OpTech Polishing Slurry - 3 micron

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Page 1
 
Page 1/8
Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
59.1.0
* 1 Identification
· Product name: OpTech Polishing Slurry, 3 micron
· Part number: 90-188020, 90-188020-G
· Application of the substance / the mixture Polishing solution
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Allied High Tech Products Inc.
16207 Carmenita Road
USA-Cerritos, CA, 90703
USA
info@alliedhightech.com
· Information department: Product safety department
· Emergency telephone number:
During normal opening times: +1 (310) 635-2466
Chemtrec: +1 (202) 483-7616
2 Hazard(s) identification
· Classification of the substance or mixture
GHS07
Sensitization - Skin 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3
H402 Harmful to aquatic life.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
GHS07
· Signal word Warning
· Hazard-determining components of labeling:
2-methyl-2H-isothiazol-3-one
· Hazard statements
May cause an allergic skin reaction.
Harmful to aquatic life.
· Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace.
Avoid release to the environment.
(Contd. on page 2)


Page 2
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: OpTech Polishing Slurry, 3 micron
(Contd. of page 1)
59.1.0
Wear protective gloves.
If on skin: Wash with plenty of water.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Hazardous components and components with occupational exposure limits:
1344-28-1 aluminium oxide
30-40%
7631-86-9 silicon dioxide, chemically prepared
10-20%
102-71-6 Triethanolamine
 Sensitization - Skin 1B, H317
0.1-<1%
141-43-5 2-aminoethanol
 Skin Corrosion 1B, H314;
 Acute Toxicity - Oral 4, H302; Acute Toxicity - Dermal 4, H312; Acute
Toxicity - Inhalation 4, H332; Flammable Liquids 4, H227
<1%
2682-20-4 2-methyl-2H-isothiazol-3-one
 Acute Toxicity - Oral 3, H301; Acute Toxicity - Dermal 3, H311; Acute Toxicity - Inhalation 2, H330;
 Skin Corrosion 1B, H314; Eye Damage 1, H318;
 Aquatic Acute 1, H400; Aquatic Chronic 1, H410;
 Sensitization - Skin 1A, H317
0.025-<0.1%
111-42-2 2,2'-iminodiethanol
 Carcinogenicity 2, H351; Specific Target Organ Toxicity - Repeated Exposure 2, H373;
 Eye Damage 1,
H318;
 Acute Toxicity - Oral 4, H302; Skin Irritation 2, H315
<0.1%
14808-60-7 Quartz (SiO2)
 Carcinogenicity 1A, H350
<0.1%
107-22-2 glyoxal
 Germ Cell Mutagenicity 2, H341;
 Acute Toxicity - Inhalation 4, H332; Skin Irritation 2, H315; Eye
Irritation 2A, H319; Sensitization - Skin 1, H317
<0.1%
· Non-hazardous components:
7732-18-5 water, distilled, conductivity or of similar purity
50-60%
· Additional information: The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.
4 First-aid measures
· Description of first aid measures
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
Allergic reactions
Dermatitis
· Indication of any immediate medical attention and special treatment needed No further relevant information available.
5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents: Use fire fighting measures that suit the environment.
· Special hazards arising from the substance or mixture No further relevant information available.
(Contd. on page 3)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: OpTech Polishing Slurry, 3 micron
(Contd. of page 2)
59.1.0
· Advice for firefighters
· Protective equipment: No special measures required.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling
Ensure proper ventilation/exhaustion at workplaces.
Prevent formation of aerosols.
· Information about protection against explosions and fires: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a cool location.
No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Protect from frost.
Store receptacle in a well ventilated area.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical systems: No additional data. See 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the remaining constituent has no known exposure limits.
1344-28-1 aluminium oxide
PEL
Long-term value: 15*; 5** mg/m³
*Total dust; ** Respirable fraction
REL
Long-term value: 10* 5** mg/m³
as Al*Total dust**Respirable/pyro powd./welding f.
TLV
Long-term value: 1* mg/m³
as Al; *as respirable fraction, A4
7631-86-9 silicon dioxide, chemically prepared
PEL
Long-term value: 6*3** mg/m³
*total **respirable
(Contd. on page 4)


Page 4
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: OpTech Polishing Slurry, 3 micron
(Contd. of page 3)
59.1.0
102-71-6 Triethanolamine
TLV
Long-term value: 5 mg/m³
141-43-5 2-aminoethanol
PEL
Long-term value: 6 mg/m³, 3 ppm
REL
Short-term value: 15 mg/m³, 6 ppm
Long-term value: 8 mg/m³, 3 ppm
TLV
Short-term value: 6 ppm
Long-term value: 3 ppm
111-42-2 2,2'-iminodiethanol
REL
Long-term value: 15 mg/m³, 3 ppm
TLV
Long-term value: 1* mg/m³
Skin; *inhalable fraction and vapor, A3
14808-60-7 Quartz (SiO2)
PEL
Long-term value: 0.05* mg/m³
*resp. dust; 30mg/m3/%SiO2+2
REL
Long-term value: 0.05* mg/m³
*respirable dust; See Pocket Guide App. A
TLV
Long-term value: 0.025* mg/m³
*respirable particulate matter, A2
107-22-2 glyoxal
REL
See Pocket Guide App. C
TLV
Long-term value: 0.1* mg/m³
DSEN;*as inh. fraction and vapor, A4
WEEL Long-term value: 0.1 mg/m³
DSEN; (H)
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
Nitrile rubber, NBR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer
to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance
and has therefore to be checked prior to the application.
· Eye protection: Goggles recommended during refilling.
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form:
Solution
(Contd. on page 5)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: OpTech Polishing Slurry, 3 micron
(Contd. of page 4)
59.1.0
Color:
White
· Odor:
Light
· Odor threshold:
Not determined.
· pH-value at 20 °C (68 °F):
9-10
· Change in condition
Melting point/Melting range:
-10 °C (14 °F)
Boiling point/Boiling range:
110 °C (230 °F)
· Flash point:
Not applicable.
· Flammability (solid, gaseous):
Not applicable.
· Decomposition temperature:
Not determined.
· Ignition temperature:
Product is not selfigniting.
· Danger of explosion:
Product does not present an explosion hazard.
· Explosion limits:
Lower:
Not determined.
Upper:
Not determined.
· Vapor pressure at 20 °C (68 °F):
23 hPa (17.3 mm Hg)
· Density:
Not determined.
· Relative density
Not determined.
· Vapor density
Not determined.
· Specific gravity at 4 °C (39.2 °F):
1.1 g/cm³ (9.18 lbs/gal) (Water = 1)
· Evaporation rate
Not determined.
· Solubility in / Miscibility with
Water:
Fully miscible.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Not determined.
Kinematic:
Not determined.
· Solvent content:
Organic solvents:
0.9 %
Water:
55.4 %
VOC content:
0.93 %
Solids content:
44.6 %
· Other information
No further relevant information available.
10 Stability and reactivity
· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid
Keep away from alkaline solutions.
Keep away from oxidising agents and acidic substances.
Keep away from heat.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: Carbon monoxide and carbon dioxide
· Additional information: Hazardous decomposition products may form during combustion.
(Contd. on page 6)


