Zirconia Alumina Abrasive Discs - Belts1(US)

Refer to the original PDF for tables, figures and page layout.

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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 5.0
59.1.0
* 1 Identification
· Product name: Zirconia Alumina Abrasive Discs - Belts
· Part number:
50-10001-Z , 50-10045-Z, 50-10050-Z
50-10210-Z, 50-10215-Z, 50-10220-Z
50-10420-Z, 50-10425-Z, 50-10435-Z
50-11045-Z, 50-11050-Z
50-146025-Z, 50-146035-Z
· Application of the substance / the mixture Abrasive
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Allied High Tech Products Inc.
16207 Carmenita Road
USA-Cerritos, CA, 90703
USA
info@alliedhightech.com
· Information department: Product safety department
· Emergency telephone number:
During normal opening times: +1 (310) 635-2466
Chemtrec: +1 (202) 483-7616
2 Hazard(s) identification
· Classification of the substance or mixture
GHS08 Health hazard
Specific Target Organ Toxicity - Repeated Exposure 1 H372 Causes damage to the lung and the bones through prolonged or repeated
exposure.
Aquatic Chronic 3
H412 Harmful to aquatic life with long lasting effects.
· Additional information:
All components listed for this product are bound within the product. When handled as intended and under normal conditions of use, there is
no evidence that any of the ingredients are released in amounts that pose a significant health risk.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
GHS08
· Signal word Danger
(Contd. on page 2)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 5.0
Product name: Zirconia Alumina Abrasive Discs - Belts
(Contd. of page 1)
59.1.0
· Hazard-determining components of labeling:
trisodium hexafluoroaluminate
· Hazard statements
Causes damage to the lung and the bones through prolonged or repeated exposure.
Harmful to aquatic life with long lasting effects.
· Precautionary statements
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Avoid release to the environment.
Get medical advice/attention if you feel unwell.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Hazardous components and components with occupational exposure limits:
7440-67-7 Zirconia alumina
30-40%
7727-43-7 barium sulphate, natural
30-40%
1317-65-3 Limestone
 Acute Toxicity - Inhalation 4, H332
20-30%
557-05-1 zinc distearate, pure
5-10%
1332-58-7 Kaolin
5-10%
13775-53-6 trisodium hexafluoroaluminate
 Specific Target Organ Toxicity - Repeated Exposure 1, H372;
 Aquatic Chronic 2, H411;
 Acute Toxicity
- Inhalation 4, H332
5-<10%
7778-18-9 calcium sulphate, natural
1-5%
107-21-1 ethylene glycol
 Acute Toxicity - Oral 4, H302
≤1%
1309-37-1 diiron trioxide
≤1%
14075-53-7 potassium tetrafluoroborate
 Acute Toxicity - Oral 3, H301;
 Skin Irritation 2, H315; Eye Irritation 2A, H319
≤1%
15096-52-3 cryolite
 Aquatic Chronic 2, H411;
 Acute Toxicity - Inhalation 4, H332
0.25-≤1%
14808-60-7 Quartz (SiO2)
 Carcinogenicity 1A, H350
<0.1%
· Non-hazardous components:
Resin
10-20%
Paper Backing
10-20%
1592-23-0 calcium distearate, pure
5-10%
Garnet
5-10%
Lubricant
1-5%
Filler
1-5%
Nylon loop
1-5%
Wax
1-5%
1317-61-9 triiron tetraoxide
≤1%
· Additional information:
Product may contain many or all of the above ingredients.
The specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.
(Contd. on page 3)


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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 5.0
Product name: Zirconia Alumina Abrasive Discs - Belts
(Contd. of page 2)
59.1.0
4 First-aid measures
· Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
Eye irritation
Dermatitis
· Indication of any immediate medical attention and special treatment needed No further relevant information available.
5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents: Use fire fighting measures that suit the environment.
· Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced.
· Advice for firefighters
· Protective equipment: No special measures required.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures Keep away from ignition sources
· Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
Inform respective authorities in case of seepage into water course or sewage system.
· Methods and material for containment and cleaning up:
Pick up mechanically.
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling Ensure proper ventilation/exhaustion at workplaces.
· Information about protection against explosions and fires: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a cool location.
No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Store receptacle in a well ventilated area.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical systems: No additional data. See 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 5.0
Product name: Zirconia Alumina Abrasive Discs - Belts
(Contd. of page 3)
59.1.0
At this time, the remaining constituent has no known exposure limits.
