Diamond Aerosol Spray

Refer to the original PDF for tables, figures and page layout.

Page 1
 
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
59.1.0
* 1 Identification
· Product name: Diamond Aerosol Spray
· Part number: 90-173000  -  90-173025
· Application of the substance / the mixture Polishing solution
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Allied High Tech Products Inc.
16207 Carmenita Road
USA-Cerritos, CA, 90703
USA
info@alliedhightech.com
· Information department: Product safety department
· Emergency telephone number:
During normal opening times: +1 (310) 635-2466
Chemtrec: +1 (202) 483-7616
2 Hazard(s) identification
· Classification of the substance or mixture
GHS02 Flame
Flammable Aerosols 1
H222 Extremely flammable aerosol.
GHS04 Gas cylinder
Gases under Pressure - Compressed gas
H280 Contains gas under pressure; may explode if heated.
GHS08 Health hazard
Carcinogenicity 2
H351 Suspected of causing cancer.
Specific Target Organ Toxicity - Single Exposure 1 H370 Causes damage to the central nervous system and the cardiovascular system.
GHS07
Eye Irritation 2A
H319 Causes serious eye irritation.
Simple Asphyxiant
  
May displace oxygen and cause rapid suffocation.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2)


Page 2
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Diamond Aerosol Spray
(Contd. of page 1)
59.1.0
· Hazard pictograms
GHS02
GHS04
GHS07
GHS08
· Signal word Danger
· Hazard-determining components of labeling:
methyl isobutyl ketone
methyl alcohol
· Hazard statements
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Suspected of causing cancer.
Causes damage to the central nervous system and the cardiovascular system.
May displace oxygen and cause rapid suffocation.
· Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves/protective clothing/eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Store locked up.
Protect from sunlight. Store in a well-ventilated place.
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Hazardous components and components with occupational exposure limits:
68476-86-8 Petroleum gases, liquefied, sweetened
 Flammable Gases 1, H220;
 Gases under Pressure - Compressed gas, H280
40-50%
64-17-5 ethyl alcohol
 Flammable Liquids 2, H225
30-40%
67-63-0 isopropyl alcohol
 Flammable Liquids 2, H225;
 Eye Irritation 2A, H319; Specific Target Organ Toxicity - Single Exposure 3,
H336
10%
67-56-1 methyl alcohol
 Flammable Liquids 2, H225;
 Acute Toxicity - Oral 3, H301; Acute Toxicity - Dermal 3, H311; Acute
Toxicity - Inhalation 3, H331;
 Specific Target Organ Toxicity - Single Exposure 1, H370
3-<5%
108-10-1 methyl isobutyl ketone
 Flammable Liquids 2, H225;
 Carcinogenicity 2, H351;
 Acute Toxicity - Inhalation 4, H332; Eye Irritation
2A, H319; Specific Target Organ Toxicity - Single Exposure 3, H336
1-5%
(Contd. on page 3)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Diamond Aerosol Spray
(Contd. of page 2)
59.1.0
· Non-hazardous components:
7732-18-5 water, distilled, conductivity or of similar purity
1-5%
7782-40-3 Diamond
≤1%
· Additional information:
Water is a byproduct of ethyl alcohol.
The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.
4 First-aid measures
· Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
Disorientation
Unconsciousness
Breathing difficulty
Coughing
Eye irritation
· Indication of any immediate medical attention and special treatment needed No further relevant information available.
5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced.
· Advice for firefighters
· Protective equipment: Wear fully protective suit.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
· Environmental precautions:
Do not allow product to reach sewage system or any water course.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling
Protect from heat and direct sunlight.
Ensure proper ventilation/exhaustion at workplaces.
Open and handle receptacle with care.
· Information about protection against explosions and fires:
Do not spray on a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
(Contd. on page 4)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Diamond Aerosol Spray
(Contd. of page 3)
59.1.0
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C, i.e. electric lights. Do not pierce or burn,
even after use.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Observe official regulations on storing packagings with pressurized containers.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Store receptacle in a well ventilated area.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical systems: No additional data. See 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the remaining constituent has no known exposure limits.
64-17-5 ethyl alcohol
PEL Long-term value: 1900 mg/m³, 1000 ppm
REL Long-term value: 1900 mg/m³, 1000 ppm
TLV Short-term value: 1000 ppm
A3
67-63-0 isopropyl alcohol
PEL Long-term value: 980 mg/m³, 400 ppm
REL Short-term value: 1225 mg/m³, 500 ppm
Long-term value: 980 mg/m³, 400 ppm
TLV Short-term value: 400 ppm
Long-term value: 200 ppm
BEI, A4
67-56-1 methyl alcohol
PEL Long-term value: 260 mg/m³, 200 ppm
REL Short-term value: 325 mg/m³, 250 ppm
Long-term value: 260 mg/m³, 200 ppm
Skin
TLV Short-term value: 250 ppm
Long-term value: 200 ppm
Skin; BEIc
108-10-1 methyl isobutyl ketone
PEL Long-term value: 410 mg/m³, 100 ppm
REL Short-term value: 300 mg/m³, 75 ppm
Long-term value: 205 mg/m³, 50 ppm
TLV Short-term value: 75 ppm
Long-term value: 20 ppm
BEI, A3
· Ingredients with biological limit values:
67-63-0 isopropyl alcohol
BEI 40 mg/L
Medium: urine
Time: end of shift at end of workweek
Parameter: Acetone (background, nonspecific)
(Contd. on page 5)