Page 6
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: OpTech Polishing Slurry, 3 micron
(Contd. of page 5)
59.1.0
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
1344-28-1 aluminium oxide
Oral
LD50
>5,000 mg/kg (rat)
7631-86-9 silicon dioxide, chemically prepared
Oral
LD50
7,000 mg/kg (mouse)
Dermal
LD50
>2,000 mg/kg (rabbit)
102-71-6 Triethanolamine
Oral
LD50
8,000 mg/kg (rat)
141-43-5 2-aminoethanol
Oral
LD50
2,050 mg/kg (rat)
Dermal
LD50
1,000 mg/kg (rabbit)
Inhalative LC50/4 h 11 mg/l (ATE)
2682-20-4 2-methyl-2H-isothiazol-3-one
Oral
LD50
100 mg/kg (ATE)
Dermal
LD50
300 mg/kg (ATE)
Inhalative LC50/4 h 0.05 mg/l (ATE)
111-42-2 2,2'-iminodiethanol
Oral
LD50
1,600 mg/kg (rat)
Dermal
LD50
12,200 mg/kg (rabbit)
107-22-2 glyoxal
Oral
LD50
7,070 mg/kg (rat)
Dermal
LD50
10,000 mg/kg (rabbit)
Inhalative LC50/4 h 11 mg/l (ATE)
· Primary chemical irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
7631-86-9 silicon dioxide, chemically prepared
3 
102-71-6 Triethanolamine
3 
111-42-2 2,2'-iminodiethanol
2B
14808-60-7 Quartz (SiO2)
1 
· NTP (National Toxicology Program)
14808-60-7 Quartz (SiO2)
K 
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability biodegradable
(Contd. on page 7)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: OpTech Polishing Slurry, 3 micron
(Contd. of page 6)
59.1.0
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation: Contact waste processors for recycling information.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agent: Water, if necessary with cleansing agents.
14 Transport information
· UN-Number
· DOT, ADN, IMDG, IATA
not regulated
· UN proper shipping name
· DOT, ADN, IMDG, IATA
not regulated
· Transport hazard class(es)
· DOT, ADN, IMDG, IATA
· Class
not regulated
· Packing group
· DOT, IMDG, IATA
not regulated
· Environmental hazards:
· Marine pollutant:
No
· Special precautions for user
Not applicable.
· Transport in bulk according to Annex II of MARPOL73/78 and
the IBC Code
Not applicable.
· UN "Model Regulation":
not regulated
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
1344-28-1 aluminium oxide
111-42-2 2,2'-iminodiethanol
· TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
(Contd. on page 8)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 4.0
Product name: OpTech Polishing Slurry, 3 micron
(Contd. of page 7)
59.1.0
· Hazardous Air Pollutants
111-42-2 2,2'-iminodiethanol
· Proposition 65
· Chemicals known to cause cancer:
111-42-2 2,2'-iminodiethanol
14808-60-7 Quartz (SiO2)
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties
and does not establish a contractual legal relationship.
· Department issuing SDS: Technical Services
· Contact: Pablo Mendoza
· Last revision / supersedes version: 06/01/2024 / 3.0
· Supersedes date: 06/01/2022
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by
Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flammable Liquids 4: Flammable liquids – Category 4
Acute Toxicity - Oral 3: Acute toxicity – Category 3
Acute Toxicity - Oral 4: Acute toxicity – Category 4
Acute Toxicity - Inhalation 2: Acute toxicity – Category 2
Skin Corrosion 1B: Skin corrosion/irritation – Category 1B
Skin Irritation 2: Skin corrosion/irritation – Category 2
Eye Damage 1: Serious eye damage/eye irritation – Category 1
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
Sensitization - Skin 1: Skin sensitisation – Category 1
Sensitization - Skin 1A: Skin sensitisation – Category 1A
Sensitization - Skin 1B: Skin sensitisation – Category 1B
Germ Cell Mutagenicity 2: Germ cell mutagenicity – Category 2
Carcinogenicity 1A: Carcinogenicity – Category 1A
Carcinogenicity 2: Carcinogenicity – Category 2
Specific Target Organ Toxicity - Repeated Exposure 2: Specific target organ toxicity (repeated exposure) – Category 2
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard – Category 3
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
· * Data compared to the previous version altered.