7440-67-7 Zirconia alumina
PEL
Long-term value: 5 mg/m³
as Zr
REL
Short-term value: 10 mg/m³
Long-term value: 5 mg/m³
as Zr
TLV
Short-term value: 10 mg/m³
Long-term value: 5 mg/m³
as Zr; A4
7727-43-7 barium sulphate, natural
PEL
Long-term value: 15* 5** mg/m³
*total dust **respirable fraction
REL
Long-term value: 10* 5** mg/m³
*total dust **respirable fraction
TLV
Long-term value: 5* mg/m³
*inhalable fraction; E
1317-65-3 Limestone
PEL
Long-term value: 15 mg/m³
557-05-1 zinc distearate, pure
PEL
Long-term value: 15* 5** mg/m³
*total dust **respirable fraction
REL
Long-term value: 10* 5** mg/m³
*total dust **respirable fraction
TLV
Long-term value: 10* 3** mg/m³
*inhalable, **respirable particulate matter, *A4
1332-58-7 Kaolin
PEL
Long-term value: 15* 5** mg/m³
*total dust **respirable fraction
REL
Long-term value: 10* 5** mg/m³
*total dust **respirable fraction
TLV
Long-term value: 2* mg/m³
E; respirable particulate matter, A4
7778-18-9 calcium sulphate, natural
PEL
Long-term value: 15* 5** mg/m³
*total dust **respirable fraction
REL
Long-term value: 10* 5** mg/m³
*total dust **respirable fraction
TLV
Long-term value: 10* mg/m³
*as inhalable fraction
107-21-1 ethylene glycol
TLV
Short-term value: 10** mg/m³, 50* ppm
Long-term value: 25* ppm
*vapor fraction:**inh. fraction, aerosol only, A4
WEEL I (2)
1309-37-1 diiron trioxide
PEL
Long-term value: 10* mg/m³
*Fume
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 5.0
Product name: Zirconia Alumina Abrasive Discs - Belts
(Contd. of page 4)
59.1.0
REL
Long-term value: 5 mg/m³
Dust & fume, as Fe
TLV
Long-term value: 5* mg/m³
*Respirable particulate matter, A4
14075-53-7 potassium tetrafluoroborate
PEL
Long-term value: 2.5 mg/m³
as F
REL
Long-term value: 2.5 mg/m³
as F
TLV
Long-term value: 2.5 mg/m³
as F, A4; BEI
15096-52-3 cryolite
PEL
Long-term value: 2.5 mg/m³
as F
REL
Long-term value: 2.5 mg/m³
as F
14808-60-7 Quartz (SiO2)
PEL
Long-term value: 0.05* mg/m³
*resp. dust; 30mg/m3/%SiO2+2
REL
Long-term value: 0.05* mg/m³
*respirable dust; See Pocket Guide App. A
TLV
Long-term value: 0.025* mg/m³
*respirable particulate matter, A2
· Ingredients with biological limit values:
14075-53-7 potassium tetrafluoroborate
BEI 2 mg/L
Medium: urine
Time: prior to shift
Parameter: Fluoride (background, nonspecific)
3 mg/L
Medium: urine
Time: end of shift
Parameter: Fluoride (background, nonspecific)
15096-52-3 cryolite
BEI 2 mg/L
Medium: urine
Time: prior to shift
Parameter: Fluoride (background, nonspecific)
3 mg/L
Medium: urine
Time: end of shift
Parameter: Fluoride (background, nonspecific)
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
· Breathing equipment: Use suitable respiratory protective device when high concentrations are present.
· Protection of hands: Not required.
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Safety Data Sheet
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Printing date 07/02/2024
Last revision 06/01/2024
Version 5.0
Product name: Zirconia Alumina Abrasive Discs - Belts
(Contd. of page 5)
59.1.0
· Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form:
Belt
Color:
According to product specification
· Odor:
uncharacteristic
· Odor threshold:
Not determined.
· pH-value:
Not applicable.
· Change in condition
Melting point/Melting range:
Undetermined.
Boiling point/Boiling range:
Undetermined.
· Flash point:
Not applicable.
· Flammability (solid, gaseous):
Not determined.
· Decomposition temperature:
Not determined.
· Ignition temperature:
Product is not selfigniting.
· Danger of explosion:
Product does not present an explosion hazard.
