.0 · Ecotoxical effects: · Remark: Harmful to fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Harmful to aquatic organisms · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation: Contact waste processors for recycling information. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. 14 Transport information · UN-Number · DOT, ADN, IMDG, IATA not regulated · UN proper shipping name · DOT, ADN, IMDG, IATA not regulated · Transport hazard class(es) · DOT, ADN, IMDG, IATA · Class not regulated · Packing group · DOT, IMDG, IATA not regulated · Environmental hazards: · Marine pollutant: No · Special precautions for user Not applicable. · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · UN "Model Regulation": not regulated 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available. · Sara · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): 67-63-0 isopropyl alcohol · TSCA (Toxic Substances Control Act): All components have the value ACTIVE. · Hazardous Air Pollutants None of the ingredients is listed. (Contd. on page 8) Page 8 Page 8/8 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: Mold Release, Liquid, Hot and Cold, PTFE (Contd. of page 7) 59.1.0 · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties and does not establish a contractual legal relationship. · Department issuing SDS: Technical Services · Contact: Pablo Mendoza · Last revision / supersedes version: 06/01/2024 / 3.0 · Supersedes date: 06/01/2024 · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit BEI: Biological Exposure Limit Flammable Liquids 2: Flammable liquids – Category 2 Acute Toxicity - Inhalation 4: Acute toxicity – Category 4 Skin Irritation 2: Skin corrosion/irritation – Category 2 Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A Eye Irritation 2B: Serious eye damage/eye irritation – Category 2B Specific Target Organ Toxicity - Single Exposure 3: Specific target organ toxicity (single exposure) – Category 3 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3 · * Data compared to the previous version altered.