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Safety Data Sheet
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Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Diamond Aerosol Spray
(Contd. of page 4)
59.1.0
67-56-1 methyl alcohol
BEI 15 mg/L
Medium: urine
Time: end of shift
Parameter: Methanol (background, nonspecific)
108-10-1 methyl isobutyl ketone
BEI 1 mg/L
Medium: urine
Time: end of shift
Parameter: MIBK
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.
· Protection of hands:
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer
to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance
and has therefore to be checked prior to the application.
· Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form:
Aerosol
Color:
According to product specification
· Odor:
Alcohol-like
· Odor threshold:
Not determined.
· pH-value:
Not determined.
· Change in condition
Melting point/Melting range:
Undetermined.
Boiling point/Boiling range:
78 °C (172.4 °F)
· Flash point:
-88.3 °C (-126.9 °F)
(Contd. on page 6)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Diamond Aerosol Spray
(Contd. of page 5)
59.1.0
· Flammability (solid, gaseous):
Not applicable.
· Auto igniting:
425 °C (797 °F)
· Decomposition temperature:
Not determined.
· Ignition temperature:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive. However, formation of explosive air/vapor mixtures are possible.
· Explosion limits:
Lower:
1.8 Vol %
Upper:
9.5 Vol %
· Vapor pressure at 20 °C (68 °F):
64 hPa (48 mm Hg)
· Density:
Not determined.
· Relative density
Not determined.
· Vapor density
1.6-1.9 (Air = 1)
· Specific gravity:
0.8 (water = 1)
· Evaporation rate
Not applicable.
· Solubility in / Miscibility with
Water:
Fully miscible.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Not determined.
Kinematic:
Not determined.
· Solvent content:
Organic solvents:
52.3 %
Water:
3.5 %
VOC content:
52.25 %
0.0 g/l / 0.00 lb/gal
Solids content:
1.0 %
· Other information
No further relevant information available.
10 Stability and reactivity
· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid
Keep away from heat.
Keep away from open flames. - No smoking.
Keep away from oxidising agents and acidic substances.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products:
Formaldehyde
Carbon monoxide and carbon dioxide
· Additional information: Hazardous decomposition products may form during combustion.
(Contd. on page 7)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Diamond Aerosol Spray
(Contd. of page 6)
59.1.0
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
ATE (Acute Toxicity Estimate)
Oral
LD50
2,840 mg/kg
Dermal
LD50
8,520 mg/kg
Inhalative LC50/4 h 62.6-72.2 mg/l
  64-17-5 ethyl alcohol
Oral
LD50
7,060 mg/kg (rat)
Dermal
LD50
15,800 mg/kg (rabbit)
Inhalative LC50/4 h 20,000 mg/l (rat)
67-63-0 isopropyl alcohol
Oral
LD50
5,045 mg/kg (rat)
Dermal
LD50
12,800 mg/kg (rabbit)
Inhalative LC50/4 h 30 mg/l (rat)
67-56-1 methyl alcohol
Oral
LD50
100 mg/kg (ATE)
Dermal
LD50
300 mg/kg (ATE)
Inhalative LC50/4 h 3 mg/l (ATE)
108-10-1 methyl isobutyl ketone
Oral
LD50
2,080 mg/kg (rat)
Dermal
LD50
16,000 mg/kg (rab)
Inhalative LC50/4 h 11 mg/l (ATE)
8.3-16.6 mg/l (rat)
· Primary chemical irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
64-17-5 ethyl alcohol
1 
67-63-0 isopropyl alcohol
3 
108-10-1 methyl isobutyl ketone
2B
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
(Contd. on page 8)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Diamond Aerosol Spray
(Contd. of page 7)
59.1.0
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation: Contact waste processors for recycling information.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agent: Water, if necessary with cleansing agents.
14 Transport information
· UN-Number
· DOT, IMDG, IATA
UN1950
· UN proper shipping name
· DOT
Aerosols, flammable
· IMDG
AEROSOLS
· IATA
AEROSOLS, flammable
· Transport hazard class(es)
· DOT
· Class
2.1 Gases
· Label
2.1
· IMDG, IATA
· Class
2.1 Gases
· Label
2.1
· Packing group
· DOT, IMDG, IATA
not regulated
· Environmental hazards:
· Marine pollutant:
No
· Special precautions for user
Warning: Gases
· Hazard identification number (Kemler code):
- 
· EMS Number:
F-D,S-U
(Contd. on page 9)


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Safety Data Sheet
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Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Diamond Aerosol Spray
(Contd. of page 8)
59.1.0
· Stowage Code
SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre: Category
A. For AEROSOLS with a capacity above 1 litre: Category B. For
WASTE AEROSOLS: Category C, Clear of living quarters.
· Segregation Code
SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1 except for
division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
· Transport in bulk according to Annex II of MARPOL73/78 and
the IBC Code
Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations
On passenger aircraft/rail: 75 kg
On cargo aircraft only: 150 kg
· Limited quantities (LQ)
1L
· Transport category
2 
· Tunnel restriction code
D 
· IMDG
· Limited quantities (LQ)
1L
· Excepted quantities (EQ)
Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation":
UN 1950 AEROSOLS, 2.1
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
67-63-0 isopropyl alcohol
67-56-1 methyl alcohol
108-10-1 methyl isobutyl ketone
· TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
· Hazardous Air Pollutants
67-56-1 methyl alcohol
108-10-1 methyl isobutyl ketone
· Proposition 65
· Chemicals known to cause cancer:
108-10-1 methyl isobutyl ketone
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
(Contd. on page 10)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 6.0
Product name: Diamond Aerosol Spray
(Contd. of page 9)
59.1.0
· Chemicals known to cause developmental toxicity:
64-17-5 ethyl alcohol
67-56-1 methyl alcohol
108-10-1 methyl isobutyl ketone
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties
and does not establish a contractual legal relationship.
· Department issuing SDS: Technical Services
· Contact: Pablo Mendoza
· Last revision / supersedes version: 06/01/2024 / 5.0
· Supersedes date: 06/01/2022
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by
Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Flammable Gases 1: Flammable gases – Category 1
Flammable Aerosols 1: Aerosols – Category 1
Gases under Pressure - Compressed gas: Gases under pressure – Compressed gas
Flammable Liquids 2: Flammable liquids – Category 2
Acute Toxicity - Oral 3: Acute toxicity – Category 3
Acute Toxicity - Inhalation 4: Acute toxicity – Category 4
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
Carcinogenicity 2: Carcinogenicity – Category 2
Specific Target Organ Toxicity - Single Exposure 1: Specific target organ toxicity (single exposure) – Category 1
Specific Target Organ Toxicity - Single Exposure 3: Specific target organ toxicity (single exposure) – Category 3
· * Data compared to the previous version altered.