· Explosion limits:
Lower:
Not determined.
Upper:
Not determined.
· Vapor pressure:
Not applicable.
· Density:
Not determined.
· Relative density
Not determined.
· Vapor density
Not applicable.
· Evaporation rate
Not applicable.
· Solubility in / Miscibility with
Water:
Insoluble.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Not applicable.
Kinematic:
Not applicable.
· Solvent content:
VOC content:
1.00 %
Solids content:
100.0 %
· Other information
No further relevant information available.
10 Stability and reactivity
· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 5.0
Product name: Zirconia Alumina Abrasive Discs - Belts
(Contd. of page 6)
59.1.0
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
ATE (Acute Toxicity Estimate)
Oral
LD50
10,000 mg/kg
Inhalative LC50/4 h 7.69 mg/l
  1317-65-3 Limestone
Oral
LD50
6,450 mg/kg (rat)
Dermal
LD50
>2,000 mg/kg (rat)
Inhalative LC50/4 h 3 mg/l (rat)
557-05-1 zinc distearate, pure
Oral
LD50
5,000 mg/kg (rat)
Dermal
LD50
>2,000 mg/kg (rabbit)
13775-53-6 trisodium hexafluoroaluminate
Inhalative LC50/4 h 1.5 mg/l (ATE)
107-21-1 ethylene glycol
Oral
LD50
5,840 mg/kg (rat)
Dermal
LD50
9,430 mg/kg (rabbit)
1309-37-1 diiron trioxide
Oral
LD50
>5,000 mg/kg (rat)
14075-53-7 potassium tetrafluoroborate
Oral
LD50
100 mg/kg (ATE)
15096-52-3 cryolite
Inhalative LC50/4 h 1.5 mg/l (ATE)
· Primary chemical irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
Abrasive eye irritant
Abrasive skin irritant
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
1309-37-1 diiron trioxide
3 
14075-53-7 potassium tetrafluoroborate
3 
14808-60-7 Quartz (SiO2)
1 
· NTP (National Toxicology Program)
14808-60-7 Quartz (SiO2)
K 
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
(Contd. on page 8)


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Safety Data Sheet
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Printing date 07/02/2024
Last revision 06/01/2024
Version 5.0
Product name: Zirconia Alumina Abrasive Discs - Belts
(Contd. of page 7)
59.1.0
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Harmful to fish
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Harmful to aquatic organisms
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation: Contact waste processors for recycling information.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· DOT, ADN, IMDG, IATA
not regulated
· UN proper shipping name
· DOT, ADN, IMDG, IATA
not regulated
· Transport hazard class(es)
· DOT, ADN, IMDG, IATA
· Class
not regulated
· Packing group
· DOT, IMDG, IATA
not regulated
· Environmental hazards:
· Marine pollutant:
No
· Special precautions for user
Not applicable.
· Transport in bulk according to Annex II of MARPOL73/78 and
the IBC Code
Not applicable.
· UN "Model Regulation":
not regulated
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
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Safety Data Sheet
acc. to OSHA HCS
Printing date 07/02/2024
Last revision 06/01/2024
Version 5.0
Product name: Zirconia Alumina Abrasive Discs - Belts
(Contd. of page 8)
59.1.0
· Section 313 (Specific toxic chemical listings):
7727-43-7 barium sulphate, natural
557-05-1 zinc distearate, pure
107-21-1 ethylene glycol
· TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
· Hazardous Air Pollutants
107-21-1 ethylene glycol
· Proposition 65
· Chemicals known to cause cancer:
14808-60-7 Quartz (SiO2)
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
107-21-1 ethylene glycol
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
To the best of our knowledge, the information contained herein is accurate. However, it does not describe a guarantee of product properties
and does not establish a contractual legal relationship.
· Department issuing SDS: Technical Services
· Contact: Pablo Mendoza
· Last revision / supersedes version: 06/01/2024 / 4.0
· Supersedes date: 06/01/2022
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by
Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Acute Toxicity - Oral 3: Acute toxicity – Category 3
Acute Toxicity - Inhalation 4: Acute toxicity – Category 4
Skin Irritation 2: Skin corrosion/irritation – Category 2
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
Carcinogenicity 1A: Carcinogenicity – Category 1A
Specific Target Organ Toxicity - Repeated Exposure 1: Specific target organ toxicity (repeated exposure) – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered.