M-Bond 610
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Page 1 Page 1/10 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 59.1.0 * 1 Identification · Product name: M-Bond 610 Adhesive · Part number: 71-20000 · Application of the substance / the mixture Adhesives · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Allied High Tech Products Inc. 16207 Carmenita Road USA-Cerritos, CA, 90703 USA info@alliedhightech.com · Information department: Product safety department · Emergency telephone number: During normal opening times: +1 (310) 635-2466 Chemtrec: +1 (202) 483-7616 2 Hazard(s) identification · Classification of the substance or mixture GHS02 Flame Flammable Liquids 2 H225 Highly flammable liquid and vapor. GHS08 Health hazard Carcinogenicity 2 H351 Suspected of causing cancer. GHS09 Environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Skin Irritation 2 H315 Causes skin irritation. Eye Irritation 2A H319 Causes serious eye irritation. Sensitization - Skin 1 H317 May cause an allergic skin reaction. Specific Target Organ Toxicity - Single Exposure 3 H335 May cause respiratory irritation. (Contd. on page 2) Page 2 Page 2/10 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Adhesive (Contd. of page 1) 59.1.0 · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS02 GHS07 GHS08 GHS09 · Signal word Danger · Hazard-determining components of labeling: tetrahydrofuran Polyglycidyl Ether of Phenol-Formaldehyde · Hazard statements Highly flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. Toxic to aquatic life with long lasting effects. · Precautionary statements Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapors/spray Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. Specific treatment (see on this label). Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, powder or water spray to extinguish. Collect spillage. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. (Contd. on page 3) Page 3 Page 3/10 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Adhesive (Contd. of page 2) 59.1.0 · Hazardous components and components with occupational exposure limits: 109-99-9 tetrahydrofuran Flammable Liquids 2, H225; Carcinogenicity 2, H351; Eye Irritation 2A, H319; Specific Target Organ Toxicity - Single Exposure 3, H335 60-70% 28064-14-4 Polyglycidyl Ether of Phenol-Formaldehyde Aquatic Chronic 2, H411; Skin Irritation 2, H315; Sensitization - Skin 1, H317 25-30% 78-93-3 ethyl methyl ketone Flammable Liquids 2, H225; Eye Irritation 2A, H319; Specific Target Organ Toxicity - Single Exposure 3, H336 5-<10% · Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret. 4 First-aid measures · Description of first aid measures · General information: Immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: If symptoms persist consult doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed Breathing difficulty Headache Dizziness Coughing Allergic reactions Nausea Dermatitis Eye irritation · Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: Wear fully protective suit. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Keep away from ignition sources · Environmental precautions: Do not allow product to reach sewage system or any water course. Do not allow to enter sewers/ surface or ground water. Prevent seepage into sewage system, workpits and cellars. Inform respective authorities in case of seepage into water course or sewage system. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section 13. Ensure adequate ventilation. · Reference to other sections See Section 7 for information on safe handling. (Contd. on page 4) Page 4 Page 4/10 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Adhesive (Contd. of page 3) 59.1.0 See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Handling: · Precautions for safe handling Protect from heat and direct sunlight. Ensure proper ventilation/exhaustion at workplaces. Open and handle receptacle with care. Prevent formation of aerosols. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Protect from sunlight. Store at temperatures not exceeding 35°C. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Store receptacle in a well ventilated area. · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No additional data. See 7. · Control parameters · Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the remaining constituent has no known exposure limits. 109-99-9 tetrahydrofuran PEL Long-term value: 590 mg/m³, 200 ppm REL Short-term value: 735 mg/m³, 250 ppm Long-term value: 590 mg/m³, 200 ppm TLV Short-term value: 100 ppm Long-term value: 50 ppm Skin, A3, BEI 78-93-3 ethyl methyl ketone PEL Long-term value: 590 mg/m³, 200 ppm REL Short-term value: 885 mg/m³, 300 ppm Long-term value: 590 mg/m³, 200 ppm TLV Short-term value: 150 ppm Long-term value: 75 ppm BEI, Skin · Ingredients with biological limit values: 109-99-9 tetrahydrofuran BEI 2 mg/L Medium: urine Time: end of shift Parameter: Tetrahydrofuran (Contd. on page 5) Page 5 Page 5/10 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Adhesive (Contd. of page 4) 59.1.0 78-93-3 ethyl methyl ketone BEI 2 mg/L Medium: urine Time: end of shift Parameter: Methyl ethyl ketone (nonspecific) · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. · Breathing equipment: Use suitable respiratory protective device when high concentrations are present. · Protection of hands: Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves PVC or PE gloves Recommended thickness of the material: 0.1 mm The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Eye protection: Tightly sealed goggles 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Color: Colorless · Odor: Ether-like · Odor threshold: Not determined. · pH-value: Not determined. · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 65.5 °C (149.9 °F) · Flash point: -14 °C (6.8 °F) · Flammability (solid, gaseous): Highly flammable. · Auto igniting: 320 °C (608 °F) · Decomposition temperature: Not determined. (Contd. on page 6) Page 6 Page 6/10 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Adhesive (Contd. of page 5) 59.1.0 · Ignition temperature: Product is not selfigniting. · Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. · Explosion limits: Lower: 1.5 Vol % Upper: 12 Vol % · Vapor pressure at 20 °C (68 °F): 172 hPa (129 mm Hg) · Density: Not determined. · Relative density 0.9 (Water =1) · Vapor density 2.4 (Air=1) · Evaporation rate 8.0 (BuAc=1) · Solubility in / Miscibility with Water: Partly miscible. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · Solvent content: Organic solvents: 70.1 % VOC content: 70.10 % Solids content: 0.0 % · Other information No further relevant information available. 10 Stability and reactivity · Reactivity No further relevant information available. · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions Reacts with amines. · Conditions to avoid Store at temperatures not exceeding 32°C. Protect from sunlight. Keep away from oxidising agents and acidic substances. Do not mix with alkalis. Keep away from heat. Keep away from open flames. - No smoking. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: Explosive peroxides Phenolic compounds Carbon monoxide and carbon dioxide · Additional information: Hazardous decomposition products may form during combustion. 11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 109-99-9 tetrahydrofuran Oral LD50 2,500 mg/kg (rat) (Contd. on page 7) Page 7 Page 7/10 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Adhesive (Contd. of page 6) 59.1.0 78-93-3 ethyl methyl ketone Oral LD50 3,300 mg/kg (rat) Dermal LD50 5,000 mg/kg (rabbit) · Primary chemical irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Irritating effect. · Sensitization: Sensitization possible through skin contact. · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) 109-99-9 tetrahydrofuran 2B · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information · Toxicity · Aquatic toxicity: LC50 (48 h) 1-10 mg/l (oncorhynchus mykiss) · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Toxic for fish · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation: Contact waste processors for recycling information. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information · UN-Number · DOT, IMDG, IATA UN1133 · UN proper shipping name · DOT Adhesives (Contd. on page 8) Page 8 Page 8/10 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Adhesive (Contd. of page 7) 59.1.0 · IMDG ADHESIVES, MARINE POLLUTANT · IATA ADHESIVES · Transport hazard class(es) · DOT · Class 3 Flammable liquids · Label 3 · IMDG · Class 3 Flammable liquids · Label 3 · IATA · Class 3 Flammable liquids · Label 3 · Packing group · DOT, IMDG, IATA II · Environmental hazards: Product contains environmentally hazardous substances: Polyglycidyl Ether of Phenol-Formaldehyde · Marine pollutant: Yes Symbol (fish and tree) · Special precautions for user Warning: Flammable liquids · Hazard identification number (Kemler code): 33 · EMS Number: F-E,S-D · Stowage Category B · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · DOT · Quantity limitations On passenger aircraft/rail: 5 L On cargo aircraft only: 60 L · Limited quantities (LQ) 5L · Transport category 2 · Tunnel restriction code D/E · IMDG · Limited quantities (LQ) 5L · Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml (Contd. on page 9) Page 9 Page 9/10 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Adhesive (Contd. of page 8) 59.1.0 · UN "Model Regulation": UN 1133 ADHESIVES, 3, II, ENVIRONMENTALLY HAZARDOUS 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available. · Sara · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All components have the value ACTIVE. · Hazardous Air Pollutants None of the ingredients is listed. · Proposition 65 · Chemicals known to cause cancer: 109-99-9 tetrahydrofuran · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties and does not establish a contractual legal relationship. · Department issuing SDS: Technical Services · Contact: Pablo Mendoza · Last revision / supersedes version: 06/01/2024 / 3.0 · Supersedes date: 06/01/2022 · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit BEI: Biological Exposure Limit Flammable Liquids 2: Flammable liquids – Category 2 Skin Irritation 2: Skin corrosion/irritation – Category 2 Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A (Contd. on page 10) Page 10 Page 10/10 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Adhesive (Contd. of page 9) 59.1.0 Sensitization - Skin 1: Skin sensitisation – Category 1 Carcinogenicity 2: Carcinogenicity – Category 2 Specific Target Organ Toxicity - Single Exposure 3: Specific target organ toxicity (single exposure) – Category 3 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 · * Data compared to the previous version altered. Page 11 Page 1/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 59.1.0 * 1 Identification · Product name: M-Bond 610 Curing Agent · Part number: 71-20000 · Application of the substance / the mixture Hardening agent/ Curing agent · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Allied High Tech Products Inc. 16207 Carmenita Road USA-Cerritos, CA, 90703 USA info@alliedhightech.com · Information department: Product safety department · Emergency telephone number: During normal opening times: +1 (310) 635-2466 Chemtrec: +1 (202) 483-7616 2 Hazard(s) identification · Classification of the substance or mixture GHS02 Flame Flammable Liquids 2 H225 Highly flammable liquid and vapor. GHS08 Health hazard Sensitization - Respiratory 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carcinogenicity 2 H351 Suspected of causing cancer. GHS05 Corrosion Eye Damage 1 H318 Causes serious eye damage. GHS07 Sensitization - Skin 1 H317 May cause an allergic skin reaction. Specific Target Organ Toxicity - Single Exposure 3 H335 May cause respiratory irritation. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. on page 2) Page 12 Page 2/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Curing Agent (Contd. of page 1) 59.1.0 · Hazard pictograms GHS02 GHS05 GHS07 GHS08 · Signal word Danger · Hazard-determining components of labeling: tetrahydrofuran benzene-1,2:4,5-tetracarboxylic dianhydride · Hazard statements Highly flammable liquid and vapor. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. · Precautionary statements Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. IF exposed or concerned: Get medical advice/attention. Specific treatment (see on this label). If skin irritation or rash occurs: Get medical advice/attention. If experiencing respiratory symptoms: Call a poison center/doctor. Wash contaminated clothing before reuse. In case of fire: Use CO2, powder or water spray to extinguish. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. · Hazardous components and components with occupational exposure limits: 109-99-9 tetrahydrofuran Flammable Liquids 2, H225; Carcinogenicity 2, H351; Eye Irritation 2A, H319; Specific Target Organ Toxicity - Single Exposure 3, H335 80-90% 89-32-7 benzene-1,2:4,5-tetracarboxylic dianhydride Sensitization - Respiratory 1, H334; Eye Damage 1, H318; Sensitization - Skin 1, H317 5-10% (Contd. on page 3) Page 13 Page 3/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Curing Agent (Contd. of page 2) 59.1.0 · Non-hazardous components: 89-05-4 benzene-1,2,4,5-tetracarboxylic acid 1-5% · Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret. 4 First-aid measures · Description of first aid measures · General information: Immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: If symptoms persist consult doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed Breathing difficulty Headache Dizziness Coughing Allergic reactions Nausea Dermatitis Eye irritation · Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: Wear fully protective suit. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Keep away from ignition sources · Environmental precautions: Do not allow product to reach sewage system or any water course. Do not allow to enter sewers/ surface or ground water. Prevent seepage into sewage system, workpits and cellars. Dilute with plenty of water. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to section 13. Ensure adequate ventilation. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. on page 4) Page 14 Page 4/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Curing Agent (Contd. of page 3) 59.1.0 7 Handling and storage · Handling: · Precautions for safe handling Protect from heat and direct sunlight. Ensure proper ventilation/exhaustion at workplaces. Open and handle receptacle with care. Prevent formation of aerosols. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Protect from sunlight. Store at temperatures not exceeding 27°C. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Store receptacle in a well ventilated area. · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No additional data. See 7. · Control parameters · Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the remaining constituent has no known exposure limits. 109-99-9 tetrahydrofuran PEL Long-term value: 590 mg/m³, 200 ppm REL Short-term value: 735 mg/m³, 250 ppm Long-term value: 590 mg/m³, 200 ppm TLV Short-term value: 100 ppm Long-term value: 50 ppm Skin, A3, BEI · Ingredients with biological limit values: 109-99-9 tetrahydrofuran BEI 2 mg/L Medium: urine Time: end of shift Parameter: Tetrahydrofuran · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. · Breathing equipment: Use suitable respiratory protective device when high concentrations are present. (Contd. on page 5) Page 15 Page 5/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Curing Agent (Contd. of page 4) 59.1.0 · Protection of hands: Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Eye protection: Tightly sealed goggles 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Color: Amber colored · Odor: Ether-like · Odor threshold: Not determined. · pH-value: Not determined. · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 65.5 °C (149.9 °F) · Flash point: -14 °C (6.8 °F) · Flammability (solid, gaseous): Highly flammable. · Auto igniting: 230 °C (446 °F) · Decomposition temperature: Not determined. · Ignition temperature: Product is not selfigniting. · Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. · Explosion limits: Lower: 1.5 Vol % Upper: 12 Vol % · Vapor pressure at 15 °C (59 °F): 193.3 hPa (145 mm Hg) · Density at 20 °C (68 °F): 0.959 g/cm³ (8.003 lbs/gal) · Relative density 0.9 (H2O=1) · Vapor density 2.5 (Air=1) · Evaporation rate >1 (BuAc=1) · Solubility in / Miscibility with Water: Fully miscible. · Partition coefficient (n-octanol/water): Not determined. (Contd. on page 6) Page 16 Page 6/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Curing Agent (Contd. of page 5) 59.1.0 · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · Solvent content: Organic solvents: 88.2 % VOC content: 88.21 % Solids content: 11.8 % · Other information No further relevant information available. 10 Stability and reactivity · Reactivity No further relevant information available. · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions Possible formation of peroxide. · Conditions to avoid Keep away from oxidising agents and acidic substances. Keep away from heat. Keep away from open flames. - No smoking. · Incompatible materials: Mild steel · Hazardous decomposition products: Explosive peroxides Carbon monoxide and carbon dioxide · Additional information: Hazardous decomposition products may form during combustion. 11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 109-99-9 tetrahydrofuran Oral LD50 2,500 mg/kg (rat) 89-32-7 benzene-1,2:4,5-tetracarboxylic dianhydride Oral LD50 2,250 mg/kg (rat) · Primary chemical irritant effect: · on the skin: No irritant effect. · on the eye: Strong irritant with the danger of severe eye injury. · Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact. · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) 109-99-9 tetrahydrofuran 2B · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. (Contd. on page 7) Page 17 Page 7/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Curing Agent (Contd. of page 6) 59.1.0 12 Ecological information · Toxicity · Aquatic toxicity: LC50 (48 h) >100 mg/l (oncorhynchus mykiss) · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation: Contact waste processors for recycling information. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information · UN-Number · DOT, IMDG, IATA UN2056 · UN proper shipping name · DOT Tetrahydrofuran mixture · IMDG, IATA TETRAHYDROFURAN mixture · Transport hazard class(es) · DOT · Class 3 Flammable liquids · Label 3 · IMDG, IATA · Class 3 Flammable liquids · Label 3 · Packing group · DOT, IMDG, IATA II (Contd. on page 8) Page 18 Page 8/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Curing Agent (Contd. of page 7) 59.1.0 · Environmental hazards: · Marine pollutant: No · Special precautions for user Warning: Flammable liquids · Hazard identification number (Kemler code): 33 · EMS Number: F-E,S-D · Stowage Category B · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · DOT · Quantity limitations On passenger aircraft/rail: 5 L On cargo aircraft only: 60 L · Limited quantities (LQ) 1L · Transport category 2 · Tunnel restriction code D/E · IMDG · Limited quantities (LQ) 1L · Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml · UN "Model Regulation": UN 2056 TETRAHYDROFURAN MIXTURE, 3, II 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available. · Sara · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All components have the value ACTIVE. · Hazardous Air Pollutants None of the ingredients is listed. · Proposition 65 · Chemicals known to cause cancer: 109-99-9 tetrahydrofuran · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. (Contd. on page 9) Page 19 Page 9/9 Safety Data Sheet acc. to OSHA HCS Printing date 07/02/2024 Last revision 06/01/2024 Version 4.0 Product name: M-Bond 610 Curing Agent (Contd. of page 8) 59.1.0 16 Other information To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties and does not establish a contractual legal relationship. · Department issuing SDS: Technical Services · Contact: Pablo Mendoza · Last revision / supersedes version: 06/01/2024 / 3.0 · Supersedes date: 06/01/2022 · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit BEI: Biological Exposure Limit Flammable Liquids 2: Flammable liquids – Category 2 Eye Damage 1: Serious eye damage/eye irritation – Category 1 Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A Sensitization - Respiratory 1: Respiratory sensitisation – Category 1 Sensitization - Skin 1: Skin sensitisation – Category 1 Carcinogenicity 2: Carcinogenicity – Category 2 Specific Target Organ Toxicity - Single Exposure 3: Specific target organ toxicity (single exposure) – Category 3 · * Data compared to the previous version altered.